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41.
Ranjeet Prasad Dash Bhupendrasinh F. Chauhan Sheetal Anandjiwala Manish Nivsarkar 《Chromatographia》2010,71(7-8):609-615
An RP-LC method was developed and validated for comparing the pharmacokinetics profile of Vasa Swaras (leaf juice of Adhatoda vasica Nees., Fam. Acanthaceae) with that of the pure vasicine and vasicinone (chief marker compounds of A. vasica) upon oral administration of Vasa Swaras in rats, and also in different animal groups. Significant difference with p < 0.05 was found in the oral bioavailability of vasicine and vasicinone when administered as Vasa Swaras and as single vasicine and/or vasicinone. Vasicine and vasicinone were found to be more bioavailable from Vasa Swaras than pure vasicine and/or vasicinone. 相似文献
42.
Ashok K.S. Chauhan Poornima Singh Ray J. Butcher 《Journal of organometallic chemistry》2010,695(23):2532-2539
Room temperature oxidative addition of α-bromo-2-acetylthiophene to elemental tellurium and aryltellurium(II) bromide provides direct routes to (2-thiophenoylmethyl)tellurium(IV) dibromides, (2-(C4H3S)COCH2)2TeBr2 (1b) and 2-(C4H3S)COCH2ArTeBr2 (Ar = 1-C10H7, Npl, 2b; 2,4,6-Me3C6H2, Mes, 3b). The chloro analogues, 2-(C4H3S)COCH2ArTeCl2 (Ar = Npl, 2a; Mes, 3a) were prepared by the condensation reaction of the parent methyl ketone with NplTeCl3 or MesTeCl3. Metathesis of these products with an alkali iodide affords the iodo analogues 1c, 2c and 3c. These diorganotellurium dihalides are reduced with aqueous bisulfite to diorganotellurides 1-3, which can be oxidized readily with dihalogens to the desired diorganotellurium(IV) dihalides. Compound 1 is a rare example of a symmetrical telluroether with Csp3-Te-Csp3 grouping that has been characterized by single-crystal diffraction techniques. Preference of the 2-thiophenoylmethyl ligand for small-bite (C, O) chelation over less strained (C, S) coordination is evident in the crystal structures of the Te(IV) compounds 1b, 2a, 2b and 3a. The unexpected transoidal orientation of the two acylmethyl ligands in the solid state molecular configuration of symmetrical diorganotellurium(IV) dibromide 1b appears to be a combined effect of electronic repulsion due to the thiophene moieties and steric repulsion of bromo ligands. 相似文献
43.
In the present communication we have reviewed some inverted type equations of state for solids under high pressures. An inverted
equation of state (EOS) gives volume as a function of pressure for a solid under isothermal conditions. We have considered
various equations of state proposed by earlier workers which express volume as a function of pressure. Expressions for bulk
modulus and its pressure derivatives based on such EOSs are obtained and reported here. It is emphasized here that the high
pressure derivative properties are very sensitive to the forms of equations of state representing volume-pressure relationships.
We have also studied the thermoelastic properties of solids based on pressure derivatives of bulk modulus. Applications have
been extended in the present review article to the solids which are metals as well as non-metals including geophysical minerals
present in the lower mantle and core of the Earth. 相似文献
44.
Jaspreet Sandhu Amit Kumar Singh Chauhan Govind 《Journal of nanoparticle research》2011,13(8):3503-3509
The room temperature growth of gallium atoms on the highly oriented pyrolytic graphite (HOPG) surface has been performed.
The gallium atoms were deposited by thermal evaporation method in an ultra high vacuum system at a base pressure 5 × 10−10 torr. The X-ray photo electron spectroscopy (XPS) studies had been performed to confirm the presence of gallium atoms on
HOPG surface. Scanning tunneling spectroscopy (STM) technique was employed to study the surface morphology of the clean HOPG
surface and gallium covered HOPG surfaces which recognize the formation of gallium induced nanostructures. The deconvoluted
XPS core level spectra of C (1s) and Ga (3d) demonstrate the possible interaction between substrate and the adsorbate atoms.
The STM analysis revealed that the gallium deposition on HOPG led to significant change in the surface morphology. It was
observed that the Ga atoms adsorbed as layer structure on HOPG surface for low coverage while quasi one-dimensional chain
like nanostructure (1 ± 0.2 nm) has been formed for higher Ga coverage. The nanostructured surfaces induced by Ga deposition
are found to be stable and could be used as a template for the growth of metallic nanostructures. 相似文献
45.
46.
