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91.
Farjadpour A Roundy D Rodriguez A Ibanescu M Bermel P Joannopoulos JD Johnson SG Burr GW 《Optics letters》2006,31(20):2972-2974
Finite-difference time-domain (FDTD) methods suffer from reduced accuracy when modeling discontinuous dielectric materials, due to the inhererent discretization (pixelization). We show that accuracy can be significantly improved by using a subpixel smoothing of the dielectric function, but only if the smoothing scheme is properly designed. We develop such a scheme based on a simple criterion taken from perturbation theory and compare it with other published FDTD smoothing methods. In addition to consistently achieving the smallest errors, our scheme is the only one that attains quadratic convergence with resolution for arbitrarily sloped interfaces. Finally, we discuss additional difficulties that arise for sharp dielectric corners. 相似文献
92.
Humberto Bustos Rodriguez Dagoberto Oyola Lozano Yebrayl A. Rojas Martínez Germán A. Pérez Alcázar Stefan Flege Adam G. Balogh Louis J. Cabri Michael Tubrett 《Hyperfine Interactions》2007,175(1-3):195-206
X-ray diffraction (XRD), Mössbauer spectrometry (MS), secondary ions mass spectroscopy (SIMS) and laser-ablation microprobe–inductively coupled plasma–mass spectrometry (LAM–ICP–MS) were used to study mineral samples of Colombian auriferous ores collected from the “El Diamante” mine, located in the municipality of Guachavez-Nariño, in Colombia. The samples were prepared as polished thin sections and polished sections. From XRD data, quartz, sphalerite and pyrite were detected and their respective cell parameters were estimated. From MS analyses, pyrite, arsenopyrite and chalcopyrite were identified; their respective hyperfine parameters and respective texture were deduced. Multiple regions of approximately 200 × 200 μm in each sample were analyzed with SIMS; the occurrence of “invisible gold” associated mainly with pyrite and secondarily with arsenopyrite could thus be assigned. It was also found that pyrite is of the arsenious type. Spots from 30 to 40 μm in diameter were analyzed with LAM–ICP–MS for pyrite, arsenopyrite and sphalerite; Au is “homogeneously” distributed inside the structure of the arsenious pyrite and the arsenopyrite (not as inclusions); the chemical composition indicates similarities of this “invisible gold”, forming a solid solution with arsenious pyrite and arsenopyrite. One hundred nineteen and 62 ppm of ‘invisible gold’ was quantified in 21 spots analyzed on pyrite and in 14 spots on arsenopyrite, respectively. 相似文献
93.
Daniel Gandolfo Roger Rodriguez Henry C. Tuckwell 《Journal of statistical physics》2017,166(5):1310-1333
We investigate the dynamics of large-scale interacting neural populations, composed of conductance based, spiking model neurons with modifiable synaptic connection strengths, which are possibly also subjected to external noisy currents. The network dynamics is controlled by a set of neural population probability distributions (PPD) which are constructed along the same lines as in the Klimontovich approach to the kinetic theory of plasmas. An exact non-closed, nonlinear, system of integro-partial differential equations is derived for the PPDs. As is customary, a closing procedure leads to a mean field limit. The equations we have obtained are of the same type as those which have been recently derived using rigorous techniques of probability theory. The numerical solutions of these so called McKean–Vlasov–Fokker–Planck equations, which are only valid in the limit of infinite size networks, actually shows that the statistical measures as obtained from PPDs are in good agreement with those obtained through direct integration of the stochastic dynamical system for large but finite size networks. Although numerical solutions have been obtained for networks of Fitzhugh–Nagumo model neurons, which are often used to approximate Hodgkin–Huxley model neurons, the theory can be readily applied to networks of general conductance-based model neurons of arbitrary dimension. 相似文献
94.
This study examined the time course of cochlear suppression using a tone-burst suppressor to measure decrement of distortion-product otoacoustic emissions (DPOAEs). Seven normal-hearing subjects with ages ranging from 19 to 28 yr participated in the study. Each subject had audiometric thresholds ≤ 15 dB HL [re ANSI (2004) Specifications for Audiometers] for standard octave and inter-octave frequencies from 0.25 to 8 kHz. DPOAEs were elicited by primary tones with f(2)?= 4.0 kHz and f(1)?= 3.333 kHz (f(2)/f(1)?= 1.2). For the f(2), L(2) combination, suppression was measured for three suppressor frequencies: One suppressor below f(2) (3.834 kHz) and two above f(2) (4.166 and 4.282 kHz) at three levels (55, 60, and 65 dB SPL). DPOAE decrement as a function of L(3) for the tone-burst suppressor was similar to decrements obtained with longer duration suppressors. Onset- and setoff- latencies were ≤ 4 ms, in agreement with previous physiological findings in auditory-nerve fiber studies that suggest suppression results from a nearly instantaneous compression of the waveform. Persistence of suppression was absent for the below-frequency suppressor (f(3)?= 3.834 kHz) and was ≤ 3 ms for the two above-frequency suppressors (f(3)?= 4.166 and 4.282 kHz). 相似文献
95.
