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21.
Jiunn-Wei Chen Hiroaki Kohyama Kazuaki Ohnishi Udit Raha Yue-Long Shen 《Physics letters. [Part B]》2010
We present a combined analysis of the space- and time-like electromagnetic pion form factors in light-cone perturbative QCD with transverse momentum dependence and Sudakov suppression. Including the genuine non-perturbative “soft” QCD and the power suppressed twist-3 corrections to the standard twist-2 perturbative QCD result, the experimental form factor data available at moderate energies/momentum transfers can be explained reasonably well. To this end, the bulk of the existing discrepancy between the space- and time-like experimental data is ostensibly reconciled. 相似文献
22.
Anucha Wannagon Rikuo Ota Takashi Wakasugi Jiro Fukunaga 《Journal of Sol-Gel Science and Technology》2000,19(1-3):795-798
SiO2-TiO2-ZrO2 and 5Na2O·95(SiO2 + TiO2 + ZrO2) gels were synthesized and role of Na2O in gel formation and crystallization behavior of gels were studied. From Si(OC2H5)4, Ti(iso-OC3H7)4, Zr(n-OC3H7)4 and NaOCH3 solutions in EtOH without H2O, transparent and opaque gels were obtained. Opaque bulk gels, rich in TiO2 or ZrO2 composition in Na2O containing SiO2-TiO2-ZrO2 system, contain agglomerated spherical particles of diameter small <10 m, in contrast with opaque gels having large particles <30 m in alkali-free SiO2-TiO2-ZrO2 system. Crystallization temperature (Tc) was measured by DTA on dried gels. Compared with the alkali-free SiO2-TiO2-ZrO2 gels, 5 mol% Na2O containing gels gave lower Tc in SiO2 rich compositions and higher in TiO2 rich or ZrO2 rich compositions. 相似文献
23.
Kim SW Zimmer JP Ohnishi S Tracy JB Frangioni JV Bawendi MG 《Journal of the American Chemical Society》2005,127(30):10526-10532
Quantum dots with a core/shell/shell structure consisting of an alloyed core of InAs(x)P(1-x), an intermediate shell of InP, and an outer shell of ZnSe were developed. The InAs(x)P(1-x) alloyed core has a graded internal composition with increasing arsenic content from the center to the edge of the dots. This compositional gradient results from two apparent effects: (1) the faster reaction kinetics of the phosphorus precursor compared to the arsenic precursor, and (2) a post-growth arsenic-phosphorus exchange reaction that increases the arsenic content. The cores have a zinc blend structure for all compositions and show tunable emission in the near-infrared (NIR) region. A first shell of InP leads to a red-shift and an increase in quantum yield. The final shell of ZnSe serves to stabilize the dots for applications in aqueous environments, including NIR biomedical fluorescence imaging. These NIR-emitting core/shell/shell InAs(x)P(1-x)/InP/ZnSe were successfully used in a sentinel lymph node mapping experiment. 相似文献
24.
Ohnishi YY Matsunaga T Nakao Y Sato H Sakaki S 《Journal of the American Chemical Society》2005,127(11):4021-4032
Ruthenium-catalyzed hydrogenation of carbon dioxide to formic acid was theoretically investigated with DFT and MP4(SDQ) methods, where a real catalyst, cis-Ru(H)2(PMe3)3, was employed in calculations and compared with a model catalyst, cis-Ru(H)2(PH3)3. Significant differences between the real and model systems are observed in CO2 insertion into the Ru(II)-H bond, isomerization of a ruthenium(II) eta1-formate intermediate, and metathesis of the eta1-formate intermediate with a dihydrogen molecule. All these reactions more easily occur in the real system than in the model system. The differences are interpreted in terms that PMe3 is more donating than PH3 and the trans-influence of PMe3 is stronger than that of PH3. The rate-determining step is the CO2 insertion into the Ru(II)-H bond. Its deltaG(o++) value is 16.8 (6.8) kcal/mol, where the value without parentheses is calculated with the MP4(SDQ) method and that in parentheses is calculated with the DFT method. Because this insertion is considerably endothermic, the coordination of the dihydrogen molecule with the ruthenium(II)-eta1-formate intermediate must necessarily occur to suppress the deinsertion. This means that the reaction rate increases with increase in the pressure of dihydrogen molecule, which is consistent with the experimental results. Solvent effects were investigated with the DPCM method. The activation barrier and reaction energy of the CO2 insertion reaction moderately decrease in the order gas phase > n-heptane > THF, while the activation barrier of the metathesis considerably increases in the order gas phase < n-heptane < THF. Thus, a polar solvent should be used because the insertion reaction is the rate-determining step. 相似文献
25.
