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101.
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103.
S. Shanmuga Sundara Raj Hoong‐Kun Fun Zhong‐Lin Lu Wen Xiao Xiao‐Yang Gong Chang‐Ming Gen 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(8):1013-1014
The crystal structure of the title compound, C15H14N2O2·H2O, is in the keto tautomeric form and the configuration at the azomethine C=N double bond is E. The molecule is non‐planar, with a dihedral angle of 27.3 (1)° between the aromatic rings. The crystal structure is stabilized by extensive hydrogen bonding involving the water molecule and hydrazone moiety. 相似文献
104.
I. Victor Paul Raj 《Tetrahedron letters》2008,49(16):2646-2648
A concise route to the asymmetric synthesis of (S)-vigabatrin® and (S)-dihydrokavain has been described using Co-catalyzed hydrolytic kinetic resolution of racemic epoxides and regiospecific opening of terminal epoxides with dimethylsulfonium methylide as the key steps. 相似文献
105.
C-field cosmological models based on Hoyle-Narlikar theory with variable gravitational constant G in the frame work of FRW (Friedmann-Robertson-Walker) space–time for positive and negative curvatures are investigated. To
get the deterministic solutions in terms of cosmic time t, we have assumed G=R
n
and discussed for n=−1, −2, R being scalar factor. In both the cases, creation field C increases with time, the gravitational constant G and matter density (ρ) decrease with time in the model (21). In the model (41) G decreases with time and matter density (ρ) is constant. The other physical aspects of the models are also discussed. 相似文献
106.
N.S. Venkata Narayanan B.V. Ashok Raj S. Sampath 《Electrochemistry communications》2009,11(10):2027-2031
Room temperature, magnesium ion conducting binary molten electrolyte consisting of acetamide and magnesium perchlorate has been prepared and characterized. The molten liquid is very stable and shows high ionic conductivity, of the order of several mS cm−1 at 25 °C with other favourable physicochemical properties. Vibrational spectroscopic studies reveal that the free ion concentration is higher than that of ion pairs and aggregates in the melt. The electrochemical reversibility of magnesium deposition and dissolution is demonstrated using voltammetry and impedance studies. Preliminary studies on rechargeable batteries assembled using γ-MnO2 and Mg metal as the electrodes together with the molten electrolyte show high discharge capacity. 相似文献
107.
Zhu Dunru Song You Liu Yongjiang Xu Yan Zhang Yong You Xiaozeng Sundara Raj S. Shanmuga Fun Hoong-Kun 《Transition Metal Chemistry》2000,25(5):589-593
The novel cobalt(II) and nickel(II) complexes with 4-(p-methoxyphenyl)-3,5-bis(pyridin-2-yl)-1,2,4-triazole (MOBPT) have been synthesized and their molecular structures determined by X-ray analysis, i.r. and by ESI-MS spectroscopy. The metal atom is in a distorted octahedral environment. Two bidentate chelating ligands (MOBPT) coordinate to the metal center equatorially and two water molecules coordinate axially. Each MOBPT entity coordinates via one triazole nitrogen and one pyridine nitrogen atom. Magnetic measurements show that the complexes are high-spin species in the 75–300 K range. 相似文献
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