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1.
2.
Nucleophile(s) almost exclusively added from the equatorial side of 2-nitro-β--2-enopyranoside and the axial side of 2-nitro---1-enitol. On the other hand, methoxide and -butyl peroxide ions approached from the equatorial side of 2-nitro-α--2-enopyranoside, whereas methanol and hydrogen peroxide ion from the axial side. 相似文献
3.
Several tri- and di-organo(oxinato)-silanes and -germanes have been prepared from corresponding organo-silazanes or -germazanes. The UV spectra indicate that the compounds involve either chelated or non-chelated oxinato groups or both depending on the number and kind of organic groups on the metal atom. The PMR spectra of RR′Si(OX)2 (R = alkyl, R′ = vinyl or phenyl) are interpreted in terms of rapid exchanges between the two kinds of oxinato groups 相似文献
4.
The atomic absorption spectrometry of aluminum with a carbon tube atomizer is described, with particular reference to the heating cycle, argon flow rate and amplifier time constant. Interferences are eliminated by pre-atomization heating or with a hydrogen-argon-entrained air flame. Under optimal conditions, the sensitivity (1 % absorbance) is 5·10?11g, and the relative standard deviation is 2.3 for 2.5 ng Al. 相似文献
5.
Harada H Kazami J Watanuki S Tsuzuki R Sudoh K Fujimori A Tanaka A Tsukamoto S Yanagisawa I 《Chemical & pharmaceutical bulletin》2001,49(5):606-612
In the present article we wish to report the discovery of a novel class of ET(A)-selective endothelin (ET) receptor antagonists through the modification of the ET(A)/ET(B) non-selective antagonist, Ro47-0203 (Bosentan, 1). Replacement of the benzenesulfonamide group of 1 with a 2-phenylethenesulfonamide group gave compound 5a and resulted in improvement in ET(A)-selectivity. Optimization of the alkoxy side chain attached to the core pyrimidine ring yielded the 2-fluoroethoxy derivative (5n) with further improvement of ET(A)-selectivity. [IC50=2.1 nM for ET(A) receptor, ET(B)/ET(A) ratio=1200]. After oral administration, compound 5n inhibited the big ET-1 induced pressor response in pithed rats with a DR2 value of 2.6 mg/kg and also exhibited a potent antagonistic activity in conscious rats. 相似文献
6.
Lewis acids such as ZrCl(4) or HfCl(4) catalyze the hydrostannation of acetylenes 1 by tributyltin hydride to produce the cis vinylstannanes 2 by regio- and stereoselective anti-hydrostannation. The hydrostannation of acetylenes using dibutyltin dihydride was also catalyzed by ZrCl(4) to give the stereodefined Z-Z divinyltin derivatives 4 by an anti-hydrostannation pathway. The use of nonpolar solvents such as toluene or hexane was essential for obtaining high stereoselectivity and chemical yield. Since ZrCl(4) and HfCl(4) are not soluble in such solvents, the hydrostannations were carried out in a heterogeneous system. The reactions of internal acetylenes with Bu(3)SnH proceeded smoothly, although the use of stoichiometric amounts of ZrCl(4) gave better results. The ZrCl(4)-catalyzed hydrostannation at 0 degrees C gave better yields and stereoselectivities than the reaction at room temperature. To help clalify the reason, the reaction of Bu(3)SnH with ZrCl(4) was monitored by (1)H and (119)Sn NMR spectroscopy, and it was found that Bu(3)SnH reacted with ZrCl(4) at room temperature to afford a mixture of tributyltin hydride, dibutyltin dihydride, and tetrabutyltin. 相似文献
7.
We discuss exotic meson spectroscopy near open bottom thresholds. Assuming the exotic mesons as ${B^{(\ast)}\bar{B}^{(\ast)}}$ molecular states, we study the interaction among two heavy mesons in terms of the one boson exchange potential model. It is shown that masses of Z b (10610) and Z b (10650) are reproduced as ${B^{(\ast)}\bar{B}^{(\ast)}}$ bound and resonance states. Besides, we also show that ${B^{(\ast)}\bar{B}^{(\ast)}}$ molecular states having various exotic quantum numbers can exist around the thresholds. By contrast, there are no ${D^{(\ast)}\bar{D}^{(\ast)}}$ molecular states having exotic quantum numbers. 相似文献
8.
Rokuro Muki Eli Sternberg 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》1971,22(5):809-824
Zusammenfassung Diese Arbeit befasst sich analytisch mit der statischen Kraftübertragung auf eine einzelne unendliche, elastische Faser, die an einem Querschnitt unterbroche ist. Die Faser ist vollständig in einem unendlich ausgedehnten Körper von anderen elastischen Eigenschaften eingebettet. Der Körper selbst ist im Unendlichen einer einachsigen Zugspannung parallel zur Faser ausgesetzt. Die Charakterisierung der gesuchten Faserkraft wird durch eine schon früher erprobte Annäherungsmethode auf eine Fredholmsche Integralgleichung zweiter Art zurückgeführt und die letztere wird auf numerischem Wege gelöst. Die Verteilung der Faserkraft ist für verschiedene Werte des Verhältnisses der beiden Elastizitätsmodulen dargestellt.
The results communicated in this paper were obtained in the course of an investigation conducted under Contract N00014-67-A-0094-0020 with the Office of Naval Research in Washington, D.C. 相似文献
The results communicated in this paper were obtained in the course of an investigation conducted under Contract N00014-67-A-0094-0020 with the Office of Naval Research in Washington, D.C. 相似文献
9.
10.