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41.
Y.N. Joshi K.S. Bhatia W.E. Jones 《Spectrochimica Acta Part B: Atomic Spectroscopy》1973,28(4):149-155
The third and fourth spectra of gallium have been photographed in the region 6000–400 Å by using a 3-m normal-incidence, vacuum spectrograph and a 3.5-m Ebert spectrograph. A three-electrode vacuum spark and a spark in helium were used as sources. New measurements for the wavelengths have confirmed earlier work and provided material to extend the analysis of Ga III and Ga IV. 相似文献
42.
We report the integration of inorganic nanotubes into metal-oxide-solution field effect transistors (FETs) which exhibit rapid field effect modulation of ionic conductance. Surface functionalization, analogous to doping in semiconductors, can switch the nanofluidic transistors from p-type to ambipolar and n-type field effect transistors. Transient study reveals the kinetics of field effect modulation is controlled by ion-exchange step. Nanofluidic FETs have potential implications in subfemtoliter analytical technology and large-scale nanofluidic integration. 相似文献
43.
Adams J Aggarwal MM Ahammed Z Amonett J Anderson BD Arkhipkin D Averichev GS Badyal SK Bai Y Balewski J Barannikova O Barnby LS Baudot J Bekele S Belaga VV Bellwied R Berger J Bezverkhny BI Bharadwaj S Bhasin A Bhati AK Bhatia VS Bichsel H Billmeier A Bland LC Blyth CO Bonner BE Botje M Boucham A Brandin AV Bravar A Bystersky M Cadman RV Cai XZ Caines H Calderón de la Barca Sánchez M Carroll J Castillo J Cebra D Chajecki Z Chaloupka P Chattopdhyay S Chen HF Chen Y Cheng J Cherney M Chikanian A 《Physical review letters》2004,93(25):252301
Results on high transverse momentum charged particle emission with respect to the reaction plane are presented for Au + Au collisions at square root s(NN)=200 GeV. Two- and four-particle correlations results are presented as well as a comparison of azimuthal correlations in Au + Au collisions to those in p + p at the same energy. The elliptic anisotropy v(2) is found to reach its maximum at p(t) approximately 3 GeV/c, then decrease slowly and remain significant up to p(t) approximately 7-10 GeV/c. Stronger suppression is found in the back-to-back high-p(t) particle correlations for particles emitted out of plane compared to those emitted in plane. The centrality dependence of v(2) at intermediate p(t) is compared to simple models based on jet quenching. 相似文献
44.
It is well known that mass-metric tensor determinants det(G(s)) influence the equilibrium statistics and the rates of conformational transitions for polymers with constrained bond lengths and bond angles. It is now standard practice to include a Fixman-style compensating potential of the form U(c)(q(s)) proportional, variant(-k(B)T/2)ln[det(G(s))] as part of algorithms for torsional space molecular dynamics. This elegant strategy helps eliminate unwarranted biases that arise due to the imposition of holonomic constraints. However, the precise nature and extent of variation of det(G(s)) and hence ln[det(G(s))] with chain conformation and chain length has never been quantified. This type of analysis is crucial for understanding the nature of the conformational bias that the introduction of a Fixman potential aims to eliminate. Additionally, a detailed analysis of the conformational dependence of det(G(s)) will help resolve ambiguities regarding suggestions for incorporating terms related to det(G(s)) in the design of move sets in torsional space Monte Carlo simulations. In this work, we present results from a systematic study of the variation of det(G(s)) for a serial polymer with fixed bond lengths and bond angles as a function of chain conformation and chain length. This analysis requires an algorithm designed for rapid computation of det(G(s)) which simultaneously allows for a physical/geometric interpretation of the conformational dependence of det(G(s)). Consequently, we provide a detailed discussion of our adaptation of an O(n) algorithm from the robotics literature, which leads to simple recursion relations for direct evaluation of det(G(s)). Our analysis of the conformational dependence of det(G(s)) yields the following insights. (1) det(G(s)) is maximized for spatial conformers and minimized for planar conformations. (2) Previous work suggests that it is logical to expect that the conformational dependence of det(G(s)) becomes more pronounced with increase in chain length. Confirming this expectation, we provide systematic quantification of the nature of this dependency and show that the difference in det(G(s)) between spatial and planar conformers, i.e., between the maxima and minima of det(G(s)) grows systematically with chain length. Finally, we provide a brief discussion of implications of our analysis for the design of move sets in Monte Carlo simulations. 相似文献
45.
