全文获取类型
收费全文 | 360篇 |
免费 | 31篇 |
国内免费 | 1篇 |
专业分类
化学 | 336篇 |
晶体学 | 2篇 |
力学 | 5篇 |
数学 | 24篇 |
物理学 | 25篇 |
出版年
2023年 | 1篇 |
2022年 | 4篇 |
2021年 | 3篇 |
2020年 | 5篇 |
2019年 | 12篇 |
2018年 | 5篇 |
2017年 | 7篇 |
2016年 | 16篇 |
2015年 | 13篇 |
2014年 | 17篇 |
2013年 | 27篇 |
2012年 | 36篇 |
2011年 | 31篇 |
2010年 | 20篇 |
2009年 | 14篇 |
2008年 | 32篇 |
2007年 | 26篇 |
2006年 | 24篇 |
2005年 | 17篇 |
2004年 | 32篇 |
2003年 | 20篇 |
2002年 | 15篇 |
2001年 | 3篇 |
2000年 | 4篇 |
1999年 | 2篇 |
1998年 | 3篇 |
1997年 | 2篇 |
1985年 | 1篇 |
排序方式: 共有392条查询结果,搜索用时 15 毫秒
111.
Lemierre V Chrostowska A Dargelos A Chermette H 《The journal of physical chemistry. A》2005,109(37):8348-8355
With the help of various theoretical methods, ionization potentials (IPs) have been computed for a panel of small molecules containing atoms of group 14, 15, or 16 and representing different singly, doubly, or triply bonded systems with or without an interacting heteroatom lone pair. Comparison of experimental IP values to theoretical results indicates that (i) the standard outer valence green function (OVGF), density functional theory (DFT), and DeltaSCF methods lead to rather accurate values, (ii) the CASPT2 method systematically underestimates IPs, (iii) the method of deducing IPs from a shift of some standard DFT eigenvalue spectrum is a straightforward approach leading to rather accurate IPs, (iv) the eigenvalue spectrum obtained with the so-called statistical average of different orbital model potential (SAOP) exchange-correlation model potential is an efficient approach leading directly to quite accurate IPs, and (v) a good prediction of the IP spectrum can be obtained from the shifted excitation spectra of the system calculated by the time-dependent DFT (TD-DFT) method. It is also shown that the TD-DFT calculations of the ionized species bring a significant improvement over the calculations of the neutral molecules, indicating that a great part of the electronic relaxation is already taken into account (in a similar way for all ionizations). Finally, in the case of TD-DFT calculations of neutral molecules, the statistical average of different orbital model potential (SAOP) functional does not lead to significantly better results than the B3LYP functional. 相似文献
112.
113.
114.
Virginie Martinet Patrick Saulnier Val rie Beaumal Jean-Luc Courthaudon Marc Anton 《Colloids and surfaces. B, Biointerfaces》2003,31(1-4):185-194
Hen egg yolk is largely used as food ingredient notably because of its exceptional emulsifying properties. Low-density lipoproteins (LDL) are the main egg yolk constituent. LDL and particularly apoLDL are thought to control largely emulsifying properties of egg yolk-based products. Nevertheless, few studies have concerned the interfacial behaviour of these lipoproteins at the oil–water interface and nothing has been published about the air–water interface. Controversies still remain about LDL adsorption mechanism at the oil–water interface even if a widely spread theory suggests their breaking at the interface, allowing then their constituents to spread. The Langmuir film balance and atomic force microscopy (AFM) were used in this study in the aim to characterise LDL surface behaviour in dynamic conditions at the air–water interface. The understanding of LDL adsorption mechanism and surface organisation at the air–water interface should provide useful information about LDL behaviour at the oil–water interface. LDL and lipids extracted from LDL—neutral lipids, phospholipids and total lipids (mixture of the two previous species)—were spread at the air–water interface to clarify the role of each constituent in the lipoprotein film. Results clearly show that LDL are disrupted at the interface to release notably neutral lipids from the lipoprotein core, enabling then their spreading. Each lipid class has been identified on the LDL film isotherm and seems to behave independently and individually at the interface within the lipoprotein film. 相似文献
115.
Ribot F Escax V Martins JC Biesemans M Ghys L Verbruggen I Willem R 《Chemistry (Weinheim an der Bergstrasse, Germany)》2004,10(7):1747-1751
Pulsed field gradient (1)H NMR spectroscopy has been applied to investigate the association behavior of the Sn(12)-oxo cluster macrocation [(BuSn)(12)O(14)(OH)(6)](2+) with two different and smaller anions, p-toluenesulfonate (PTS(-)) and diphenylphosphinate (Ph(2)PO(2) (-)). By monitoring the translational diffusion coefficients of the various species involved, it is shown that the association depends on the anion involved and on the solvent used. Moreover, the possibility to individually monitor the diffusion characteristics of multiple anionic and cationic species in mixtures, by virtue of resolved (1)H resonances available from each species, allows us to evidence the occurrence of ion exchange in such systems. Thus when [(BuSn)(12)O(14)(OH)(6)](PTS)(2) is mixed with two equivalents of Ph(2)PO(2)NMe(4), PTS(-) is displaced by Ph(2)PO(2) (-), highlighting the greater affinity of the organotin macrocation for the diphenylphosphinate. This example clearly illustrates the potential of pulsed field gradient (1)H NMR spectroscopy in inorganic/organometallic chemistry, to follow preferential ion pairing in multi-ion systems at the level of each individually charged species. 相似文献
116.
117.
118.
119.
120.
Virginie Detallante Dominique Langevin Corinne Chappey Michel Mtayer Rgis Mercier Michel Pinri 《Journal of membrane science》2001,190(2):155-241
The water vapor uptake of sulfonated polyimides (SP) was investigated by electronic microbalance (IGA, Hiden) from 15 to 55°C. The sigmoïdal isotherms obtained (BET II type) are considered as dual sorption (concave part) plus clustering (convex part) and are fitted with good agreement by Park’s equation. Zimm–Lundberg’s method is used to study the clustering process of water molecules: limit clustering activity, a*, and the number of molecules per cluster are estimated.
To obtain a better understanding of polymer structure and isotherm analysis, H+ (counter-ions of sulfonic groups) were replaced by ions with a smaller hydration shell (Cs+ and EDAH+). Comparison of the three isotherms shows no significant difference in the water affinity of the cations. This is attributed to a partial control of the sorption by microcavities existing in the membrane. 相似文献