全文获取类型
收费全文 | 213篇 |
免费 | 7篇 |
国内免费 | 2篇 |
专业分类
化学 | 159篇 |
晶体学 | 1篇 |
数学 | 27篇 |
物理学 | 35篇 |
出版年
2023年 | 1篇 |
2021年 | 1篇 |
2020年 | 1篇 |
2019年 | 1篇 |
2018年 | 1篇 |
2017年 | 1篇 |
2016年 | 4篇 |
2015年 | 7篇 |
2014年 | 11篇 |
2013年 | 10篇 |
2012年 | 11篇 |
2011年 | 12篇 |
2010年 | 18篇 |
2009年 | 14篇 |
2008年 | 22篇 |
2007年 | 14篇 |
2006年 | 15篇 |
2005年 | 13篇 |
2004年 | 11篇 |
2003年 | 4篇 |
2002年 | 11篇 |
2001年 | 3篇 |
2000年 | 2篇 |
1999年 | 2篇 |
1998年 | 2篇 |
1997年 | 3篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 2篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 3篇 |
1985年 | 2篇 |
1982年 | 1篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1977年 | 2篇 |
1961年 | 1篇 |
1959年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有222条查询结果,搜索用时 15 毫秒
101.
Hiltunen Y Kaartinen J Pulkkinen J Häkkinen AM Lundbom N Kauppinen RA 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2002,154(1):1-5
Long echo time (TE=270 ms) in vivo proton NMR spectra resembling human brain metabolite patterns were simulated for lineshape fitting (LF) and quantitative artificial neural network (ANN) analyses. A set of experimental in vivo 1H NMR spectra were first analyzed by the LF method to match the signal-to-noise ratios and linewidths of simulated spectra to those in the experimental data. The performance of constructed ANNs was compared for the peak area determinations of choline-containing compounds (Cho), total creatine (Cr), and N-acetyl aspartate (NAA) signals using both manually phase-corrected and magnitude spectra as inputs. The peak area data from ANN and LF analyses for simulated spectra yielded high correlation coefficients demonstrating that the peak areas quantified with ANN gave similar results as LF analysis. Thus, a fully automated ANN method based on magnitude spectra has demonstrated potential for quantification of in vivo metabolites from long echo time spectroscopic imaging. 相似文献
102.
Characteristics of the blood-oxygenation-level-dependent (BOLD) functional magnetic resonance imaging (fMRI) signal poststimulus undershoot in the visual cortex were studied at varying levels of arterial blood oxygen saturation (Ysat). Undershoot with an amplitude of -0.6+/-0.2% appeared after positive BOLD response (+1.7+/-0.5%) under control conditions. Cerebral blood volume (CBV), as determined with vascular-space-occupancy-dependent fMRI, increased by 26-43% during the positive BOLD peak, but the CBV proceeded at baseline level during the BOLD poststimulus undershoot. Mild hypoxic hypoxia (Ysat ranging from 0.82 to 0.89) had no effect on the amplitude or duration of poststimulus undershoot in activated BOLD pixels. Hypoxia did not influence CBV during the BOLD poststimulus undershoot. In contrast, the positive BOLD signal at the level of all activated pixels was smaller in hypoxia than in normoxia. The present results show that the BOLD poststimulus undershoot is not influenced by curtailed oxygen availability and that, during the undershoot, CBV is not different from resting state. 相似文献
103.
Risto Laitinen 《Journal of Molecular Structure》1985,124(3-4):293-305
A theoretical study of HSH, HSeH, HTeH, HSSH, HSeSH, HSeSeH, HTeSH, HTeSeH, and HTeTeH was carried out by ab initio molecular orbital methods employing minimal Gaussian basis sets MINI-1 and MINI-1* of Huzinaga and his group. Both basis sets yield accurate estimates on the equilibrium geometries of monochalcogen hydrides. In the case of dichalcogen hydrides, however, the inclusion of d-polarization functions for sulfur, selenium, and tellurium greatly improve the accuracy of the geometry prediction. The unpolarized MINI-1 basis sets yield essentially correct orbital energies and therefore suffice for the comparative study on the electronic structures in similar molecules. The results with both basis sets imply close similarities in the electronic structures of SS, SeS, and SeSe bonds with more marked differences in bonds containing tellurium as a consequence of notably smaller orbital energy of the 5s- orbital of tellurium as compared to the corresponding orbitals in sulfur and selenium. The barriers to internal rotation about the chalcogen—chalcogen bond in all dichalcogen hydrides are similar. The cis- and trans-barrier heights are ca. 23 and 14 kJ mol−1, respectively. The relative stabilities of different hydrides are discussed. 相似文献
104.
Zusammenfassung Es werden die Anforderungen festgelegt, die an einen Trockenschrank zur Trocknung und Entwicklung von Papierchromatogrammen zu stellen sind. Der Entwurf und der Aufbau eines solchen, den speziellen Anforderungen genügenden Gerätes wird beschrieben und anschließend werden die Erfahrungen mit dem fertigen Trockenschrank diskutiert.
Summary The demands which have to be made on a drying oven concerning proper drying and development of paper chromatograms are stated. Detailed plan and construction of an oven fullfilling these demands are presented and the practical experience of its use is discussed.
Résumé Les demandes qu'on doit poser à une étuve pour séchage et révélation des chromatogrammes sur papier sont présentées. L'ébauche et la construction d'une étuve qui satisfaira à ces demandes spécielles sont exposées et à la fin on discute les expériences qu'on a fait sur son emploi.相似文献
105.
