Synthesis of Mesoporous Silica Molecular Sieves via a NovelTemplating Scheme

ThediscoveryofM41SfamilyofmesoporousmolecularsievesbyMobilresearchersI'2hasstimulatedconsiderableinterestintheuseofthesematerialsascatalysts,catalystsupports,aswellasadsorbents3'#.Intheoriginalreport"=,MCM-41waspreparedfromaself-assemblyprocesswhichinvolveselectrostaticinteractionsbetweenpositivelychargedquaternaryammoniummicelles(S )andinorganicanions(l-)usedasframeworkprecursors.Huoetal5extendedtheelectrostaticassemblyapproachesbyproposingfourcomplementarysynthesisschemes(S l-,S-I ,S X-…     

Experimental Investigation of Heat Transfer for a Jet Impinging Obliquely on a Flat Surface

An experimental study investigated the effects of the inclination of an impinging circular jet on heat transfer from a horizontal flat plate. Local Nusselt number distribution was determine depending on inclination angle, jet-to-plate distance, and Reynolds number. The results show that the maximum heat transfer point moves toward the uphill side of the plate and that the maximum heat transfer decreases as the inclination angle decreases. The correlations were conducted to predict maximum and local Nusselt number as a function of Re, θ, L/D, and x/D for three specific regions.     

空间非均匀啁啾双色场驱动下氦离子的高次谐波以及孤立阿秒脉冲的产生

本文理论上研究了初态为基态与第一激发态等权叠加的一维氦离子在空间非均匀啁啾双色场驱动下氦离子的高次谐波发射及孤立阿秒脉冲的产生. 研究表明, 一维氦离子在空间非均匀啁啾双色场驱动下发射的高次谐波相对于均匀场情况截止位置得到明显扩展, 得到了光滑的超连续谱,并应用半经典三步模型解释了高次谐波发射的物理机理. 通过小波变换的方法对连续谱进行了时频分析, 并且与电子的经典运动轨迹进行了对比分析, 结果显示在空间非均匀场中长量子轨道消失, 短量子轨道加强. 讨论了空间非均匀啁啾双色场中时间延迟对谐波和孤立阿秒脉冲产生的影响, 发现适当调整时间延迟值可以得到较大延展的光滑的超连续谐波谱, 本方案中时间延迟为t₀=1.6πup/ω₁时得到了最大延展, 通过对谐波中600次到680次(80次)谐波合成得到32 as的孤立脉冲.     

基于电磁感应的脉冲功率发生器试验研究

为了验证基于电磁感应原理的脉冲发生器的可行性,设计了一种小型脉冲发生器试验模型。对发生器的初始磁场与磁芯转变过程进行了分析与计算,建立了发生器的等效电路模型,并结合试验测量的负载电阻电压得出发生器的感应电压。设计的发生器整体直径约70mm,长度约85mm,其中磁芯直径为25mm,长度为25mm,提供初始磁场的永磁体厚度为10mm,试验得出发生器感应电压峰值为784.5V,与理论计算结果基本吻合,验证了发生器的可行性。     

Polymorphism in 3‐acetyl‐4‐hydroxy‐2H‐chromen‐2‐one

A new polymorph (denoted polymorph II) of 3‐acetyl‐4‐hydroxy‐2H‐chromen‐2‐one, C₁₁H₈O₄, was obtained unexpectedly during an attempt to recrystallize the compound from salt–melted ice, and the structure is compared with that of the original polymorph (denoted polymorph I) [Lyssenko & Antipin (2001). Russ. Chem. Bull. 50 , 418–431]. Strong intramolecular O—H...O hydrogen bonds are observed equally in the two polymorphs [O...O = 2.4263 (13) Å in polymorph II and 2.442 (1) Å in polymorph I], with a slight delocalization of the hydroxy H atom towards the ketonic O atom in polymorph II [H...O = 1.32 (2) Å in polymorph II and 1.45 (3) Å in polymorph I]. In both crystal structures, the packing of the molecules is dominated and stabilized by weak intermolecular C—H...O hydrogen bonds. Additional π–π stacking interactions between the keto–enol hydrogen‐bonded rings stabilize polymorph I [the centres are separated by 3.28 (1) Å], while polymorph II is stabilized by interactions between α‐pyrone rings, which are parallel to one another and separated by 3.670 (5) Å.     

Circular dichroism induced by Fano resonances in planar chiral oligomers

We present a general theory of circular dichroism in planar chiral nanostructures with rotational symmetry. It is demonstrated, analytically, that the handedness of the incident field's polarization can control whether a nanostructure induces either absorption or scattering losses, even when the total optical loss (extinction) is polarization‐independent. We show that this effect is a consequence of modal interference so that strong circular dichroism in absorption and scattering can be engineered by combining Fano resonances with planar chiral nanoparticle clusters.

     

An improved customer lifetime value model based on Markov chain

Firms are increasingly looking to provide a satisfactory prediction of customer lifetime value (CLV), a determining metric to target future profitable customers and to optimize marketing resources. One of the major challenges associated with the measurement of CLV is the choice of the appropriate model for predicting customer value because of the large number of models proposed in the literature. Earlier models to forecast CLV are relatively unsuccessful, whereas simple models often provide results which are equivalent or even better than sophisticated ones. To predict CLV, Rust et al. (2011) proposed a framework model that performs better than simple managerial heuristic models, but its implementation excludes cases where customer's profit is negative and does not handle lost‐for‐good situations. In this paper, we propose a modified model that handles both negative and positive profits based on Markov chain model (MCM), hence offering a greater flexibility by covering always‐a‐share and lost‐for‐good situations. The proposed model is compared with the Pareto/Negative Binomial Distribution (Pareto/NBD), the Beta Geometric/Negative Binomial Distribution (BG/NBD), the MCM, and the Rust et al. (2011) models. Based on customer credit card transactions provided by the North African retail bank, an empirical study shows that the proposed model has better forecasting performance than competing models. Copyright © 2014 John Wiley & Sons, Ltd.