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441.
442.
A.K. Chauhan D.K. Aswal S.P. Koiry S.K. Gupta J.V. Yakhmi C. Sürgers D. Guerin S. Lenfant D. Vuillaume 《Applied Physics A: Materials Science & Processing》2008,90(3):581-589
We report the deposition of 3-aminopropyltrimethoxysilane (APTMS) multilayers on SiOx/Si(p++) substrates by a layer-by-layer self-assembly process. The multilayers were grafted in a glove box having nitrogen ambient
with both humidity and oxygen contents <1 ppm using APTMS solutions prepared in an anhydrous toluene. Deposition of the multilayers
has been carried out as a function of solution concentration and grafting time. Characterization of the multilayers using
static de-ionized water contact angle, ellipsometry, X-rayphotoelectron spectroscopy and atomic force microscope measurements
revealed that self-assembling of the multilayers takes place in two distinct stages: (i) the first APTMS monolayer chemisorbs
on a hydroxylated oxide surface by a silanization process and, (ii) the surface amino group of the first monolayer chemisorbs
the hydrolyzed silane group of other APTMS molecules present in the solution, leading to the formation of a bilayer. The second
stage is a self-replicating process that results in the layer-by-layer self-assembly of the multilayers with trapped NH3
+ ions. The current–voltage characteristics of the multilayers exhibit a hysteresis effect along with a negative differential
resistance, suggesting their potential application in the molecular memory devices. A possible mechanism for the observed
hysteresis effect based on filling and de-filling of the NH3
+ acting as traps is presented.
PACS 73.30.+y 相似文献
443.
Bis(N, N′‐dialkyldithiocarbamato)antimony(III) alkylenedithiophosphates of the type [R2NCS2]2 SbS(S)POGO [where NR2 = N(CH3)2, N(C2H5)2 and N(CH2)4; G = ? CH2? C(C2H5)2? CH2? , ? CH2? C(CH3)2? CH2? , ? CH(CH3)? CH(CH3)? and ? C(CH3)2? C(CH3)2? ] were synthesized and characterized by physico‐chemical, spectral [UV, IR and NMR (1H, 13C and 31P)] and thermal (TG, DTA and DSC) analysis. The TG decomposition analysis step of the complex indicated the formation of Sb2S3 as the final product. The first endothermic peak in DSC indicated the melting point of the complexes. These complexes were screened for their antimicrobial activities using the disk diffusion method. All the complexes showed good activity as antibacterial and antifungal agents on some selected bacterial and fungal strains, which increased on increasing the concentration. Chloroamphenicol and terbinafin were used as standards for comparison. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
444.
Activated polystyrene cuvet is used for the determination of oxalate in urine sample and immunoglobulin in human sera. Polystyrene cuvet was activated by introducing active functional group onto its surface by coating the surface with a heterobifunctional photolinker, 1-fluoro-2-nitro-4-azidobenzene and exposing to UV light at 365 nm. Modified cuvet was active enough to covalently link oxalate oxidase in just 45 min at 50 °C without any additional catalyst or reagent. Remarkable reduction of time was achieved when immobilization was carried out by microwave irradiation. It took only 50 s to immobilize oxalate oxidase in the activated cuvet when exposed to microwaves in a domestic microwave oven. Immobilized-oxalate oxidase was stable, reusable and conveniently used for determination of urinary oxalate for diagnosis of primary hyperoxaluria and calcium oxalate nephrolithaiasis. Detection of human IgG involving ELISA in antihuman IgG-immobilized cuvet showed the feasibility of the cuvet in other immunoassays. 相似文献
445.
A. K. Narula S. K. Goyal Savita Saini R. P. Chauhan S. K. Chakarvarti 《Indian Journal of Physics》2009,83(8):1171-1175
The diffusion of radon in dwellings is a process determined by the radon concentration gradient across the building material
structure between the radon source and the surrounding air, and can be a significant contributor to indoor radon inflow. Radon
can originate from the deeply buried deposit beneath homes and can migrate to the surface of earth. Radon emanates to the
surfaces mainly by diffusion processes from the point of origin following α-decay of 226Ra in underground soil and building materials used, in the construction of floors, walls, and ceilings. In the present study
radon diffusion through some building materials viz. coarse sand and stone dust of different grain size has been carried out using LR-115 type II solid-state nuclear track detectors
(SSNTDs). The radon diffusion coefficients and diffusion lengths through these building construction materials have been calculated.
The effect of grain size on radon diffusion through these building materials shows the decrease in radon diffusion with decrease
in grain size. 相似文献
446.
Fatemeh Jahanzad Gini Chauhan Sherif Mustafa Basu Saha Shahriar Sajjadi Brian W. Brooks 《Macromolecular Symposia》2007,259(1):145-150
Summary: A new route was employed to produce composite polymer nanoparticles. First, a model polymer (a low molecular-weight polyisobutene) was dissolved in a model monomer (styrene) and then the solution was emulsified in water containing a pair of nonionic surfactants via a transitional phase inversion route. After phase inversion, which produced an oil-in-water miniemulsion, polymerisation of the vinyl monomer gave composite polymer particles. Low temperature emulsification was not practical because the inverted oil-in-water emulsions reinverted to water-in-oil emulsions upon raising the temperature to the reaction temperature. Miniemulsions prepared at the reaction temperature with low monomer content in the oil phase showed good stabilty in the course of polymerisation and produced latexes with a particle size similar to the size of drops in the initial miniemulsions. 相似文献
447.
The biomimetic oxidation of curcumin, a main turmeric pigment with hydrogen peroxide catalyzed by different 5,10,15,20-tetraarylporphyrinatoiron(III) chlorides [TAPFe(III)Cl] in dichloromethane has been studied to give a C-C coupled curcumin dimer in 40-70% yield. The structure of the dimer has been elucidated by (1)H-, (13)C-NMR, IR and FAB-Mass spectroscopic data. 相似文献
448.
XANES and EXAFS techniques are proving very popular in the study of local environment in disordered systems. Results of such
studies in a large number of metal (Fe, Co, Ni, etc)-metalloid (B, Si, C, etc) glasses are reported. Experiments were done
with synchrotron radiation as well as an x-ray tube. The values of bond lengths and co-ordination numbers computed from one-electron
single scattering Fourier transform method turn out substantially smaller. The values of bondlength determined from the other
EXAFS calculation method and the multiple-scattering computation scheme show good agreement. Importance of choice of suitable
reference materials for analysis of data is emphasized.
The experimental work was done at EXAFS 5.1 Station at Daresbury Laboratory, U.K. 相似文献
449.
450.
Chauhan S.S. Dahiya R.P. Seungjun Yi Lonngren K.E. 《IEEE transactions on plasma science. IEEE Nuclear and Plasma Sciences Society》1997,25(6):1425-1430
The variable coefficient modified Korteweg-de Vries (mKdV) equations for incident and reflected solitons are derived and solved to study the reflection of compressive and rarefactive ion acoustic solitons at the critical density in an inhomogeneous negative ion plasma. The polarity of the incident compressive and rarefactive solitons is not altered during the reflection process. Increasing the density gradient reinforces the reflection of both compressive and rarefactive mKdV solitons, whereas enhancement of the unperturbed plasma density weakens the reflection 相似文献