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21.
From readily available allylamine, aldehyde and isocyanoacetamide, a three-component reaction followed by a Pummerer cyclization provided tetracyclic ring systems (6-7-5-6 and 6-6-5-6) in excellent overall yields. 相似文献
22.
Rocio Gonzalez-Diaz Javier Lamar Ronald Umble 《Foundations of Computational Mathematics》2014,14(4):721-744
Let \(I=(\mathbb {Z}^3,26,6,B)\) be a three-dimensional (3D) digital image, let \(Q(I)\) be an associated cubical complex, and let \(\partial Q(I)\) be a subcomplex of \(Q(I)\) whose maximal cells are the quadrangles of \(Q(I)\) shared by a voxel of \(B\) in the foreground—the object under study—and by a voxel of \(\mathbb {Z}^3\backslash B\) in the background—the ambient space. We show how to simplify the combinatorial structure of \(\partial Q(I)\) and obtain a 3D polyhedral complex \(P(I)\) homeomorphic to \(\partial Q(I)\) but with fewer cells. We introduce an algorithm that computes cup products in \(H^*(P(I);\mathbb {Z}_2)\) directly from the combinatorics. The computational method introduced here can be effectively applied to any polyhedral complex embedded in \(\mathbb {R}^3\) . 相似文献
23.
Haloacetic acids (HAAs) are by-products of the chlorination of drinking water containing natural organic matter and bromide. A simple and sensitive method has been developed for determination of ten HAAs in drinking water. The pressure-assisted electrokinetic injection (PAEKI), an on-line enrichment technique, was employed to introduce the sample into a capillary electrophoresis (CE)–electrospray ionization–tandem mass spectrometry system (ESI-MS/MS). HAAs were monitored in selected reaction monitoring mode. With 3 min of PAEKI time, the ten major HAAs (HAA10) in drinking water were enriched up to 20,000-fold into the capillary without compromising resolution. A simple solid phase clean-up method has been developed to eliminate the influence of ionic matrices from drinking water on PAEKI. Under conditions optimized for mass spectrometry, PAEKI and capillary electrophoresis, detection limits defined as three times ratio of signal to noise have been achieved in a range of 0.013–0.12 μg L−1 for ten HAAs in water sample. The overall recoveries for all ten HAAs in drinking water samples were between 76 and 125%. Six HAAs including monochloro- (MCAA), dichloro- (DCAA), trichloro- (TCAA), monobromo- (MBAA), bromochloro- (BCAA), and bromodichloroacetic acids (BDCAA) were found in tap water samples collected. 相似文献
24.
Guo X Ortiz RP Zheng Y Hu Y Noh YY Baeg KJ Facchetti A Marks TJ 《Journal of the American Chemical Society》2011,133(5):1405-1418
Developing new high-mobility polymeric semiconductors with good processability and excellent device environmental stability is essential for organic electronics. We report the synthesis, characterization, manipulation of charge carrier polarity, and device air stability of a new series of bithiophene-imide (BTI)-based polymers for organic field-effect transistors (OFETs). By increasing the conjugation length of the donor comonomer unit from monothiophene (P1) to bithiophene (P2) to tetrathiophene (P3), the electron transport capacity decreases while the hole transport capacity increases. Compared to the BTI homopolymer P(BTimR) having an electron mobility of 10(-2) cm(2) V(-1) s(-1), copolymer P1 is ambipolar with balanced hole and electron mobilities of ~10(-4) cm(2) V(-1) s(-1), while P2 and P3 exhibit hole mobilities of ~10(-3) and ~10(-2) cm(2) V(-1) s(-1), respectively. The influence of P(BTimR) homopolymer M(n) on film morphology and device performance was also investigated. The high M(n) batch P(BTimR)-H affords more crystalline film microstructures; hence, 3× increased electron mobility (0.038 cm(2) V(-1) s(-1)) over the low M(n) one P(BTimR)-L (0.011 cm(2) V(-1) s(-1)). In a top-gate/bottom-contact OFET architecture, P(BTimR)-H achieves a high electron mobility of 0.14 cm(2) V(-1) s(-1), only slightly lower than that of state-of-the-art n-type polymer semiconductors. However, the high-lying P(BTimR)-H LUMO results in minimal electron transport on exposure to ambient. Copolymer P3 exhibits a hole mobility approaching 0.1 cm(2) V(-1) s(-1) in top-gate OFETs, comparable to or slightly lower than current