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81.
Dipl.‐Chem. Christian Schöttle Dr. Pascal Bockstaller Dr. Radian Popescu Prof. Dr. Dagmar Gerthsen Prof. Dr. Claus Feldmann 《Angewandte Chemie (International ed. in English)》2015,54(34):9866-9870
Mo0, W0, Fe0, Ru0, Re0, and Zn0 nanoparticles—essentially base metals—are prepared as a general strategy by a sodium naphthalenide ([NaNaph])‐driven reduction of simple metal chlorides in ethers (1,2‐dimethoxyethane (DME), tetrahydrofuran (THF)). All the nanoparticles have diameters ≤10 nm, and they can be obtained either as powder samples or long‐term stable suspensions. Direct follow‐up reactions (e.g., Mo0+S8, FeCl3+AsCl3, ReCl5+MoCl5), moreover, allow the preparation of MoS2, FeAs2, or Re4Mo nanoparticles of similar size as the pristine metals (≤10 nm). 相似文献
82.
Higher order elements were first design for linear problems where, in certain situations, they present advantages over the lower order elements. A method to efficiently extend their use to geometrical nonlinear problems as panel flutter and postbuckling behavior is presented. The chaotic and limit-cycle oscillations of an isotropic plate are obtained based on direct integration of the discretized equation of motion. The plate is modeled using the von Karman theory and the geometrical nonlinearities are separated in a nonlinear term of the first kind which manifests especially in the prebuckling and buckling regimes, and a nonlinear term of the second kind which is responsible for the postbuckling behavior. A fifth order, fully compatible element has been used to model thin plates while the inplane loads where introduced through a membrane element. The aerodynamics was modeled using the first order 'piston theory. The method introduces the concept of a deteriorated form of the second geometric matrix which is equivalent to neglecting higher order terms in the strain energy of the plate. This allows for a drastic reduction in the computational effort with no observable loss of accuracy. Well established results in the literature are used to validate the method. 相似文献
83.
Comorosan S Polosan S Jipa S Popescu I Marton G Ionescu E Cristache L Badila D Mitrica R 《Journal of photochemistry and photobiology. B, Biology》2011,102(1):39-44
Free radicals generation is inhibited through green light (GL) irradiation in cellular systems and in chemical reactions. Standard melanocyte cultures were UV-irradiated and the induced cellular reactive oxygen species (ROS) were quantified by the fluorescence technique. The same cell cultures, previously protected by a 24h GL exposure, displayed a significantly lower ROS production. A simple chemical reaction is subsequently chosen, in which the production of free radicals is well defined. Paraffin wax and mineral oil were GL irradiated during thermal degradation and the oxidation products checked by chemiluminescence [CL] and Fourier transform infrared spectra [FT-IR]. The same clear inhibition of the radical oxidation of alkanes is recorded. A quantum chemistry modeling of these results is performed and a mechanism involving a new type of Rydberg macromolecular systems with implications for biology and medicine is suggested. 相似文献
84.
Alessandro Fonda Rodica Toader 《Nonlinear Analysis: Theory, Methods & Applications》2011,74(7):2485-2496
We prove the existence of infinitely many periodic solutions for radially symmetric systems with a singularity of repulsive type. The nonlinearity is assumed to have a linear growth at infinity, being controlled by two constants which have a precise interpretation in terms of the Dancer-Fu?ik spectrum. Our result generalizes an existence theorem by Del Pino et al. (1992) [4], obtained in the case of a scalar second order differential equation. 相似文献
85.
Rodica Olar Mihaela Badea Dana Marinescu Larisa Calu Cristina Bucur 《Journal of Thermal Analysis and Calorimetry》2011,105(2):571-575
Novel complexes of type [M2LCl4]·nH2O ((1) M:Ni, n = 5; (2) M:Cu, n = 0 and (3) M:Zn, n = 2; L: ligand resulted from 1,2-phenylenediamine, 3,6-diazaoctane-1,8-diamine and formaldehyde template condensation) were
synthesised and characterised. The features of complexes have been assigned from microanalytical, IR and UV–Vis data. The
thermal analyses have evidenced the thermal intervals of stability and also the thermodynamic effects that accompany them.
Processes as water or hydrochloric acid elimination as well as oxidative degradation of the organic ligand were observed.
Complexes display a different thermal behaviour as result of dissimilar chemical interaction of metal ions with chloride anions.
The final product of decomposition was metal(II) oxide as powder X-ray diffraction indicated. 相似文献
86.
