Vibration of simply supported cylindrical shells with longitudinal stiffeners

The vibration of simply supported cylindrical shells stiffened by discrete longitudinal stiffeners is investigated by using an energy method. Vlasov's thin walled beam theory is used for stringers. Shell theories based on Donnell's approximate theory and Flügge's more exact theory are used for the skin and numerical results indicate that Donnell's approximate theory gives excellent results for the stiffened shells. Sinusoidal wave form is considered in the longitudinal direction, and mode shapes in the circumferential direction are represented by Fourier series. Numerical results on frequencies and mode shapes computed for a shell stiffened by various number of stiffeners are presented and compared favorably with existing experimental results and other analytical solutions.     

Laurencienyne,a new acetylenic cyclic ether from the marine red alga laurencia obtusa

The structure and absolute stereochemistry of laurencienyne, a non-isoprenoid cyclic ether isolated from $\text{Laurencia obtusa}$, has been established by X-ray and spectroscopic studies.     

Size-Controlled Hapticity Switching in [Ln(C9H9)(C8H8)] Sandwiches

Sandwich complexes of lanthanides have recently attracted a considerable amount of interest due to their applications as Single Molecule Magnet (SMM). Herein, a comprehensive series of heteroleptic lanthanide sandwich complexes ligated by the cyclononatetraenyl (Cnt) and the cyclooctatetraenyl (Cot) ligand [Ln(Cot)(Cnt)] (Ln=Tb, Dy, Er, Ho, Yb, and Lu) is reported. The coordination behavior of the Cnt ligand has been investigated along the series and shows different coordination patterns in the solid-state depending on the size of the corresponding lanthanide ion without altering its overall anisotropy. Besides the characterization in the solid state by single-crystal X-ray diffraction and in solution by ¹H NMR, static magnetic studies and ab initio computational studies were performed.