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81.
Naba K. Mondal Saurabh D. Rindani Kaustubh Agashe Pankaj Agrawal B. Ananthanarayan Ketevi Assamagan Alfred Bartl Subhendu Chakrabarti Utpal Chattopadhyay Debajyoti Choudhury Eung-Jin Chun Prasanta K. Das Siba P. Das Amitava Datta Sukanta Dutta Jeff Forshaw Thomas Gajdosik Dilip K. Ghosh Rohini M. Godbole Monoranjan Guchait Partha Konar Sabine Kraml Manas Maity Kajari Mazumdar Naba K. Mondai Biswarup Mukhopadhyaya Meenakshi Narain Santosh K. Rai Sreerup Raychaudhuri Saurabh D. Rindani D. P. Roy Seema Sharma Ritesh K. Singh Rishikesh Vaidya 《Pramana》2004,63(6):1331-1353
This is a summary of the projects undertaken by the working group I on high energy and collider physics. 相似文献
82.
The Mixing Effect of Glycylglycine with KCl, KBr, and Na2SO4 from Volumetric and Viscometric Investigations at 298.15 K 总被引:1,自引:1,他引:0
The mixing effect of a simple peptide such as glycylglycine, in the presence of aqueous electrolytes, has been studied by examining their volumetric and viscometric behavior. The increase in the apparent molar properties of both glycylglycine and electrolytes is attributed to the interactions present among cation, anion, the head groups of the peptide, and the peptide bond. Simple equations are developed to account for such interactions with a view to correlate apparent molar properties of glycylglycine and electrolyte in their aqueous mixtures. Transfer properties of both glycylglycine and electrolyte are investigated in order to understand the changes in the property of one component by the addition of another. These interactions are also supported by viscosity data, for which a simple model is developed to correlate the variation in viscosities with composition of a component. 相似文献
83.
84.
The threshold enhancement in the cross section γγ → ?0?0, including the lower energy point reported by the CELLO group, and the observed angular distributions have been interpreted in terms of an isoscalar resonance with JPC = 0++, mass 1450–1550 MeV and width 100–150 MeV. 相似文献
85.
86.
M. Deshmukh D. Kharade S. D. Shirke 《Monatshefte für Chemie / Chemical Monthly》1994,125(8-9):971-976
Summary Treatment of 2-phenoxypropionic acid with polyphosphoric acid gave substituted benzofuran-3-ones (2a–h), which were converted into 2,3,4-trihydrodibenzofuran-3-ones (4a–h)via the compounds3a–h.Clemmensen reduction of the compounds4a–h gave the 2,3,4-trihydrodibenzofuranes (5a–h).
Eine einfache Synthese von 2,3,4-Trihydrobenzofuranen
Zusammenfassung Behandlung von 2-Phenoxypropionsäure mit Polyphosphorsäure lieferte die substituierten Benzofuran-3-one (2a–h), welche über3a–h in die 2,3,4-Trihydrodibenzofuran-3-one (4a–h) übergeführt wurden. DurchClemmensen-Reduktion von4a–h wurden die gewünschten 2,3,4-Trihydrobenzofurane (5a–h) erhalten.相似文献
87.
Parag V. Adhyapak Prashant R. Karandikar Jagdish W. Dadge Rohini C. Aiyer Asha J. Chandwadkar 《Central European Journal of Chemistry》2006,4(2):317-328
Uniform nanowires of silver and gold inside the channels of MCM-41 were prepared by controlled reduction of their respective
metal salts with sodium borohydride (NaBH4). Presence of nanowires of silver and gold in MCM-41 were confirmed by high angle X-ray diffraction (XRD) data (peaks between
2ϑ = 30 − 60°) and transmission electron microscopy (TEM) confirmed the diameter of the nanowires. Diameter of nanowires is
found to be ∼ 2.8 nm which is coincident with channel diameter of MCM-41. Optical properties of these heterostructured materials
Ag-MCM-41 and Au-MCM-41 reveals the presence of surface plasmon absorption peaks of silver and gold respectively, and the
shift in the absorption bands are associated to agglomeration of clusters inside the channels. Room temperature photoluminescence
spectra exhibits interesting optical properties as observed for direct band gap semiconductors. Non-linear optical properties
(NLO) corresponding to second harmonic generation (SHG) values were also recorded for self supported films of these heterostructured
materials. Enhanced optical non-linearity was found to be arising from a corresponding increase of local field near the surface
plasmon resonance. Further enhancement in SHG was found with poling due to an induction of orientation order. 相似文献
88.
