Climbing Mount Scalable: Physical Resource Requirements for a Scalable Quantum Computer

The primary resource for quantum computation is Hilbert-space dimension. Whereas Hilbert space itself is an abstract construction, the number of dimensions available to a system is a physical quantity that requires physical resources. Avoiding a demand for an exponential amount of these resources places a fundamental constraint on the systems that are suitable for scalable quantum computation. To be scalable, the effective number of degrees of freedom in the computer must grow nearly linearly with the number of qubits in an equivalent qubit-based quantum computer.     

UV curing of a novel resin derived from poly(ethylene terephthalate)

The synthesis and characterization of photopolymerizable unsaturated polyester resins based on PET waste are described. The resins came from a depolymerization process based on the glycolysis of PET by diethylene glycol (DEG). Different molecular weights of glycolysates were synthesized. Then, the latter was functionalized by a methyl hemiester of maleic acid to obtain unsatured α,ω‐bismaleate PET oligomers. In the presence of an electron donor monomer, such as triethylene glycol divinyl ether, these electron acceptor oligomers were copolymerized by way of charge‐transfer complexes under UV irradiation. The reaction was monitored in situ by real‐time IR spectroscopy to study the kinetics of photopolymerization. This one was studied in relation with the physical and chemical characteristics of oligoesters and the composition of mixtures containing divinyl ethers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1324–1335, 2007     

An iterative procedure for differential analysis of gene expression

Microarrays are a popular technology to study genes that are differentially expressed between two conditions. In this Note, we propose an iterative procedure to determine the biggest subset of non-differentially expressed genes. We prove a pseudo Markov relationship that allows practical computations. We obtain explicit expressions for FDR and the level of the proposed test at each step. To cite this article: A. Bar-Hen, S. Robin, C. R. Acad. Sci. Paris, Ser. I 337 (2003).     

Generalized Rotation numbers

A rooted graph is a pair (G,x), where G is a simple undirected graph and x ∈ V(G). If G is rooted at x, its kth rotation number h_k (G,x) is the minimum number of edges in a graph F of order |G| + k such that for every v ∈ V(F) we can find a copy of G in F with the root vertex x at v. When k = 0, this definition reduces to that of the rotation number h(G,x), which was introduced in [“On Rotation Numbers for Complete Bipartite Graphs,” University of Victoria, Department of Mathematics Report No. DM-186-IR (1979)] by E.J. Cockayne and P.J. Lorimer and subsequently calculated for complete multipartite graphs. In this paper, we estimate the kth rotation number for complete bipartite graphs G with root x in the larger vertex class, thereby generalizing results of B. Bollobás and E.J. Cockayne [“More Rotation Numbers for Complete Bipartite Graphs,” Journal of Graph Theory, Vol. 6 (1982), pp. 403–411], J. Haviland [“Cliques and Independent Sets,” Ph. D. thesis, University of Cambridge (1989)], and J. Haviland and A. Thomason [“Rotation Numbers for Complete Bipartite Graphs,” Journal of Graph Theory, Vol. 16 (1992), pp. 61–71]. © 1993 John Wiley & Sons, Inc.     

Particle production from signature change

We consider the (massless) scalar field on 2-dimensional manifolds whose metric changes signature and which admit a spacelike isometry. Choosing the wave equation so that there will be a conserved Klein-Gordon product implicitly determines the junction conditions one needs to impose in order to obtain global solutions. The resulting mix of positive and negative frequencies produced by the presence of Euclidean regions depends only on the total width of the regions, and not on the detailed form of the metric.This essay received honorable mention in the 1991 competition of the Gravity Research Foundation.     

Anticancer agent development: X-ray crystal structure and keto-enol tautomerism of dimethyl 1-hydroxy-6,7-methylenedioxy-4-(3′,4′,5′-trimethoxyphenyl-trans-3,4-dihydronaphthalene-2,3-dicarboxylate

Structural and conformational information obtained from the crystal structure and solution¹H nmr investigations of the title compound are compared. The 4-aryltetralone, C₂₄H₂₄O₁₀, crystallizes as a chloroform solvate in the monoclinic space group, P2₁/n, witha=12.519(4),b=17.938(6),c=12.534(9)Å,=111.90(5)°, and D_calc=1.51 g cm^–3 forZ=4. The data for this compound were collected at –150°C. Least-squares refinement of 2796 observed [F _o5(F _o)] reflections led to the final agreement index ofR=0.062. A threefold static disorder was observed for one of the carboxyl groups. The second carboxyl group participates in an intramolecular hydrogen bond and is thus ordered. The¹H nmr spectrum revealed the title compound to exist as a keto-enol tautomeric mixture in solution. Vicinal hydrogen coupling constant analysis proved reliable in ascertaining B-ring stereochemistry of 2,3-disubstituted-4-aryltetralones.     

Gas-phase electron diffraction determination of the molecular structure of perfluoro(methyloxirane)

The molecular geometry of perfluoro(methyloxirane) has been studied using gas-phase electron diffraction data, effective least-squares refinement of the structure being achieved with the aid of constraints to limit the number of variable parameters. With the CCF₃ bond constrained to be 0.078 Å longer than the ring CC, the refined bond- length values CF (av.) = 1.323(2), CO (av.) = 1.410(8), and CC (ring) = 1.467(7) Å ($\text{r}$_g values, with e.s.d. in parentheses) were obtained; the angles between ring bonds and substituent CF bonds were CCF (av.) 121(1) and OCF (av.) 114(1)^o, the corresponding parameters involving the bulkier CCF₃ fragment being larger by 3^o in each case [∠CCCF₃ 124(1)^o∠OCCF₃ 117(2)^o]. The remaining refined parameters were ∠CCF(of CF₃) = 110.6(4)^o and τ , a torsion angle defining the orientation of the CF bonds of the CF₃ group with respect to ring bonds, = 29(2)^o. Dependent bond angles possessed the values 62.7 (COC), 58.7 [OCC (ring)], 108.3 [FCF (CF₃ group)], 114 [FCF (ring CF₂)], and 111^o (FCCF₃).