Rheologische Messungen an Kunststoff-Schmelzen mit einem neuen Rotationsrheometer

Zusammenfassung In der vorliegenden Arbeit wird ein neues Rotationsrheometer vorgestellt und über Messungen an zwei Polymethylmethacrylat-Formmassen berichtet. Bei dem Rheometer handelt es sich um ein Couette-Rheometer mit feststehendem Innenzylinder als Meßkörper. Der Meßkörper ist beidseitig eingespannt. In dem geschlossenen Meßraum können die Schmelzen bis zu einem Druck von 500 bar belastet werden.Der zeitliche Verlauf der Schubspannung in den Schmelzen wird in Abhängigkeit von Temperatur und Druck aufgezeichnet.

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Summary A new type of rotational rheometer is described, and results for two samples of polymethylmethacrylate are reported. The rheometer consists of a Couette system with fixed inner cylinder, supported at both ends for torque measurements. Pressure may be varied up to 500 bar. Shear stresses have been recorded as a function of time, temperature and pressure.

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Nomenklatur C [kp cm^–2 s^–1] Steigung der Anlaufkurve im Nullpunkt - D [kp cm rad^–1] Direktionsmoment - E ₀ [kcal mol^–1] Aktivierungsenergie der Newtonschen Viskosität - G [kp cm^–2] Schubmodul - G [—] Griffith-Zahl - l [mm] Länge des Meßkörpers - p [kp cm^–2] Druck - R _i [mm] Radius des Innenzylinders - R _a [mm] Radius des Außenzylinders - t _max [s] Zeit, bei der das Maximum in der Anlaufkurve auftritt - T [°C] Temperatur - ₀ [cm² kp^–1] Druckkoeffizient der Newtonschen Viskosität - [s^–1] Schergeschwindigkeit - ₀ [kp s cm^–2] Newtonsche Viskosität - (g cm²] Trägheitsmoment des Meßkörpers - v ₀ [s^–1] Eigenfrequenz des Meßsystems - _max [kp cm^–2] maximale Schubspannung - _st [kp cm^–2] stationäre Schubspannung Mit 7 Abbildungen und 1 Tabelle     

Gas flow in cylindrical capillaries under intermediate conditions

At present, there are sufficient solutions of the problem of free-molecular gas flow through a short cylindrical channel, for example, [1–3]. In intermediate flow conditions, for Knudsen number Kn 1, solutions have been obtained for the limiting cases: an infinitely long channel [4] and a channel of zero length (an aperture) [5]. However, no solution is known for short channels for Kn 1. The present work reports a calculation by the Monte Carlo method of the macroscopic characteristics of the gas flow through a short cylindrical channel (for various length—radius ratios), taking into account intermolecular collisions.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 1, pp. 187–190, January–February, 1977.     

On deformations of cracked anisotropic slabs

The effect of a crack on the bending and shearing of an anisotropic elastic slab is considered. The problems considered are reduced to simultaneous Fredholm equations which may be solved numerically.     

Unsteady state diffusion of vapour in a closed tube

Results of one-dimensional calculations for unsteady state diffusion of a vapour in a closed tube are compared to calculations (a) for unsteady state diffusion of a vapour in an open tube, and (b) for heat conduction in a finite slab and an infinite slab. In the cases of (b) the effect of the convective term in the transport equation is absent.The total pressure is calculated and differences in the two cases are explained.An experiment is described in which the pressure increase in a closed tube due to the diffusion of water vapour in dry air is measured as a function of time. The experimental results agree quite well with the theoretical predictions. The results of this investigation may be used for the experimental determination of the diffusion coefficient of a vapour in a gas and in pressure measurements in systems with an evaporating liquid.Nomenclature a thermal diffusivity - D diffusion coefficient - w mean particle velocity - g particle flux in the laboratory system - g* particle flux in a system moving with the mean particle velocity w - L length of the tube - n number density of molecules - n _vs saturation number density of vapour molecules - p pressure - p _vs saturation pressure of the vapour - t time - z distance from the liquid surface - N total quantity of evaporated liquid     

Limiting viscosity of ferromagnetic suspensions in a strong magnetic field

The effective viscosity of a suspension of ferromagnetic particles with anisotropy of the “easy-axis” type is calculated. The case considered is that in which the magnetic field in which the suspension is flowing greatly exceeds the internal anisotropy field, and the concept of the “frozen” magnetic moments of the particles is inapplicable. The relationship between the viscosity and the anisotropy field is established. The question as to the magnitude of the viscosity for an arbitrary ratio of the internal and external fields is discussed.     

Combined influence of the Reynolds number and localised wall suction on a turbulent boundary layer

This paper considers the effect the Reynolds number has on a turbulent boundary layer that is subjected to concentrated suction, applied through a short porous wall strip. The response of the skin friction coefficient to suction is strongly modulated by the momentum thickness Reynolds number R ₀. The magnitude and wavelength of the variation of the skin friction decrease as R ₀ increases. Measurements clearly show that it is the combination of R ₀ and the suction rate that controls the boundary layer response. Relaminarisation of the near-wall flow, which occurs just downstream of the suction strip when =5.5 and R ₀=660, could not be achieved at higher Reynolds numbers. It is suggested that the ratio R ₀/ should not exceed a (as yet undetermined) critical value if pseudo-relaminarisation is to occur. The mean velocity profiles differ from the undisturbed profile for all the values of R ₀ and considered here. Although the redistribution of the turbulent kinetic energy among the normal Reynolds stresses is affected by , a variation in R ₀ does not appear to alter the effect of on this redistribution.     

Continuum theory of dislocations revisited

The paper continues the discussion of continuum theory of dislocations suggested by Berdichevsky and Sedov (PMM 31(6): 981–1000, 1967). The major new points are: the choice of energy, the variational form of the governing dynamical equations, the variational principle for the final plastic state.     

On an analytic solution in the theory of large elastoviscoplastic strains

Analytic solutions for motions of viscoplastic media under pressure drop [1, 2] have become classical. They have served for the progress in the theory and as a necessary tool for testing numerical methods for problems with unknown boundaries (the boundaries of rigid cores and stagnation regions). In the present paper, we essentially generalize these solutions to the case in which one cannot neglect elastic properties. It turns out that the assumption that the medium is incompressible permits obtaining the analytic solution with large strains taken into account, while without this assumption the analytic solution cannot be obtained even for small strains in elastic strain regions.     

A criterion for the onset of growth of two shear cracks in an elastic body under plane-strain conditions

The Wiener-Hopf method is used to find a solution to a symmetric problem that gives a criterion for the onset of growth of long shear cracks emanating from a corner point on the boundary of a hole and filled with a plastic material __________ Translated from Prikladnaya Mekhanika, Vol. 42, No. 4, pp. 83–90, April 2006.