Watano S Okamoto T Sato Y Ohnishi Y Yasutomo T Osako Y 《Chemical & pharmaceutical bulletin》2005,53(1):18-21
A novel multi-functional vertical high shear kneader has been developed and its performance in wet kneading has previously been reported [Watano et al., Chem. Pharm. Bull., 50(3), 341-345 (2002)]. In this study, scale-up of wet kneading in the novel vertical high shear kneader was conducted. Pharmaceutical excipients composed of lactose, cornstarch and micro-crystalline cellulose were used as powder samples. Kneading operations were conducted under various operating conditions and three different vessel scales. The dried pellets were then prepared by extruding the wet kneaded masses through a dome-type extruder and their drying by a fluidized bed. The physical properties such as strength and disintegration time of the dried pellets were evaluated. It was found that the properties of the dried pellets and their scale-up characteristics were well expressed by an agitation power per unit vessel volume and dimensionless Froude number. 相似文献
26.
Y. Ishii S. Saito S. Ohnishi 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1987,7(3):289-292
Bonding properties of sodium-cluster dimers, (X 4)2 and (X 8)2, whereX n is a jellium sphere corresponding to a cluster ofn atoms, were investigated by the linear-combination-of-jellium-orbitals method with local-spin-density-functional approximation. The stability ofn=8 clusters, observed in the experiment, is discussed in relation to the binding properties of dimers. We have found that (1) the (X 4)2 bonding has a covalent character, which makes theX 8 formation favorable, and (2)X 8 has an inert property because the force between jellium spheres in (X 8)2 is due to a weak dispersion force. 相似文献
27.
Ariaki Murata Ryota Akaike Tatsuya Kawahashi Ryo Tsuchiya Hiroyuki Takemoto Toshiyuki Ohnishi Yasushi Todoroki Nobuyuki Mase Mineyuki Yokoyama Kazuteru Takagi Peter Winterhalter Naoharu Watanabe 《Tetrahedron》2014
A flower-inducing compound, LDS1, was isolated from a free-floating aquatic plant, Lemna paucicostata. The chemical structure and the absolute stereochemistry of LDS1 were determined as (9R,13R,11E,15Z)-9,13-dihydroxy-10-oxooctadeca-11,15-dienoic acid for its most abundant diastereomer. LDS1 was enzymatically produced when the plant was exposed to drought stress, and induced flowering at a concentration of 10 nM. 相似文献
28.
The optical torque and the trapping position (focal point) in optical tweezers are analyzed for upward-directed focused laser
illumination using a ray optics model, considering that laser light is incident at not only the lower surface but also the
side surface of a 3-wing rotor. The viscous drag force due to the pressure and the shearing stress on all surfaces of the
rotor is evaluated using computational fluid dynamics. The rotation rate is simulated in water by balancing the optical torque
with the drag force, resulting in 500 rpm for an SU-8 rotor with 20 μm diameter at a laser power of 200 mW. The trapping position
is estimated to be 7.6 μm in the rotor with an upward-directed laser at 200 mW via an objective lens having a numerical aperture
of 1.4. Both the rotation rate and the trapping position agree well with the values obtained in the experiment. 相似文献
29.
Elastic and inelastic scattering of 7Li by 58Ni at Elab = 14.2 and 20.3 MeV is investigated theoretically, special emphasis being laid on polarization phenomena. A parameter-independent study shows second-rank tensor interactions to be the main origin of tensor analyzing powers for both elastic and inelastic scattering. Coupled-channel (CC) calculations using cluster-folding interactions which include the tensor terms are found to be successful in reproducing the data for cross sections and vector and tensor analyzing powers, when projectile excitation effects are sufficiently taken into account. Scattering of 6Li by 58Ni at Elab = 20.0 MeV is also investigated by the CC calculation, where successes similar to the 7Li case are obtained in understanding experimental data. 相似文献
30.
Both abilities of germination of spores formed after UV irradiation and of growth of amoeboid cells emerged from the spores were studied on two kinds of Dictyostelium discoideum strains, NC-4 and ys-13.
An inhibition of germination was observed on the spores of ys -13 when formed after UV irradiation, while no inhibition was detected on the ability of germination of spores of NC-4. The amoeboid cells of ys -13 emerged from the spores showed a heavy delay of growth, although no delay of growth was detected even on the amoeboid cells of NC-4 emerged from the spores formed after UV irradiation. The strain of NC-4 must repair UV lesions fully before spore formation, while the spores of ys-13 must keep some UV lesions unrepaired and send them to the next generation of amoeboid cells. The characters of UV lesion inheritable through the spores to the next amoeboid cells in ys-13 were discussed. 相似文献
An inhibition of germination was observed on the spores of ys -13 when formed after UV irradiation, while no inhibition was detected on the ability of germination of spores of NC-4. The amoeboid cells of ys -13 emerged from the spores showed a heavy delay of growth, although no delay of growth was detected even on the amoeboid cells of NC-4 emerged from the spores formed after UV irradiation. The strain of NC-4 must repair UV lesions fully before spore formation, while the spores of ys-13 must keep some UV lesions unrepaired and send them to the next generation of amoeboid cells. The characters of UV lesion inheritable through the spores to the next amoeboid cells in ys-13 were discussed. 相似文献