Comparison of the Optoelectronic Performance of Neutral and Cationic Forms of Riboflavin

The riboflavin dye 2,3,4,5-tetra-O-acetyl-1-[3-(6-bromohexyl)-7,8-dimethyl-2,4-dioxo-3,4-dihydrobenzo[g]pteridin-10(2H)-yl]-1-deoxypentitol and its pyridinium salt were synthesized, and studied by absorption and fluorescence spectroscopy in solutions and on thin film states. The first absorption band of riboflavin-pyridinium salt derivative is red-shifted by 10 nm compared to neutral one on film. Cationic riboflavin derivative shows significant wavelength changes on its fluorescence emission spectrum in the excited state depending on the solvent polarity and the electronic environment. The fluorescence quantum yields of cationic riboflavin gave much higher values as compared to that of its neutral form. The fluorescence lifetimes were found to be in the range of 5.5–6.6 ns with mono ? exponential behavior. These dyes possess low-lying HOMO energy levels which are suitable to be able to inject holes to donor polymers so that they can be used as acceptor component in the active layer of bulk heterojunction solar cells (BHJ-SCs). Photovoltaic responses are reported for P3HT:riboflavin active layer wherein the synthesized dyes are used as acceptor component. Also, neutral riboflavin shows greater electron mobility value of 1.3 × 10^?3 cm²/V?s compared to its cationic derivative.     

Novel Fluorometric Turn On Detection of Aluminum by Chalcone-Based Chemosensor in Aqueous Phase

A novel, 100% water-soluble chalcone based chemosensing receptor {1-[3-(2-Hydroxy-phenyl)-3-oxo-propenyl]-naphthalen-2-yloxy}-acetic acid, L was synthesized and characterized. The receptor L is designed based on the chelation enhanced fluorescence (CHEF) mechanism. The chemosensing properties of L were evaluated by UV–vis and fluorescence spectrometric methods. It exhibits highly selective recognition ability towards aluminum ions in water over other metal ions. The binding stoichiometry of L? Al³⁺ complex is 2:1 by means of Job’s plot and the detection limit is 5.66?×?10^??8 M.     

Study on the Interaction of the CpG Alternating DNA with CdTe Quantum Dots

A novel sensitive method for detection of DNA methylation was developed with thioglycollic acid (TGA)-capped CdTe quantum dots (QDs) as fluorescence probes. Recognition of methylated DNA sites would be useful strategy due to the important roles of methylation in disease occurrence and developmental processes. DNA methylation occurs most often at cytosine-guanine sites (CpG dinucleotides) of gene promoters. The QDs significantly interacted with hybridized unmethylated and methylated DNA. The interaction of CpG rich methylated and unmethylated DNA hybrid with quantum dots as an optical probe has been investigated by fluorescence spectroscopy and electrophoresis assay. The fluorescence intensity of QDs was highly dependent to unmethylated and methylated DNA. Specific site of CpG islands of Adenomatous polyposis coli (APC), a well-studied tumor suppressor gene, was used as the detection target. Under optimum conditions, upon the addition of unmethylated dsDNA, the fluorescence intensity increased in linear range from 1.0?×?10^??10 to 1.0?×?10^??6M with detection limit of 6.2?×?10^??11 M and on the other hand, the intensity of QDs showed no changes with addition of methylated dsDNA. We also demonstrated that the unmethylated and methylated DNA and QDs complexes showed different mobility in electrophoresis assay. This easy and reliable method could distinguish between methylated and unmethylated DNA sequences.     

Triangle Geometry of the Qubit State in the Probability Representation Expressed in Terms of the Triada of Malevich’s Squares

We map the density matrix of the qubit (spin-1/2) state associated with the Bloch sphere and given in the tomographic probability representation onto vertices of a triangle determining Triada of Malevich’s squares. The three triangle vertices are located on three sides of another equilateral triangle with the sides equal to\( \sqrt{2} \). We demonstrate that the triangle vertices are in one-to-one correspondence with the points inside the Bloch sphere and show that the uncertainty relation for the three probabilities of spin projections +1/2 onto three orthogonal directions has the bound determined by the triangle area introduced. This bound is related to the sum of three Malevich’s square areas where the squares have sides coinciding with the sides of the triangle. We express any evolution of the qubit state as the motion of the three vertices of the triangle introduced and interpret the gates of qubit states as the semigroup symmetry of the Triada of Malevich’s squares. In view of the dynamical semigroup of the qubit-state evolution, we constructed nonlinear representation of the group U(2).     

