全文获取类型
收费全文 | 1312篇 |
免费 | 49篇 |
国内免费 | 3篇 |
专业分类
化学 | 1018篇 |
晶体学 | 3篇 |
力学 | 43篇 |
数学 | 146篇 |
物理学 | 154篇 |
出版年
2023年 | 8篇 |
2022年 | 28篇 |
2021年 | 47篇 |
2020年 | 22篇 |
2019年 | 21篇 |
2018年 | 23篇 |
2017年 | 16篇 |
2016年 | 39篇 |
2015年 | 38篇 |
2014年 | 39篇 |
2013年 | 97篇 |
2012年 | 113篇 |
2011年 | 87篇 |
2010年 | 43篇 |
2009年 | 49篇 |
2008年 | 69篇 |
2007年 | 66篇 |
2006年 | 64篇 |
2005年 | 52篇 |
2004年 | 54篇 |
2003年 | 54篇 |
2002年 | 48篇 |
2001年 | 9篇 |
2000年 | 9篇 |
1999年 | 16篇 |
1998年 | 4篇 |
1997年 | 4篇 |
1996年 | 29篇 |
1995年 | 12篇 |
1994年 | 22篇 |
1993年 | 10篇 |
1992年 | 20篇 |
1990年 | 4篇 |
1989年 | 7篇 |
1988年 | 4篇 |
1987年 | 9篇 |
1985年 | 10篇 |
1983年 | 4篇 |
1981年 | 6篇 |
1980年 | 6篇 |
1979年 | 4篇 |
1978年 | 7篇 |
1977年 | 4篇 |
1976年 | 11篇 |
1975年 | 8篇 |
1974年 | 7篇 |
1973年 | 7篇 |
1972年 | 9篇 |
1968年 | 3篇 |
1967年 | 3篇 |
排序方式: 共有1364条查询结果,搜索用时 15 毫秒
51.
52.
Javier Illescas Mariano Casu Valeria Alzari Daniele Nuvoli Mariano Andrea Scorciapino Roberta Sanna Vanna Sanna Alberto Mariani 《Journal of polymer science. Part A, Polymer chemistry》2014,52(24):3521-3532
A new series of linear and crosslinked copolymers, obtained from 3‐octyl‐1‐vinylimidazolium bromide (VImBr) and N‐isopropylacrylamide (NIPAAm), were prepared by radical polymerization. Namely, VImBr was synthesized from 1‐bromooctane and an ionic liquid such as 1‐vinylimidazole. NIPAAm was used because it gives raise to well known thermoresponsive (co‐)polymers. The copolymers were thoroughly characterized by means of 1H NMR and 13C NMR spectroscopies. Besides, differential scanning calorimetry, Fourier transform infrared spectroscopy, and scanning electron microscopy were also used. Moreover, the swelling behavior and the thermoresponsive properties of the corresponding hydrogels were studied. It was found that the VImBr incorporation into the copolymers does have a dramatic influence on both the thermal properties of the dried materials and the lower critical solution temperature of the corresponding hydrogels. In detail, the glass transition temperature was dependent on the monomer ratios, and ranged from 5 to 155 °C. Analogously, the lower critical solution temperature of the resulting hydrogels ranged from less than 10 up to 38 °C, thus including the physiological temperature. NMR spectroscopies, which were performed on the linear polymers, indicated that the monomers exhibit an alternating tendency resulting in a microstructure in which blocks are not present, at least when the two monomers are in equimolar amounts. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 3521–3532 相似文献
53.
Eva Lucaccini Matteo Briganti Dr. Mauro Perfetti Dr. Laure Vendier Dr. Jean‐Pierre Costes Dr. Federico Totti Prof. Dr. Roberta Sessoli Prof. Dr. Lorenzo Sorace 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(16):5552-5562
The magnetic behaviour of a Dy(LH)3 complex (LH? is the anion of 2‐hydroxy‐N′‐[(E)‐(2‐hydroxy‐3‐methoxyphenyl)methylidene]benzhydrazide) was analysed in depth from both theoretical and experimental points of view. Cantilever torque magnetometry indicated that the complex has Ising‐type anisotropy, and provided two possible directions for the easy axis of anisotropy due to the presence of two magnetically non‐equivalent molecules in the crystal. Ab initio calculations confirmed the strong Ising‐type anisotropy and disentangled the two possible orientations. The computed results obtained by using ab initio calculations were then used to rationalise the composite dynamic behaviour observed for both pure DyIII phase and YIII diluted phase, which showed two different relaxation channels in zero and non‐zero static magnetic fields. In particular, we showed that the relaxation behaviour at the higher temperature range can be correctly reproduced by using a master matrix approach, which suggests that Orbach relaxation is occurring through a second excited doublet. 相似文献
54.
55.
56.
57.
Structural and Dynamic Characterization of the Molecular Hub Early Region 1A (E1A) from Human Adenovirus 下载免费PDF全文
Marcela Oliveira Nogueira Michele Salvi Dr. Talita Duarte Pagani Prof. Isabella C. Felli Prof. Roberta Pierattelli 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(37):13010-13013
The small‐DNA human adenovirus encodes one of the most versatile molecular hubs, the E1A protein. This protein is essential for productive viral infection in human cells and a vast amount of biologically relevant data are available on its interactions with host proteins. Up to now, however, no high‐resolution structural and dynamic information on E1A is available despite its important biological role. Among the different spliced variants of E1A, two are expressed at high level in the early stage of infection. These are 243 and 289 residues isoforms. Herein, we present their NMR characterization, showing that they are both highly disordered, but also demonstrate a certain heterogeneous behavior in terms of structural and dynamic properties. Furthermore, we present the characterization of the isolated domain of the longer variant, known as CR3. This study opens the way to understanding at the molecular level how E1A functions. 相似文献
58.
Alfred Schmidpeter Angela Willhalm Jürgen Kroner Roberta O. Day Joan M. Holmes Robert R. Holmes 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-2):495-498
Abstract Phosphamethincyanines prepared in 1964 by Dimroth and Hoffmann were among the first compounds with two-coordinate phosphorus. They are special cases of 2-phospha-allylic cations. Simple representatives of this type become available from the reaction of imidoyl chlorides with tris(trimethylsily1)phosphane. 相似文献
59.
60.
Dr. Roberta Pievo Brigitta Angerstein Dr. Alistair J. Fielding Dr. Christian Koch Prof. Dr. Ivo Feussner Prof. Dr. Marina Bennati 《Chemphyschem》2013,14(18):4094-4101
Electron paramagnetic resonance (EPR) spectroscopy in combination with the rapid freeze‐quench (RFQ) technique is a well‐established method to trap and characterize intermediates in chemical or enzymatic reactions at the millisecond or even shorter time scales. The method is particularly powerful for mechanistic studies of enzymatic reactions when combined with high‐frequency EPR (ν≥90 GHz), which permits the identification of substrate or protein radical intermediates by their electronic g values. In this work, we describe a new custom‐designed micro‐mix rapid freeze‐quench apparatus, for which reagent volumes for biological samples as small as 20 μL are required. The apparatus was implemented with homemade sample collectors appropriate for 9, 34, and 94 GHz EPR capillaries (4, 2, and 0.87 mm outer diameter, respectively) and the performance was evaluated. We demonstrate the application potential of the RFQ apparatus by following the enzymatic reaction of PpoA, a fungal dioxygenase producing hydro(pero)xylated fatty acids. The larger spectral resolution at 94 GHz allows the discernment of structural changes in the EPR spectra, which are not detectable in the same samples at the standard 9 GHz frequency. 相似文献