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21.
J. M. Rivas Mercury A. A. Cabral A. E. M. Paiva R. S. Angélica R. F. Neves T. Scheller 《Journal of Thermal Analysis and Calorimetry》2011,104(2):635-643
This article studied the thermal behavior and the evolution of the crystalline phases with temperature of the red mud (bauxite tailing) from an aluminum industry at Maranhão, North-Northwestern Brazil. The experiments were carried out by Field Emission Scanning Electron Microscopy (FE-SEM), Simultaneous Thermal Analysis (TG–DSC), Optical Dilatometry up to 1623 K, and X-ray diffraction (XRD) of previously heated samples between 523 and 1523 K. The crystalline phases and the amorphous contents were quantified on raw and heated samples (at 1523 K) according to the Rietveld Quantitative Analysis (RQA) method. The data obtained showed that the raw red mud is composed by a mixture of seven different phases (hematite, goethite, sodalite, anatase, gibbsite, calcite, and amorphous). Finally in the interval of 1023–1523 K the following crystalline phases: hematite, nepheline, sodalite, anatase, perovskite, and pseudobrookite have been observed. 相似文献
22.
23.
Raquel Antón Hercilio Rivas Jean-Louis Salager 《Journal of Dispersion Science and Technology》2013,34(6):553-566
Anionic and nonionic surfactants exhibit opposite changes in hydrophilicity with a change of temperature. This antagonism can be harnessed by the use of mixtures. The phase behavior and emulsion type are mapped on a temperature water-oil/ratio diagram for different anionic-nonionic mixtures. It is shown that the mixing can result in insensitivity to temperature of different kinds of emulsions. 相似文献
24.
In beam measurements have been made of the F colouring curves in NaCl between 20 and 300°C. The first colouring stage has been empirically fitted by up to three exponential components which become smaller and faster with increasing temperature. A model is presented which gives physical significance to the fitting parameters. 相似文献
25.
Unprecedented optical control of the surface plasmon polariton assisted transmission of terahertz radiation through subwavelength apertures is rendered possible by carrier-induced changes to the dielectric properties of a semiconductor grating. Although the study presented is static, the extension of our approach to dynamic switching and tuning is deemed straightforward, opening the way for the realization of ultrafast surface plasmon based devices. 相似文献
26.
Influence of velocity in nanoscale friction processes 总被引:3,自引:0,他引:3
R. Prioli A.M.F. Rivas F.L. Freire Jr. A.O. Caride 《Applied Physics A: Materials Science & Processing》2003,76(4):565-569
Force-microscopy images of boric acid crystals were obtained experimentally and simulated with the use of a two-dimensional
mechanical model. An analysis of the stick and slip movement of the microscope tip shows that the energy-dissipation mechanism
is strongly influenced by the non-linear dynamics of the sliding system. The contributions of stick and viscous forces on
the energy dissipation (or friction forces) are studied as a function of the relative scanning velocity. At low relative velocities,
the stick forces are shown to be responsible for the energy dissipation. This energy is velocity-dependent, due to the coupling
between the two degrees of freedom of the sliding system. As the scanning velocity increases the stick forces are damped;
the viscous force is then predominant in the energy-dissipation process.
Received: 30 October 2001 / Accepted: 17 May 2002 / Published online: 22 November 2002
RID="*"
ID="*"Corresponding author. Fax: +55-21/2295-9397, E-mail: prioli@vdg.fis.puc-rio.br 相似文献
27.
Carlos Rodríguez-Abreu Pablo M. Botta José Rivas Kenji Aramaki Manuel Arturo López Quintela 《Journal of Non》2008,354(10-11):1074-1079
The formation of fluorocarbon–silica nanocomposites by the self-assembly of a fluorinated surfactant and aminoalkoxysilane coupling agents was studied by X-ray diffraction, electron microscopy, NMR spectroscopy and thermal analysis. The prepared materials posses a lamellar nanostructure consisting of non-crystalline fluorinated and condensed silica layers, the latter being very thin. The prepared materials show interesting properties for applications, such as hydrophobicity, thermal stability, high content of aminopropyl groups and low dielectric constant (≈2.8), which is almost independent on frequency. Moreover, the dielectric response can be interpreted in the framework of the Maxwell–Wagner model. 相似文献
28.
Francisca Zamora Khalid Hakkou Abdelillah Alla Manuel Rivas Antxón Martínez De Ilarduya Sebastián Muñoz‐Guerra Juan A. Galbis 《Journal of polymer science. Part A, Polymer chemistry》2009,47(4):1168-1177
The synthesis, characterization, and some properties of new copolyesters analogous to poly(butylene terephthalate) (PBT), based on L ‐arabinaric and galactaric acids, are described. These copolyesters were obtained by polycondensation reaction in the melt of mixtures of methyl 2,3,4‐tri‐O‐methyl‐L ‐arabinarate or methyl 2,3,4,5‐tetra‐O‐methyl‐galactarate and dimethyl terephthalate with 1,4‐butanediol. Their weight‐average molecular weights ranged between 10,000 and 34,000, with polydispersities ranging from 1.4 to 2.2. The composition of all the copolymers was analyzed by NMR, and was found to have a statistical microstructure. All these copolyesters were thermally stable, with degradation temperatures well above 300 °C. The melting temperature and crystallinity decreased in both series, and the glass transition temperature increased and decreased respectively, for the PBTGa and PBTAr series with increasing amounts of aldaric units in the copolyester chain. Only PBT‐derived copolyesters containing a maximum of 30% aldaric units showed discrete scattering characteristic of crystalline material. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 1168–1177, 2009 相似文献
29.
30.
Fabiana Gutiérrez Gabriela Ortega José Luis Cabrera María D. Rubianes Gustavo A. Rivas 《Electroanalysis》2010,22(22):2650-2657
This work reports the highly sensitive detection of quercetin using glassy carbon electrodes modified with multiwall carbon nanotubes (MWCNT) dispersed in polyethylenimine and poly(acrylic acid). The adsorptive stripping with square wave voltammetric transduction allowed the detection of 7.5 nM quercetin after 1.0 min accumulation at open circuit potential. The amperometric detection at 0.150 V is reported as an easier and simpler alternative to determine quercetin, with detection limits of 0.2 µM. The careful selection of the working conditions also made possible the detection of submicromolar levels of quercetin in the presence of excess of rutin. The proposed methodology was successfully used to quantify quercetin in onion samples. 相似文献