Quantitative treatment of substituent effects in the polarographic investigations of some potential antineoplastic 2-amino-4-aryl-5-phenylazothiazoles

Polarographic reduction of 2-amino-4-aryl-5-phenylazothiazoles takes place in a single 2-electron transfer, giving a diffusion-controlled irreversible wave in the pH range 2.0-10.0. Substituents in the 4-position of the thiazole moiety shift the half-wave potential through conjugation of the system. A correlation of E(sol;1 2 ) with the Brown and Hammett substituent constant has also been established.     

Reactivity of 2-ethoxy-5-alkyl-3,4-dihydro-2H-pyrans towards aluminum alkyls : a facile synthesis of cyclobutylmethanols

2-Ethoxy-5-alkyl-3,4-dihydro-2H-pyrans react with Albuⁱ₃ and through a regioselective hydride addition provide substituted cyclobutylmethanols in very good yields.     

Formation of circular fringes with dark centre in diffused light at infinity

The generation of a circular fringe system of Newton rings' type with dark fringe at the centre is described. Such fringes are localized at infinity and are produced by a pair of longitudinally displaced mutually complimentary diffusers. Experimental results under various displacement configurations have been presented.     

Optimal Decision Rules for Producing Greeting Cards

A first attempt at applying OR techniques and approaches in a fine art printing firm manufacturing greeting cards is reported in this paper. The problem of economic production of cards is formulated and four related methods are presented, the fourth being a probabilistic model with possibly wider applications in the fashion industry     

Determination of economic packaging frequency in a multi-brand joint replenishment inventory system

The search procedure developed in this paper is typically applicable in those inventory systems where a product is packaged immediately after manufacture into a number of container sizes and the packaged items of similar sizes are sold under more than one brand name. The most common example of such items can be seen in supermarkets where grocery items of identical characteristics (produced by the same manufacture) are available under the supermarket's own brand and under the manufacturer's nationally advertised brand. An example has been solved to illustrate the method.     

Alloy contribution to phonon softening in ultra-heavily doped Si:As

Experimentally observed phonon softening of the 520 cm^-1 Raman line in ultra-heavily doped n-Si is attributed to the electron-phonon self-energy effects as well as change in lattice force constants of the alloy system.     

Direct evidence for As as a Zn-site impurity in ZnO

Arsenic has been reported in the literature as one of the few p-type dopants in the technologically promising II-VI semiconductor ZnO. However, there is an ongoing debate whether the p-type character is due to As simply replacing O atoms or to the formation of more complicated defect complexes, possibly involving As on Zn sites. We have determined the lattice location of implanted As in ZnO by means of conversion-electron emission channeling from radioactive (73)As. In contrast to what one might expect from its nature as a group V element, we find that As does not occupy substitutional O sites but in its large majority substitutional Zn sites. Arsenic in ZnO (and probably also in GaN) is thus an interesting example for an impurity in a semiconductor where the major impurity lattice site is determined by atomic size and electronegativity rather than its position in the periodic system.