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21.
Robert Muencke 《Fresenius' Journal of Analytical Chemistry》1885,24(1):242
Ohne Zusammenfassung 相似文献
22.
Robert Jerrard Alberto Montero Peter Sternberg 《Communications in Mathematical Physics》2004,249(3):549-577
We establish the existence of locally minimizing vortex solutions to the full Ginzburg-Landau energy in three dimensional simply-connected domains with or without the presence of an applied magnetic field. The approach is based upon the theory of weak Jacobians and applies to nonconvex sample geometries for which there exists a configuration of locally shortest line segments with endpoints on the boundary.Research partially supported by NSERC grant number 261955 相似文献
23.
24.
Robert R. Gamache Jean-Michel Hartmann 《Journal of Quantitative Spectroscopy & Radiative Transfer》2004,83(2):119-147
A complex semiclassical model for the calculation of line widths and shifts of H2O broadened by N2, derived from the Robert and Bonamy approach, is tested by comparisons with measurements for selected transitions in various vibrational bands. The lines retained, which involve rotational states with Kc=J or J−1 have been chosen for two reasons. The first is that they show large variations of the widths with J and thus enable a severe test of the model. The second is that, as explained in this paper, they are well-suited for the study of the effects of vibration on the collisional parameters. The measured values have been extracted from an updated version of a database built years ago (JQSRT 52 (1994) 481) that contains all available measurements. Comparisons between experimental and calculated widths and shifts at room temperature illustrate the quality of the model and clearly demonstrate, for the first time, that there is a vibrational dependence of the broadening. Values of collisional parameters are first studied in fundamental bands. This shows that the theoretical approach accounts for most of the dependence of broadening and shifting on rotational quantum numbers: the variations of γ, which reach a factor of nearly 20 from low to high J values, are correctly accounted for by the model as are some specific features of the shifts δ. Analysis confirms that the bending and stretching vibrations have significantly different effects on δ, due to the vibrational dependence of the intermolecular potential. On the other hand, differences on the widths are rather small with slightly smaller broadening for lines of the bending band. Calculations show that there is a spectroscopic effect, due to the larger rotational constant A in the v2=1 state. Calculations made for overtone bands involving numerous quanta of the stretching vibration are then presented. They predict that a significant dependence of the width should be observed for high J lines due to the effect of vibration on the interaction potential. This is confirmed by comparisons with measurements for lines involving a change of three and four quanta of stretching vibration. 相似文献
25.
Mingbao Zhang Raymond Reeves Cheng Bi Robert Dally Gaetan Ladouceur William Bullock Jefferson Chin 《Tetrahedron letters》2004,45(27):5229-5231
Three novel, optically active, 6-substituted 2-(aminomethyl)chromans were synthesized from readily available chroman 2-carboxylic acid precursors. These chroman-containing primary amines are useful building blocks for the synthesis of chroman-derived pharmaceutical agents. 相似文献
26.
Thorsten Brand Kyle Ratinac Jeffrey V. Castro Robert G. Gilbert 《Journal of polymer science. Part A, Polymer chemistry》2004,42(22):5706-5713
A method was developed for free‐radical polymerization in the confines of a hollow latex particle. Hollow particles were prepared via the dynamic swelling method from polystyrene seed and divinylbenzene and had hollows of 500–1000 nm. So that these hollow poly(divinylbenzene) particles could function as submicrometer reactors, the particles were filled with a monomer (N‐isopropylacrylamide) via the dispersion of the dried particles in the molten monomer. The monomer that was not contained in the hollows was removed by washing and gentle abrasion. Free‐radical polymerization was then initiated by γ radiolysis in the solid state. Transmission electron microscopy showed that poly(N‐isopropylacrylamide) formed in the hollow interior of the particles, which functioned as submicrometer reactors. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5706–5713, 2004 相似文献
27.
A computer construction of the Monster is used to prove thatPSL(2, 59) is a subgroup of the Monster. 相似文献
28.
In this note we show how 1-factors in the middle two layers of the discrete cube can be used to construct 2-factors in the
Odd graph (the Kneser graph of (k − 1)-sets from a (2k − 1)-set). In particular, we use the lexical matchings of Kierstead and Trotter, and the modular matchings of Duffus, Kierstead
and Snevily, to give explicit constructions of two different 2-factorisations of the Odd graph.
This revised version was published online in September 2006 with corrections to the Cover Date. 相似文献
29.
Robert Krauthgamer Nathan Linial Avner Magen 《Discrete and Computational Geometry》2004,31(3):339-356
The extensive study of metric spaces and their embeddings
has so far focused on embeddings that preserve pairwise distances.
A very intriguing concept introduced by Feige
allows us to quantify the extent to which larger
structures are preserved by a given embedding.
We investigate this concept, focusing on several major graph families
such as paths, trees, cubes, and expanders.
We find some similarities to the regular (pairwise) distortion,
as well as some striking differences. 相似文献
30.