A Compact-Intracavity Frequency-Doubling Nd:YAG Laser with 1.3 W Dual-Wavelength (659.6 nm/669.4 nm) Light Output

Terahertz wave radiation has important applications in medical instrumentation, optical communication, and so on. In this paper, we demonstrate a dual-wavelength (659.6 nm/669.4 nm) light output of a compact intracavity frequency-doubling Nd:YAG laser. We achieve a maximum output power of 1.3 W at central wavelengths of 659.6 and 669.4 nm with linewidths of 57 and 74 pm, respectively. The power instability at the maximum output power is less than 1%, and the beam quality is 1.5. This dual-wavelength laser provides a potential source for generating a coherent terahertz wave radiation of 6.46 THz by the nonlinear optical difference frequency method.     

Optimization of Diode-Pumped Continuous-Wave Tape-Casting YAG/Nd:YAG/YAG-Ceramic Lasers

We demonstrate a diode-laser-pumped solid-state 1.06 μm laser using a novel YAG/Nd:YAG/YAG composite ceramics with a sandwich structure. We optimize the laser performance using different output couplers, pumping beam waists, and cavity lengths. A maximum CW output power of 11 W for the YAG/Nd:YAG/YAG-ceramic laser is obtained at an absorbed pump power of 25 W resulting in a slope efficiency of 49.4%. The excellent output performance shows that the novel YAG/Nd:YAG/YAGceramic material has a great potential in applications with diode-laser pumping.     

High-Power Diode-End-Pumped Slab Composite Tm:YLF Compact Laser

We design a continuous-wave Tm:YLF laser with a composite slab crystal end-pumped by two fiber-coupled laser diodes at room temperature. We achieve a maximum continuous wave output power of 105 W for the bonded slab Tm:YLF laser; the corresponding slope efficiency is 47.7% and the optical-to-optical conversion efficiency is 42.0% with respect to the incident pump power. The laser operated at 1,907.5 nm with a beam quality factor of M² ～3.2 at the highest output power.     

Philosophical Implications of Kadanoff’s Work on the Renormalization Group

This paper investigates the consequences for our understanding of physical theories as a result of the development of the renormalization group. Kadanoff’s assessment of these consequences is discussed. What he called the “extended singularity theorem” (that phase transitons only can occur in infinite systems) poses serious difficulties for philosophical interpretation of theories. Several responses are discussed. The resolution demands a philosophical rethinking of the role of mathematics in physical theorizing.     

Shock Fluctuations for the Hammersley Process

We consider the Hammersley interacting particle system starting from a shock initial profile with densities \(\rho ,\lambda \in {\mathbb R}\) (\( \rho < \lambda \)). The microscopic shock is taken as the position of a second-class particle initially at the origin, and the main results are: (i) a central limit theorem for the shock; (ii) the variance of the shock equals \(2[\lambda \rho (\lambda - \rho )]^{-1}t + O(t^{2/3})\). By using the same method of proof, we also prove similar results for first-class particles.     

Emergent <Emphasis Type=Italic>SO</Emphasis>(3) Symmetry of the Frictionless Shear Jamming Transition

We study the shear jamming of athermal frictionless soft spheres, and find that in the thermodynamic limit, a shear-jammed state exists with different elastic properties from the isotropically-jammed state. For example, shear-jammed states can have a non-zero residual shear stress in the thermodynamic limit that arises from long-range stress-stress correlations. As a result, the ratio of the shear and bulk moduli, which in isotropically-jammed systems vanishes as the jamming transition is approached from above, instead approaches a constant. Despite these striking differences, we argue that in a deeper sense, the shear jamming and isotropic jamming transitions actually have the same symmetry, and that the differences can be fully understood by rotating the six-dimensional basis of the elastic modulus tensor.