state-of-the-art p-type polymer semiconductors (0.1-0.6 cm(2) V(-1) s(-1)). Although BTI building block incorporation does not enable air-stable n-type OFET performance for P(BTimR) or P1, it significantly increases the OFET air stability for p-type P2 and P3. Bottom-gate/top-contact and top-gate/bottom-contact P2 and P3 OFETs exhibit excellent stability in the ambient. Thus, P2 and P3 OFET hole mobilities are almost unchanged after 200 days under ambient, which is attributed to their low-lying HOMOs (>0.2 eV lower than that of P3HT), induced by the strong BTI electron-withdrawing capacity. Complementary inverters were fabricated by inkjet patterning of P(BTimR)-H (n-type) and P3b (p-type). 相似文献
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Proton Transport in a Highly Conductive Porous Zirconium‐Based Metal–Organic Framework: Molecular Insight
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Dr. Daiane Damasceno Borges Dr. Sabine Devautour‐Vinot Dr. Hervé Jobic Dr. Jacques Ollivier Dr. Farid Nouar Dr. Rocio Semino Dr. Thomas Devic Dr. Christian Serre Prof. Francesco Paesani Prof. Guillaume Maurin 《Angewandte Chemie (International ed. in English)》2016,55(12):3919-3924
The water stable UiO‐66(Zr)‐(CO2H)2 MOF exhibits a superprotonic conductivity of 2.3×10?3 S cm?1 at 90 °C and 95 % relative humidity. Quasi‐elastic neutron scattering measurements combined with aMS‐EVB3 molecular dynamics simulations were able to probe individually the dynamics of both confined protons and water molecules and to further reveal that the proton transport is assisted by the formation of a hydrogen‐bonded water network that spans from the tetrahedral to the octahedral cages of this MOF. This is the first joint experimental/modeling study that unambiguously elucidates the proton‐conduction mechanism at the molecular level in a highly conductive MOF. 相似文献
28.
Arianna Melillo Rocio García-Aboal Dr. Sergio Navalón Dr. Pedro Atienzar Dr. Belén Ferrer Prof. Dr. Mercedes Álvaro Prof. Dr. Hermenegildo García 《Chemphyschem》2021,22(9):842-848
Solid-state photovoltaic cells based on robust metal-organic frameworks (MOFs), MIL-125(Ti), MIL-125(Ti)-NH2, UiO-67, Ru(bpy)2-UiO-67, (bpy 2,2‘-bipyridine) as active components and spiro-MeOTAD (MeOTAD 2,2‘,7,7‘-tetrakis[N,N-di(p-methoxyphenyl)amino]-9,9′-spirobifluorene) as hole transporting layer have been prepared., The photovoltaic response of this material increases in the presence of bathochromic −NH2 groups on the linker or Ru (II) polypyridyl complexes light harvester. These results show that the strategies typically employed in photocatalysis to enhance the photocatalytic activity of MOFs can also be applied in the field of photovoltaic devices. 相似文献
29.
Ibarra-Rivera TR Gámez-Montaño R Miranda LD 《Chemical communications (Cambridge, England)》2007,(33):3485-3487
An efficient xanthate-based method for the preparation of azaspirocyclic cyclohexadienones via an ipso oxidative radical cyclization of p-oxygenated N-benzylacetamides and N-phenetylacetamide is described. 相似文献
30.
Yongqiang Shi Dr. Han Guo Jiachen Huang Xianhe Zhang Ziang Wu Dr. Kun Yang Yujie Zhang Dr. Kui Feng Prof. Han Young Woo Prof. Rocio Ponce Ortiz Prof. Ming Zhou Prof. Xugang Guo 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(34):14557-14565
A distannylated electron-deficient bithiophene imide (BTI-Tin) monomer was synthesized and polymerized with imide-functionalized co-units to afford homopolymer PBTI and copolymer P(BTI-BTI2), both featuring an acceptor–acceptor backbone with high molecular weight. Both polymers exhibited excellent unipolar n-type character in transistors with electron mobility up to 2.60 cm2 V−1 s−1. When applied as acceptor materials in all-polymer solar cells, PBTI and P(BTI-BTI2) achieved high power-conversion efficiency (PCE) of 6.67 % and 8.61 %, respectively. The PCE (6.67 %) of polymer PBTI, synthesized from the distannylated monomer, is much higher than that (0.14 %) of the same polymer PBTI*, synthesized from typical dibrominated monomer. The 8.61 % PCE of copolymer P(BTI-BTI2) is also higher than those (<1 %) of homopolymers synthesized from dibrominated monomers. The results demonstrate the success of BTI-Tin for accessing n-type polymers with greatly improved device performance. 相似文献