Ya. I. Azimov V. A. Khoze Risto Raitio 《Zeitschrift fur Physik C Particles and Fields》1979,2(1):49-53
We discuss the inclusive energy spectrum and angular distribution of a secondary particleh ine + e ?→heavy particle pair→h+X and derive the mathematical results of earlier work in a way tht makes the qualitative features of the formulae easily understandable. Some interesting examples of heavy lepton and new hadron decays are considered in detail. 相似文献
106.
107.
Glass microfabricated nebulizer chip for mass spectrometry 总被引:1,自引:0,他引:1
A microfluidic nebulizer chip for mass spectrometry is presented. It is an all-glass device which consists of fusion bonded Pyrex wafers with embedded flow channels and a nozzle at the chip edge. A platinum heater is located on the wafer backside. Fabrication of the chip is detailed, especially glass deep etching, wafer bonding, and metal patterning. Various process combinations of bonding and metallization have been considered (anodic bonding vs. fusion bonding; heater inside/outside channel; metallization before/after bonding; platinum lift-off vs. etching). The chip vaporizes the liquid sample (0.1-10 microL min(-1)) and mixes it with a nebulizer gas (ca. 100 sccm N2). Operating temperatures can go up to 500 degrees C ensuring efficient vaporization. Thermal insulation of the glass ensures low temperatures at the far end of the chip, enabling easy interconnections. 相似文献
108.
Degtyarenko IM Jalkanen KJ Gurtovenko AA Nieminen RM 《The journal of physical chemistry. B》2007,111(16):4227-4234
We report the results of a Born-Oppenheimer molecular dynamics study on an L-alanine amino acid in neutral aqueous solution. The whole system, the L-alanine zwitterion and 50 water molecules, was treated quantum mechanically. We found that the hydrophobic side chain (R = CH3) defines the trajectory path of the molecule. Initially fully hydrated in an isolated droplet of water, the amino acid moves to the droplet's surface, exposing its hydrophobic methyl group and alpha-hydrogen out of the water. The structure of an L-alanine with the methyl group exposed to the water surface was found to be energetically favorable compared to a fully hydrated molecule. The dynamic behavior of the system suggests that the first hydration shell of the amino acid is localized around carboxylate (CO2-) and ammonium (NH3+) functional groups; it is highly ordered and quite rigid. In contrast, the hydration shell around the side chain is much less structured, suggesting a modest influence of the methyl group on the structure of water. The number of water molecules in the first hydration shell of an alanine molecule is constantly changing; the average number was found to equal 7. The molecular dynamics results show that L-alanine in water does not have a preferred conformation, as all three of the molecule's functional sites (i.e., CH3, NH3+, CO2-) perform rotational movements around the C(alpha)-site bond. 相似文献
109.
Tuula Kuivalainen Risto Kostiainen Rolf Uggla Markku R. Sundberg Heikki Björk 《Journal of the American Society for Mass Spectrometry》1996,7(2):189-197
The gas-phase ion chemistry of protonated O,O-diethyl O-aryl phosphorothionates was studied with tandem mass spectrometric and ab initio theoretical methods. Collision-activated dissociation (CAD) experiments were performed for the [M+H]+ ions on a triple quadrupole mass spectrometer. Various amounts of internal energy were deposited into the ions upon CAD by variation of the collision energy and collision gas pressure. In addition to isobutane, deuterated isobutane C4D10 also was used as reagent gas in chemical ionization. The daughter ions [M+H?C2H4]+ and [M+H?2C2H4]+ dominate the CAD spectra. These fragments arise via various pathways, each of which involves γ-proton migration. Formation of the terminal ions [M+H?2C2H4?H2O]+, [M+H?2C2H4?H2S]+, [ZPhOH2]+, [ZPhSH2]+, and [ZPhS]+ [Z = substituent(s) on the benzene ring] suggests that (1) the fragmenting [M+H]+ ions of O,O-diethyl O-aryl phosphorothionates have protons attached on the oxygen of an ethoxy group and on the oxygen of the phenoxy group; (2) thiono-thiolo rearrangement by aryl migration to sulfur occurs; (3) the fragmenting rear-ranged [M+H]+ ions have protons attached on the oxygen of an ethoxy group and on the sulfur of the thiophenoxy group. To get additional support for our interpretation of the mass spectrometric results, some characteristics of three protomers of O,O-diethyl O-phenyl phosphorothionate were investigated by carrying out ab initio molecular orbital calculations at the RHF/3–21G* level of theory. 相似文献
110.
Hänninen V Korpinen M Ren Q Hinde R Halonen L 《The journal of physical chemistry. A》2011,115(11):2332-2339
We employ ab initio calculations of van der Waals complexes to study the potential energy parameters (C(6) coefficients) of van der Waals interactions for modeling of the adsorption of silver clusters on the graphite surface. Electronic structure calculations of the (Ag(2))(2), Ag(2)-H(2), and Ag(2)-C(6)H(6) complexes are performed using a coupled-cluster approach that includes single, double, and perturbative triple excitations (CCSD(T)), M?ller-Plesset second-order perturbation theory (MP2), and spin-component-scaled MP2 (SCS-MP2) methods. Using the atom pair approximation, the C(6) coefficients for silver-silver, silver-hydrogen, and silver-carbon atom systems are obtained after subtracting the energies of quadrupole-quadrupole interactions from the total electronic energy. 相似文献