N. K. Leite J. G. Santos R. F. Souza G. M. Cabianchi F. O. Xavier B. M. Gomes L. B. Silveira A. C. Oliveira A. F.R. Rodriguez P. C. Morais 《The European physical journal. Special topics》2008,153(1):45-48
In this study we demonstrate the usefulness of the
Photoacoustic Spectroscopy (PAS) in the investigation of water collected
from a natural site located within the Amazon region, Brazil, during the wet
to dry seasons transition (May/2006). The water samples were collected from
different stages along a hydrologic pathway including precipitation water
(Prec), groundwater (GW), through flow water (TF), overland flow water (OF),
and stream flow water (SW). The observed photoacoustic spectral features, in
the 0.3 to 1.0 μm wavelength region, fall within three distinct bands
(C, S, and L). We found band-C, band-S and band-L occurring in the spectral
range of 0.30 to 0.40 μm, 0.40 to 0.45 μm and 0.45 to 1.0 μm
regions, respectively. The photoacoustic features shift peak positions and
change intensities for all samples investigated, thus supporting the
proposal of PAS as a useful technique to investigate water samples from
natural environments. 相似文献
96.
Pierre-Yves Roger Fabien Blondeau David Bensa Thierry Constantieux Jean Rodriguez 《Molecular diversity》2009,13(4):469-473
A new one-pot domino reaction for a general entry to functionalised bridged bicyclo[n.2.1] ring systems from α ,α’-diactivated cyclic ketones and trans-1,4-dihalides is described. The sequence combines a base promoted C–O cycloalkylation reaction leading to fused polycyclic
enol ethers and their in situ palladium-catalysed isomerisation. 相似文献
97.
J M Caba I M Rodriguez I Manzanares E Giralt F Albericio 《The Journal of organic chemistry》2001,66(23):7568-7574
Marine organisms are a rich source of novel, biologically active compounds. Herein, the solid-phase total synthesis of trunkamide A, currently in preclinical trials, is presented. Trunkamide A contains a thiazoline heterocycle and two residues of Ser and Thr with the hydroxy function modified as reverse prenyl (rPr). Cornerstones of the synthesis are as follows: (i) solid-phase peptide chain elongation using a quasi-orthogonal protecting scheme with tert-butyl and fluorenyl based groups, on a chlorotrityl resin; (ii) concourse of HOAt-based coupling reagents; and (iii) cyclizations in solution. Furthermore, the following synthetic steps are discussed: (i) preparation of the reverse prenyl derivatives of Ser and Thr; (ii) introduction of precursor of thiazoline as a protected amino thionoacid derivative; and (iii) formation of the thiazoline ring with DAST. All these features make this strategy particularly suitable for the large-scale synthesis of trunkamide A and other peptides containing the same motifs. 相似文献
98.
A. F.R. Rodriguez J. G. Santos L. B. Silveira A. C. Oliveira P. C. Morais O. A.C. Nunes 《The European physical journal. Special topics》2008,153(1):543-546
Photoacoustic spectroscopy (PAS) was used to investigate
samples produced from Baru (Dipteryx alata Vog.), a typical fruit from the Brazilian
Cerrado, which is considered as a good source of nutrients. The
photoacoustic (PA) spectra of samples prepared from Baru seeds present three
different absorption bands in the wavelength range 0.3–1.0 μm, named
Band-C, Band-S, and Band-L. We found that PAS can be useful for monitoring
the strong absorption of visible light by Baru's seeds constituents mainly
in the shorter wavelength measured range. This study is important from both
agricultural and commercial point of view once it introduces PAS as a
potential characterization technique allowing better control of fruit and
seed selection, storage and transportation. 相似文献
99.
The study of nonlinear diffusion equations produces a number of peculiar phenomena not present in the standard linear theory. Thus, in the sub-field of very fast diffusion it is known that the Cauchy problem can be ill-posed, either because of non-uniqueness, or because of non-existence of solutions with small data. The equations we consider take the general form ut=(D(u,ux)ux)x or its several-dimension analogue. Fast diffusion means that D→∞ at some values of the arguments, typically as u→0 or ux→0. Here, we describe two different types of non-existence phenomena. Some fast-diffusion equations with very singular D do not allow for solutions with sign changes, while other equations admit only monotone solutions, no oscillations being allowed. The examples we give for both types of anomaly are closely related. The most typical examples are vt=(vx/∣v∣)x and ut=uxx/∣ux∣. For these equations, we investigate what happens to the Cauchy problem when we take incompatible initial data and perform a standard regularization. It is shown that the limit gives rise to an initial layer where the data become admissible (positive or monotone, respectively), followed by a standard evolution for all t>0, once the obstruction has been removed. 相似文献
100.
Cordero BM Pérez Pavón JL García Pinto C Fernández Laespada ME Carabias Martínez R Rodriguez Gonzalo E 《Journal of chromatography. A》2000,902(1):195-204
An overview of the analytical applications of membrane-based systems for sample enrichment in chromatography and capillary electrophoresis is presented. A brief introduction to the different types of membranes and the main forces related to the transport through them is also given. 相似文献