Bachhawat P Mishra S Bhatia Y Bisaria VS 《Applied biochemistry and biotechnology》2004,118(1-3):269-282
The biosynthetic activity of yeast Pichia etchellsii β-glucosidase II (BglII) expressed in recombinant Escherichia coli was utilized for synthesis of cellooligosaccharides, alkyl and terpene glucosides. Cellooligosaccharides with a degree of
polymerization of 3 and greater were resolved by thin-layer chromatography (TLC) using an ethyl acetate: 1-propanol:2-propanol:water
(8:5:1:1) solvent system followed by visualization with 0.2% naphthoresorcinol reagent. Using 2M cellobiose and 15 IU of partially purified BglII, 57 mmol/L of oligosaccharides (comprising mostly cellotriose and cellopentaose) was synthesized in 16 h. Similarly, alkyl
glucosides with chain lengths from 6 to 10 carbons were synthesized and products extracted to near purity by ethylacetate
extraction. The same extraction method was employed to separate, to near purity, various monoterpenyl (nerol, geraniol, citronellol)
glucosides. A reliable and simple method for separation of cellooligosaccharides using a combination of Bio-Gel P-2 gel filtration
and charcoal celite adsorption chromatography was developed. The cellooligosaccharides were separated to purity as confirmed
by TLC. The enzyme was among the very few that could synthesize a wide variety of glycoconjugates. 相似文献
46.
We present a theory for the transport of molecules adsorbed in slit and cylindrical nanopores at low density, considering the axial momentum gain of molecules oscillating between diffuse wall reflections. Good agreement with molecular dynamics simulations is obtained over a wide range of pore sizes, including the regime of single-file diffusion where fluid-fluid interactions are shown to have a negligible effect on the collective transport coefficient. We show that dispersive fluid-wall interactions considerably attenuate transport compared to classical hard sphere theory. 相似文献
47.
Nelson ML Ismail MY McIntyre L Bhatia B Viski P Hawkins P Rennie G Andorsky D Messersmith D Stapleton K Dumornay J Sheahan P Verma AK Warchol T Levy SB 《The Journal of organic chemistry》2003,68(15):5838-5851
A diverse collection of tetracycline derivatives has been synthesized utilizing Heck, Suzuki, and other palladium-coupling reactions via tetracycline arenediazonium and iodoarene salts. Large numbers of tetracyclines are now possible via these reactions, including numerous upper periphery derivatives of doxycycline, minocycline, sancycline, and methacycline modified at positions C7, C9, and C6-C13 on the tetracycline naphthacene ring. Application of palladium-coupling reactions to the tetracyclines has yielded new tetracycline classes with differing structural attributes, greatly increasing the structural diversity of this family of antibiotics, one of the last of the early antibiotic families to be expanded by organic and medicinal chemistry. 相似文献
48.
Rohit Deo Mengchen Hsieh Clifford M. Hurvich Philippe Soulier 《Statistical Inference for Stochastic Processes》2000,3(3):291-292
Volume Contents
Volume contents 相似文献49.
An infinitely extending homogenous partially ionized plasma endowed with several physical mechanisms and permeated by a variable magnetic field is considered. The combined effect of these parameters, namely, Hall currents, finite conductivity, ion viscosity, collision with neutrals and thermal conductivity on the gravitational instability of the plasma is studied. It is found that the several mechanisms play different physical roles in the perturbed problem. Jeans' Criterion is analyzed in the framework of Tsallis' statistics for possible modifications due to the presence of nonextensive effects. A simple generalization of the Jeans' criterion is obtained and the standard values are obtained in the limiting case q = 1, q being the nonextensive parameter. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
50.
Smita A Ghanekar Sonny Bhatia Joyce J Ruitenberg DeLa Corazon Rosa Mary L Disis Vernon C Maino Holden T Maecker Cory A Waters 《Journal of immune based therapies and vaccines》2007,5(1):7-14