Polydispersed ZnO nanoparticles (ZnO1000 and ZnO600) with two different windows of particle size distributions (∼120 and 30 nm) were synthesized using citrate gel route and different annealing treatments (1000 and 600 °C, respectively). Photocatalytic efficiency of these samples was compared with TiO2 in its commercial form-P25, on two dyes, Methylene blue (MB) and Methyl orange (MO). The X-ray diffraction data showed wrutzite ZnO and anatase and rutile phases of P25. UV-visible absorbance spectra of ZnO1000 showed broad absorption range from UV-to-visible (from 382 to 700 nm), as against sharp absorption peaks in UV range for both ZnO600 and P25. The microstructural morphology as seen through scanning electron micrographs showed ZnO1000 with tetrapod-like structures while the ZnO600 showed almost spherical morphologies. Upon subjecting these catalysts to dye solutions in sunlight it was found that both the dyes were completely decolorised within 20 min by ZnO1000, as against partial decolorisation by ZnO600 and P25 ( 53% and 78% for MO and 77% and 88% for MB samples). The effect of catalyst loading (from 125 mg to 1 g) on decolorisation showed that ZnO1000 had good efficiency for all concentrations which was followed by P25 and then by ZnO600. Small perturbations are attributed to the competition between sunlight scattering-induced, reduced irradiation field and the exposed surface area offered by catalyst, which work as active sites for decolorisation. The reusability of the catalysts when studied on fresh dye samples (4 trials), the decolorisation efficiency decreased merely from 99.2% to 99.12% for ZnO1000 as compared to ZnO600 (53.3% to 19.94%) and P25 (78.3% to 31.42%), indicating the efficient reusability of ZnO1000. The effective half life of the catalysts, in terms of number of reuses, were calculated and found to be ∼3 for both ZnO600 and P25 and was >3000 for ZnO1000, which justifies its extremely high reuse. The byproduct analysis (compared with standards prescribed by World Health Organisation (WHO) and Central Pollution Control Board of India (CPCB)) showed cleavage of the chromophore and of other bonds with opening of benzene rings, indicating degradation of the dyes in concurrence with decolorisation, in the stipulated time. Further, cytotoxicity studies performed on SiHa cell lines showed non-toxicity of the byproducts with ZnO1000 as compared to ZnO600 and P25. 相似文献
89.
Kuldeep Mahato Anupriya Baranwal Rohini Kumari Ananya Srivastava Uday Pratap Azad Prof. Dr. Pranjal Chandra 《Electroanalysis》2023,35(9):e202300094
Silver nanoparticles (AgNPs) are one of the most widely used nanomaterials for biomedical applications. However, the impact of its synthesis by chemical and plant-mediated routes on its differential electrochemical behaviour has not been examined till date. Here, we report for the first time the differential study of the electrochemical behaviour of the AgNPs synthesized by different routes. First, the AgNPs were obtained by different routes (chemical and phytofabrication) and extensively characterized to compare their physical properties. Thereafter, a comparison of electron transfer kinetics between chemically synthesized (Ag−C) and phyto-fabricated (Ag-Phy) nanoparticles (NPs) has been studied by electrochemical techniques such as potentiodynamic cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). To further investigate the electrocatalytic properties of both types of AgNPs, we have used the peroxide moieties (H2O2), and the Ag−C NPs-based sensor probe has been reported to have four times better sensitivity than the Ag−Phy NPs-based sensor. The AgNPs modified sensor probes have also been tested in real-world environments to explore the consistency of their performance in complex matrices by using clinical urine samples, where we found comparable sensitivity to the standard conditions. 相似文献
90.
Reddy PM Prasad AV Rohini R Ravinder V 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2008,70(3):704-712
Efficient catalytic method for the reduction of pralidoxime to its amine derivative by macrocyclic Ni(II) compounds has been developed. Ten macrocyclic Schiff base Ni(II) compounds were synthesized via non-template synthesis by treating the corresponding macrocycles with nickel chloride in 1:1 ratio. The resulting compounds were characterized by elemental, IR, (1)H NMR, (13)C NMR, mass, electronic spectra, conductance, magnetic, thermal studies and their structures have been proposed. These compounds were used as catalysts for the reduction of pralidoxime to its amino derivative. The reduced pralidoxime was also characterized by spectral analysis and catalytic cycle has been established. The reduced product was determined spectrophotometrically by treating with ninhydrin reagent and the percent yields were found to be in the range of 75.12-82.36%. 相似文献