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51.
Ritu Gupta Jhantu Pradhan Arabinda Haldar Chandrasekhar Murapaka Prakash Chandra Mondal 《Angewandte Chemie (International ed. in English)》2023,62(35):e202307458
The injection of pure spin current into the non-magnetic layer plays a crucial role in transmitting, processing, and storing data information in the realm of spintronics. To understand broadband molecular spintronics, pyrene oligomer film (≈20 nm thickness) was prepared using an electrochemical method forming indium tin oxide (ITO) electrode/pyrene covalent interfaces. Permalloy (Ni80Fe20) films with different nanoscale thicknesses were used as top contact over ITO/pyrene layers to estimate the spin pumping efficiency across the interfaces using broadband ferromagnetic resonance spectra. The spintronic devices are composed of permalloy/pyrene/ITO orthogonal configuration, showing remarkable spin pumping from permalloy to pyrene film. The large spin pumping is evident from the linewidth broadening of 5.4 mT at 9 GHz, which is direct proof of spin angular momentum transfer across the interface. A striking observation is made with the high spin-mixing conductance of ≈1.02×1018 m−2, a value comparable to the conventional heavy metals. Large spin angular moment transfer was observed at the permalloy-pyrene interfaces, especially at the lower thickness of permalloy, indicating a strong spinterface effect. Pure spin current injection from ferromagnetic into electrochemically grown pyrene films ensures efficient broadband spin transport, which opens a new area in molecular broadband spintronics. 相似文献
52.
Jaanus Kruusma Aidan Rhodes Radhika Bhatia J. A. Gareth Williams Adam M. Benham Ritu Kataky 《Journal of solution chemistry》2007,36(4):517-529
Increasing enrichment of dimethyl sulfoxide, DMSO, in DMSO-water mixtures causes a reversal in the thermodynamic dissociation
constants, pK
as, and has a marked effect on the redox potentails of the thiolic and amino groups in cysteine and the protein disulfide isomerase
(PDI) mimic BMC, Vectrase. This paper illustrates the effect of a hydrogen-bonding environment on the ionisation and redox
properties of thiol groups in amino acids. A combination of potentiometry and Raman spectroscopy was applied to rationalise
the observations. Intracellular environments are full of hydrophobic, hydrogen-bonding environments. The results illustrate
the profound effects of the local environment on the thiol group. 相似文献
53.
54.
Das Ritu Dhiman Abhijeet Kapil Arti Bansal Vipul Sharma Tarun Kumar 《Analytical and bioanalytical chemistry》2019,411(6):1229-1238
Analytical and Bioanalytical Chemistry - Despite of various advancements in biosensing, a rapid, accurate, and on-site detection of a bacterial pathogen is a real challenge due to the lack of... 相似文献
55.
Ritu Ahuja Ashoka G. Samuelson 《Journal of polymer science. Part A, Polymer chemistry》2005,43(15):3411-3420
A diphosphinoamine ligand with a polymerizable side chain, (PPh2)2N? CH2? C6H4? CH?CH2 (vbzpnp or 1 ), was synthesized. The ligand could be polymerized by anionic polymerization with n‐butyllithium as the initiator. Polyvbzpnp was soluble in tetrahydrofuran and chloroform but was insoluble in methanol and was characterized with NMR, IR, and gel permeation chromatography. The number‐average and weight‐average molecular weights were 40,050 and 55,690, respectively, and the polydispersity index was 1.39. [Cu(CH3CN)4]ClO4 formed a bischelated complex with the monomer and produced [Cu( 1 )2]ClO4 ( 2 ), and CuCl formed a tetramer, Cu4( 1 )2Cl4 ( 3 ). All the compounds ( 1 , 2 , and 3 ) were characterized with single‐crystal‐structure determination, NMR, and IR spectroscopy. The addition of [Cu(CH3CN)4]ClO4 to polyvbzpnp resulted in an insoluble crosslinked polymer, which was characterized with solid‐state 31P {1H} magic‐angle‐spinning NMR. The copolymerization of styrene and 1 produced a styrene–vbzpnp copolymer that was found to be soluble in common organic solvents. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 3411–3420, 2005 相似文献
56.