Apparent molar adiabatic compressibilities (K?, s) of glycine, L-alanine, L-valine, and L-leucine have been determined in aqueous and mixed aqueous solutions of lactose (2 to 6 mass%) at T = (293.15, 298.15, 303.15, and 308.15) K. From these data partial molar adiabatic compressibilities at infinite dilution (K?, s0) have been evaluated to calculate corresponding transfer function. The transfer partial molar adiabatic compressibilities at infinite dilution (ΔK?, s0) are found to be positive. The decrease in the magnitude of transfer partial molar adiabatic compressibilities from glycine to L-leucine indicates the dominance of hydrophobic-hydrophobic interactions between the increasing side chains of amino acids. Also, the contributions of NH3+COO− , and CH2 groups have been calculated by the linear correlation of K?, s0 with number of carbon atoms in the alkyl chain of amino acids. 相似文献
47.
Narendra P. S. Chauhan 《Journal of Thermal Analysis and Calorimetry》2012,110(3):1377-1388
A terpolymer resin involving p-acetylpyridine oxime and p-methylacetophenone with formaldehyde (APOMAF) was synthesized by condensation polymerization in the presence of an acid catalyst. The structure of terpolymer was elucidated by FT-IR, 1H NMR, pyrolysis gas chromatography mass spectrometer (Py?CGC?CMS), nitrogen adsorption/desorption analysis, Ubbelohde viscometer and non-aqueous conductometric titration, TG?CDTG and DSC. Molar fractions of monomer, condensing and comonomer unit (m 1, m 2, and m 3) in APOMAF using 1H NMR analysis data were calculated as 1.67; 0.27 and 0.66?mol%, respectively. The apparent activation energy of terpolymer by using various degradation models including the Flynn?CWall?COzawa (FWO), Kissinger?CAkahira?CSunose (KAS), and Friedman methods were 140.3; 144.9 and 129.9?kJ?mol?1, respectively. The results from isoconversional degradation kinetics and Pyrolysis (GC?CMS) indicates that the degradation mechanism of terpolymer are likely limited by at least two-reaction step, the first being associated with the loss of the pendent methyl, acetyl, and oxime groups (side group elimination) while the second mass loss being due to the degradation of the terpolymer backbone (random scission) which clearly indicates that grafting pendant groups to the terpolymer backbone yields polymers with lower thermal stability. From the calculation, the solid state thermal degradation mechanism is proposed to be D3 (three-dimensional diffusion) at initial stage and F 1 (Random nucleation with one nucleus on the individual particles) at final stage. 相似文献
48.
Satyaveer S. Chauhan 《Operations Research Letters》2005,33(3):249-254
The supply scheduling problem consists in finding a minimum cost delivery plan from a set of providers to a manufacturing unit, subject to given bounds on the shipment sizes and subject to the demand at the manufacturing unit. We provide a fully polynomial time approximation scheme for this problem. 相似文献
49.
Discrimination of bacteria from Jamaican bauxite soils using laser-induced breakdown spectroscopy 总被引:1,自引:0,他引:1
Lewis DE Martinez J Akpovo CA Johnson L Chauhan A Edington MD 《Analytical and bioanalytical chemistry》2011,401(7):2225-2236
Soil bacteria are sensitive to ecological change and can be assessed to gauge anthropogenic influences and ecosystem health.
In recent years, there has been a significant increase in the focus on new technologies that can be applied to the evaluation
of soil quality. Laser-induced breakdown spectroscopy (LIBS) is a promising technique that has been used for the investigation
and characterization of explosives, solids, liquids, gases, biological and environmental samples. In this study, bacteria
from un-mined and a chronosequence of reclaimed bauxite soils were isolated on Luria–Bertani agar media. Polymerase chain
reaction amplification of the bacterial 16S rDNA, sequencing, and phylogenetic analysis were applied to each isolated soil
bacteria from the sample sites resulting in the identification and classification of the organisms. Femtosecond LIBS performed
on the isolated bacteria showed atomic and ionic emission lines in the spectrum containing inorganic elements such as sodium
(Na), magnesium (Mg), potassium (K), zinc (Zn), and calcium (Ca). Principal component analysis and partial least squares regression
analysis were performed on the acquired bacterial spectra demonstrating that LIBS has the potential to differentiate and discriminate
among bacteria in the un-mined and reclaimed chronosequence of bauxite soils. 相似文献
50.
We consider a two-echelon timber supply chain in which the first echelon consists of several stands to be harvested and the
second echelon consists of mills to be supplied with logs of different length. This problem aims at minimizing harvesting
and transportation costs for one production period, while satisfying demand expressed as a mix of volumes of specific log
types. Harvesting cost, which includes felling, bucking and hauling to roadside, depends upon the number of log type to be
produced and sorted. Each stand to be harvested is modeled individually with a limited number of trees of various classes
of diameter and total length, which affects the productivity factors of the bucking patterns to be used. To take these characteristics
into account, we propose heuristics based on columns generation to solve the supply network problem at the forest level with
an anticipation of bucking operations at the stand level. 相似文献