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671.
Yuichi Ohya Tatsuya Nakao Tatsuro Ouchi Takeshi Inoi Koji Fukushima Tazuko Tashiro 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(7):503-515
Abstract The homopolymerization of vinyl monomer immobilized 5-fluorouracils (5FU) through organosilicon-amine spacer groups via urea bonds (KY-20) and the copolymerization of KY-20 with vinyl monomer were carried out by a radical technique to give the homopolymer [Poly(KY-20)] and copolymer [Poly(KY-20/vinyl monomer)], respectively. The antitumor activities of Poly(KY-20) and Poly(KY-20/vinyl monomer) were tested against p388 lymphocytic leukemia by intraperitoneal (i.p.) transplantation/i.p. or oral (p.o.) administration and against Meth-A fibrosarcoma or MM46 mammary adenocarcinoma in mice by subcutaneous (s.c.) implantation/p.o. administration. These 5FU/ organosilicon-amine hybrid polymer conjugates exhibited significant survival effects against p388 leukemia in mice i.p./i.p. or i.p./p.o. Poly(KY-20/HPMA) also showed stronger growth-inhibitory effects against Meth-A fibrosarcoma and MM46 mammary adenocarcinoma in mice s.c./p.o. 相似文献
672.
Kazuki Fukushima Daniel J. Coady Gavin O. Jones Hamid A. Almegren Abdullah M. Alabdulrahman Fares D. Alsewailem Hans W. Horn Julia E. Rice James L. Hedrick 《Journal of polymer science. Part A, Polymer chemistry》2013,51(7):1606-1611
This article describes studies on the catalytic activity of several nitrogen‐based organic catalysts for the depolymerization of poly(ethylene terephthalate) (PET), in which a few cyclic amidines work more effectively than a potent, bifunctional guanidine‐based catalyst 1,5,7‐triazabicyclo‐[4,4,0]‐dec‐5‐ene (TBD) in the presence of short chain diols that play a role in activation of carbonyl groups through hydrogen bonding. Further studies prove that the catalytic efficiency at the above specific conditions depends only on the extent of activation of a hydroxyl group rather than simply the pKa of the bases. For glycolysis with excess short‐chain alkanediols, 1,8‐diazabicyclo[5.4.0]undec‐7‐ene is the best catalyst. In contrast, TBD shows outstanding catalytic activity in depolymerizations of PET with mono‐alcohols and longer‐chain diols. © 2013 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013 相似文献
673.
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676.
M. Fukushima H. Tamate Y. Nakano 《Journal of Radioanalytical and Nuclear Chemistry》2000,244(1):55-59
Marine invertebrates are well known to accumulate trace metals from seawater, plankton, sea plants, and sediments. To test the usefulness of such organisms as a bio-indicator of environmental conditions, we have determined levels of trace elements in tissue of twelve species of marine invertebrates by photon and neutron activation analysis. Relatively higher concentration of elements were observed for Ni and Sn in mid-gut gland, for Cu and Zn in oyster tissues, for Se in swimming crabs, for Cu, Fe, and Se in gills of swimming crabs. Our results indicate that mid-gut gland of ear-shell will be useful as the indicator of environmental conditions. 相似文献
677.
The mixed complementarity problem can be reformulated as a nonsmooth equation by using the median operator. In this paper, we first study some useful properties of this reformulation and then derive the Chen-Harker-Kanzow-Smale smoothing function for the mixed complementarity problem. On the basis of this smoothing function, we present a smoothing Newton method for solving the mixed complementarity problem. Under suitable conditions, the method exhibits global and quadratic convergence properties. We also present a smoothing Broyden-like method based on the same smoothing function. Under appropriate conditions, the method converges globally and superlinearly. 相似文献
678.
A study of chiral recognition for NBD-derivatives on a Pirkle-type chiral stationary phase. 总被引:1,自引:0,他引:1
M Kato T Fukushima N Shimba I Shimada Y Kawakami K Imai 《Biomedical chromatography : BMC》2001,15(4):227-234
A chiral stationary phase (CSP 1) derived from an (S)-N-3,5-dinitrobenzoyl-1-naphthylglycine showed excellent enantiomeric separation for amino acid derivatives with a fluorogenic reagent, 4-fluoro-7-nitro-2,1,3-benzoxadiazole (NBD-F), in high-performance liquid chromatography (HPLC). We compared elution profiles (separation factor and elution order) of NBD-amino acids and their analogs on HPLC, to determine the diastereomeric complex between the chiral moiety of CSP 1 and NBD-amino acid, which is responsible for the chiral recognition. (1)H-NMR studies of a mixture of model compound of CSP 1 and NBD-Ala suggest that the diastereomeric complex is composed of two hydrogen bonding sites at the amino proton and oxygen atom, and a pi-pi interaction by the benzofurazan structure (2,1,3-benzoxadiazole) of NBD-amino acid. Furthermore CSP 1 was able to separate esters, amides and alpha-methyl amino acids derivatized with NBD-F. 相似文献
679.
Takafumi Fukushima Toshiyuki Oyama Takao Iijima Masao Tomoi Hiroshi Itatani 《Journal of polymer science. Part A, Polymer chemistry》2001,39(19):3451-3463
A soluble multiblock copolyimide without specific functional groups such as OH and COOH was prepared by a direct one‐pot polycondensation of two types of dianhydrides and diamines in the presence of γ‐valerolactone/pyridine catalyst using N‐methylpyrrolidone (NMP)/toluene mixture as a solvent. The polyimide film containing the photosensitive agent diazonaphthoquinone (DNQ) compound gave positive‐tone behavior by UV irradiation, followed by development in a mixture of ethanolamine/NMP/H2O (1/1/1 by weight). The scanning electron microscopic photograph of the resultant image showed fine patterns with about 20 μm film thickness. Its pattern forming was based on the photorearrangement of diazonaphthoquinone, a process in which the ring‐opening reaction of imide units of the polyimide with the amine used as a developer and the following degradation of the polymer are induced. Such a new imaging technique combines principles of photolithography and etching of a polyimide to give, what we call, reaction development patterning in which the main chemical reactions directly related to the pattern formation occur during development. © 2001 John Wiley & Sons, Inc. J Polym Sci Part A: Polym Chem 39: 3451–3463, 2001 相似文献
680.
μSR spectra on the spin frustrating spinel antiferromagnet Zn(Cr
x
Ga1−x
)2O4 (x=0.9,1.0) have been measured. For x=1.0 compound, both the relaxation rate and the initial asymmetry showed distinct anomalies at the Néel temperature. The magnetic
susceptibility for the x=0.9 compound was known to have a faint peak at around 12 K, whose origin was not clear so far. Our μSR study revealed that
this temperature is the onset temperature of development of the magnetic correlation accompanied by appreciable spin fluctuations.
This revised version was published online in September 2006 with corrections to the Cover Date. 相似文献