Mihaela Badea Rodica Olar Valentina Uivarosi Dana Marinescu Victoria Aldea Stefania Felicia Barbuceanu George Mihai Nitulescu 《Journal of Thermal Analysis and Calorimetry》2011,105(2):559-564
Two new complexes having general formula VOL2·nH2O [(1) L: 5-hydroxyflavone, n = 1; (2) L: chrysin, n = 4] were synthesized and characterized. Based on IR and electronic data we concluded that studied flavones act as bidentate
ligands in complexes with metallic ion coordinated in a square-pyramidal stereochemistry. The thermal analysis (TG, DTA) elucidated
the composition and also the number and nature of the water molecules. The thermal behavior also indicated strong interactions
between oxovanadium (IV) and these oxygen donor ligands. 相似文献
87.
We introduce a new class of Picard operators which includes the class of enriched contractions, enriched Kannan mappings, enriched Chatterjea mappings, and prove some fixed point theorems for these mappings. Some examples will illustrate the generality of our results.
相似文献88.
Glycans, as the most peripheral cell surface components, are the primary candidates to mediate the initial steps of cell recognition and adhesion via glycan–glycan binding. This molecular mechanism was quantitatively demonstrated by biochemical and biophysical measurements at the cellular and molecular level for the glyconectin 1 β-d-GlcpNAc3S-(1→3)-α-l-Fucp glycan structure (GN1). The use of adhesion blocking monoclonal antibody Block 2 that specifically recognize this epitope showed that, besides Porifera, human colon carcinoma also express this structure in the apical glycocalyx. Here we report that Block 2 selectively immune-precipitate a Mr 580 × 103 (g580) acidic non-glycosaminoglycan glycan from the total protein-free glycans of Lytechinus pictus sea urchin hatched blastula embryos. Immuno-fluorescence confocal light microscopy and immunogold electron microscopy localized the GN1 structure in the apical lamina glycocalyx attachments of ectodermal cells microvilli, and in the Golgi complex. Biochemical and immune-chemical analyses showed that the g580 glycan is carrying about 200 copies of the GN1 epitope. This highly polyvalent g580 glycan is one of the major components of the glycocalyx structure, maximally expressed at hatched blastula and gastrula. The involvement of g580 GN1 epitope in hatched blastula cell adhesion was demonstrated by: (1) enhancement of cell aggregation by g580 and sponge g200 glycans, (2) inhibition of cell reaggregation by Block 2, (3) dissociation of microvilli from the apical lamina matrix by the loss of its gel-like structure resulting in a change of the blastula embryonal form and consequent inhibition of gastrulation at saturating concentration of Block 2, and (4) aggregation of beads coated with the immune-purified g580 protein-free glycan. These results, together with the previous atomic force microscopy measurements of GN1 binding strength, indicated that this highly polyvalent and calcium ion dependent glycan–glycan binding can provide the force of 40 nanonewtons per single ectodermal cell association of microvilli with the apical lamina, and conservation of glycocalyx gel-like structure. This force can hold the weight of 160,000 cells in sea water, thus it is sufficient to establish, maintain and preserve blastula form after hatching, and prior to the complete formation of further stabilizing basal lamina. 相似文献
89.
We describe here a simple set-up for X-ray diffraction under high pressure using a diamond anvil cell employing a sealed tube. The set-up works in angular dispersive geometry and is built using rather common components that are available in a research laboratory. We show that using this set-up one can routinely acquire good-quality data for the determination of structural properties under pressure and the equations of state. Technical details are presented along with examples of experimental results for sodium chloride and LiV2O4. 相似文献
90.
Abdul Aleem Jamali Bernd Witzigmann Rodica Morarescu Thomas Baumert Frank Träger Frank Hubenthal 《Applied Physics A: Materials Science & Processing》2013,110(4):743-749
In this contribution we present recent experimental and theoretical results on local near-field assisted laser ablation. Along these lines, we have generated sub-diffraction sized nanostructures on fused silica substrates, exploiting the local near fields of highly ordered triangular gold nanoparticle arrays generated by nanosphere lithography. After preparation, the nanoparticle arrays were irradiated with a single 35 fs long laser pulse with a central wavelength of λ=790 nm. The pulse energy was set to E=3.9 μJ, resulting in a fluence well below the ablation threshold of the fused silica substrates. In addition, 3D electromagnetic simulations using a finite integration technique in time domain have been performed. The simulations demonstrate that indeed the local field in the vicinity of the tips of the triangular nanoparticles overcome the ablation threshold and easily explain the generated nanostructures. Most importantly, the simulations show, that higher order modes contribute to the ablation process. These modes cause ablation along the side edges of the nanoparticles. Finally, we demonstrate, that the optical properties of the triangular nanoparticles, which can be tuned by their morphology, are crucial parameters for the generation of the ablation structures. 相似文献