Effect of tones on vocal attack time in Cantonese speakers

Vocal attack time (VAT) is the time lag between the growth of the sound pressure signal and the development of physical contact of vocal folds at vocal initiation. It can be derived by a cross-correlation of short-time amplitude changes occurring in the sound pressure and electroglottographic (EGG) signals. Cantonese is a tone language in which tone determines the lexical meaning of the syllable. Such linguistic function of tone has implications for the physiology of tone production. The aim of the present study was to investigate the possible effects of Cantonese tones on VAT. Sound pressure and EGG signals were simultaneously recorded from 59 native Cantonese speakers (31 females and 28 males). The subjects were asked to read aloud 12 disyllabic words comprising homophone pairs of the six Cantonese lexical tones. Results revealed a gender difference in VAT values, with the mean VAT significantly smaller in females than in males. There was also a significant difference in VAT values between the two tone categories, with the mean VAT values of the three level tones (tone 1, 3, and 6) significantly smaller than those of the three contour tones (tone 2, 4, and 5). The findings support the notion that norms and interpretations based on nontone European languages may not be directly applied to tone languages.     

Formation of N719 dye multilayers on dye sensitized solar cell photoelectrode surfaces investigated by direct determination of element concentration depth profiles

The structure of the dye layer adsorbed on the titania substrate in a dye-sensitized solar cell is of fundamental importance for the function of the cell, since it strongly influences the injection of photoelectrons from the excited dye molecules into the titania substrate. The adsorption isotherms of the N719 ruthenium-based dye were determined both with a direct method using the depth profiling technique neutral impact collision ion scattering spectroscopy (NICISS) and with the standard indirect solution depletion method. It is found that the dye layer adsorbed on the titania surface is laterally inhomogeneous in thickness and there is a growth mechanism already from low coverage levels involving a combination of monolayers and multilayers. It is also found that the amount of N719 adsorbed on the substrate depends on the titania structure. The present results show that dye molecules in dye-sensitized solar cells are not necessarily, as presumed, adsorbed as a self-assembled monolayer on the substrate.     

Chutes and Ladders in Markov Chains

We investigate how the stationary distribution of a Markov chain changes when transitions from a single state are modified. In particular, adding a single directed edge to nearest neighbor random walk on a finite discrete torus in dimensions one, two, or three changes the stationary distribution linearly, logarithmically, or only locally. Related results are derived for birth and death chains approximating Bessel diffusions and for random walk on the Sierpinski gasket.     

Combined Photoredox and Carbene Catalysis for the Synthesis of Ketones from Carboxylic Acids**

As a key element in the construction of complex organic scaffolds, the formation of C−C bonds remains a challenge in the field of synthetic organic chemistry. Recent advancements in single-electron chemistry have enabled new methods for the formation of various C−C bonds. Disclosed herein is the development of a novel single-electron reduction of acyl azoliums for the formation of ketones from carboxylic acids. Facile construction of the acyl azolium in situ followed by a radical–radical coupling was made possible merging N-heterocyclic carbene (NHC) and photoredox catalysis. The utility of this protocol in synthesis was showcased in the late-stage functionalization of a variety of pharmaceutical compounds. Preliminary investigations using chiral NHCs demonstrate that enantioselectivity can be achieved, showcasing the advantages of this protocol over alternative methodologies.     

‘Praying Mantis’ diffuse reflectance accessory for UV-Vis-NIR spectroscopy

Conclusion The characteristics of the PM accessory allow reflecting measurements on a new variety of samples such as fruits, vegetables, tissue cultures, fermentation broths or reagent-impregnated dip sticks currently being developed for clinical laboratories.     

On weighted heights of random trees

Consider the family treeT of a branching process starting from a single progenitor and conditioned to havev=v(T) edges (total progeny). To each edge <e> we associate a weightW(e). The weights are i.i.d. random variables and independent ofT. The weighted height of a self-avoiding path inT starting at the root is the sum of the weights associated with the path. We are interested in the asymptotic distribution of the maximum weighted path height in the limit asv=n. Depending on the tail of the weight distribution, we obtain the limit in three cases. In particular ify ² P(W(e)> y)0, then the limit distribution depends strongly on the tree and, in fact, is the distribution of the maximum of a Brownian excursion. If the tail of the weight distribution is regularly varying with exponent 0<2, then the weight swamps the tree and the answer is the asymptotic distribution of the maximum edge weight in the tree. There is a borderline case, namely,P(W(e)> y)cy ^–2 asy, in which the limit distribution exists but involves both the tree and the weights in a more complicated way.     

The Application of Scientific Methodology to a Contemporary Sports Journal

Often neglected as a foundation for scientific inquiry are contemporary sports journals and the articles contained within them. It is common to encounter authoritative assertions by various authors that are in truth ordinary suppositions infrequently based on tenable scientific data. This article outlines a model for transforming an ordinary factual statement, taken from a recent sporting journal, into an educational experience that includes experimental design, supporting documentation, methods of experimental verification, and the scientific method as a whole.     

Pretreatment of corn fiber by pressure cooking in water

The pretreatment of corn fiber using liquid water at temperatures between 220 and 260°C enhances enzymatic hydrolysis. This paper describes the laboratory reactor system currently in use for cooking of corn fiber at temperatures ranging from 200 to 260°C. The corn fiber at approx 4.4% solid/liquid slurry was treated in a 2-L, 304 SS, Parr reactor with three turbine propeller agitators and a Proportional-Integral-Derivative (PID), controller that controlled temperature within ±1°C. Heat-up times to the final temperatures of 220, 240, or 260°C were achieved in 50 to 60 min. Hold time at the final temperature was less than 10 s. A serpentine cooling coil, through which tap water was circulated at the completion of the run, cooled the reactor’s contents to 180°C within 2 min after the maximum temperature was attained. Ports in the reactor’s head plate facilitated sampling of the slurry and monitoring the pH. A continuous pH monitoring system was developed to help observe trends in pH during pretreatment and to assist in the development of a base (2.0M KOH) addition profile to help keep the pH within the range of 5.0 to 7.0. Enzymatic hydrolysis gave 33 to 84% conversion of cellulose in the pretreated fiber to glucose compared to 17% for untreated fiber.     

Enantioselective partial reduction of 2,5-disubstituted pyrroles via a chiral protonation approach

[reaction: see text] The partial reduction of 2,5-pyrrole diester 1 followed by enantioselective protonation in situ to furnish synthetically useful building blocks is described. An enantiomeric excess of up to 74% was achieved using (-)-ephedrine and related analogues as chiral proton sources. The pyrroline product obtained could be recrystallized to give enantiomerically pure material.