The operator equation λM_zX = XM_(zk), for k ≥ 2, λ∈ C, is completely solved.Further, some algebraic and spectral properties of the solutions of the equation are discussed. 相似文献
57.
Bulk heterojunction photovoltaic cells based on composites of copolymer poly [N-90-hepta-decanyl-2,7-carbazole-alt-5,5-(40,70-di-2-thienyl-20,10,30-benzothiadiazole)] and the fullerene derivative [6,6]-phenyl C71-butyric acid methyl ester with an inserted layer of discotic liquid crystalline material (2, 3, 6, 7, 10, 11-hexabutyloxytriphenylene) between the interface of active layer and hole transporting layer has been reported. Different hole transporting layers deposited on indium tin oxide substrates such as poly (3,4-ethylenedioxythiophene)-poly (styrenesulphonate) or molybdenum trioxide has been used in these devices. All the devices with inserted discotic liquid crystal layer showed better performance than the reference cells. Power conversion efficiency of 5.14% was achieved for these photovoltaic solar cells containing self-organised discotic liquid crystal layer of 30 nm thickness under one sun condition which is substantial jump as compared to earlier reports. The mobility of holes in the discotic liquid crystal inserted devices was found to be of the order of 10–6 cm2 V–1 s–1 due to which high values of current density was achieved. The influence of varying the thickness of liquid crystal layer and annealing on the photovoltaic parameters of these devices was also studied. 相似文献
58.
Hurlocker B Abascal NC Repka LM Santizo-Deleon E Smenton AL Baranov V Gupta R Bernard SE Chowdhury S Rojas CM 《The Journal of organic chemistry》2011,76(7):2240-2244
By using (N-tosyloxy)-3-O-carbamoyl-D-glucal 10, which removes the need for a hypervalent iodine(III) oxidant, we provide evidence for rhodium nitrenoid-mediated ipso C-H activation as the origin of a C3-oxidized dihydropyranone product 3. This system may be especially susceptible to such a pathway because of the ease of forming a cation upon hydride transfer to the rhodium-complexed acyl nitrene. 相似文献
59.
The total (elastic + inelastic) cross sections fore
+ impact on alkaline-earth elements from Be to Ra are calculated by employing a complex spherical optical potential. This potential
has static, polarization and absorption components. The positron energy range is from a few eV to several thousand eV. We
have compared our elastic cross sections for Mg and Ca with the other available results and the agreement is good for energies
above 100eV. We have also compared our absorption cross sections withe
− ionization cross sections at high energies where our absorption cross sections are in good accord. We have made Bethe plots
fore
+ scattering on these elements. 相似文献
60.
Relationship among glottal area, static supraglottic compression, and laryngeal function studies in unilateral vocal fold paresis and paralysis 总被引:1,自引:0,他引:1
Steven Bielamowicz Ritu Kapoor Jerome Schwartz Sheila V. Stager 《Journal of voice》2004,18(1):138-145
In this study, we evaluated the relationship between laryngeal function measures and glottal gap ratio and normalized measures of supraglottic behaviors in patients with unilateral vocal fold paresis (UVFP). Thirty-one patients were found to have unilateral vocal fold paresis by videoendoscopy and laryngeal electromyography, and 13 controls participated in this study. Patients with UVFP demonstrated significantly larger glottal gap ratios (p = 0.016) than control subjects. The nonparalyzed or contralateral vocal fold was associated with significantly more static false vocal fold compression (p = 0.03) compared with the paralyzed vocal fold or with the controls. Patients with unilateral vocal fold paresis were divided into subgroups: those with normal or abnormal maximum phonation time, flow, or pressure measures. Smaller glottal gap ratios were identified in patients with normal maximum phonation times and flow measures. Greater false vocal fold activity was identified in unilateral vocal fold paresis patients with normal laryngeal function measures than in unilateral vocal fold paresis patients with abnormal measures. These findings suggest that some patients with documented unilateral paresis and glottal incompetence can compensate for vocal fold weakness such that their acoustic and aerodynamic measures are normal. 相似文献