Thermometrie

Ohne Zusammenfassung     

Ueber die Occlusion von Gasen durch Metalloxyde

Ohne Zusammenfassung     

Relative weights for frequency glide detection using narrowband noise

Narrowband noise stimuli were used to derive relative weights for detecting frequency glides in a yes/no procedure. One stimulus set was restricted to the duration of the glide. For the second stimulus set, there were fringe noise bands preceding and following the glide. For both sets, the center frequency of the linear glide was either fixed at 1000 Hz or randomly chosen on each trial from the range of 800-1200 Hz. Relative weights as a function of time were derived using a linear model and the linear classification method [A. Ahumada, J. Vis., 2, 121-131 (2002)]. Sensitivity was better for the fixed- than random-frequency conditions, and weight patterns from the random-frequency conditions were less reliable than those obtained from the fixed-frequency conditions. The magnitudes of the relative weights tended to be larger for the second half of the stimulus, suggesting that subjects paid more attention to the later than the earlier parts of stimuli. In the random-frequency conditions, the linear model failed to account for subjects' performance unless the stimuli were expressed in terms of relative changes in frequency rather than absolute frequency.     

The plastic deformation of non-homogeneous polycrystals

To describe the work hardening process of polycrystals processed using various thermomechanical cycles with isochronal annealing from 500 to 900 °C, a dislocation based strain hardening model constructed in the basis of the so-called Kocks–Mecking model is proposed. The time and temperature dependence of flow stress is accounted via grain boundary migration, and the migration is related to annihilation of extrinsic grain boundary dislocations (EGBD’s) by climb via lattice diffusion of vacancies at the triple points. Recovery of yield stress is associated with changes in the total dislocation density term ρ^T. A sequence of deformation and annealing steps generally result in reduction of flow stress via the annihilation of the total dislocation density ρ^T defined as the sum of geometrically necessary dislocations ρ^G and statistically stored dislocations ρ^S. The predicted variation of yield stress with annealing temperature and cold working stages is in agreement with experimental observations. An attempt is made to determine the mathematical expressions which best describe the deformation behaviour of polycrystals in uniaxial deformation.     

The System HCl + NdCl3 + H2O from 5 to 55 ∘C: A Study of Harned's Rule

The activity coefficients of HCl (γ_A) in aqueous mixtures of HCl and NdCl₃ were determined by the electromotive-force (emf) measurement of cells without liquid junctions of the type:

Versatile solid-phase synthesis of trisubstituted 1H-pyrido[2,3-d]pyrimidin-4-ones and related heterocycles

A solid-phase synthesis of trisubstituted 1H-pyrido[2,3-d]pyrimidin-4-ones has been developed. The synthesis utilizes solid-phase bound N-2,6-dichloronicotinoyl-1H-benzotriazole-1-carboximidamides as key intermediates. Sequential substitution of benzotriazole and the two chlorines furnishes the title compounds with regioselectivity and high purity. Application of the method to various disubstituted analogues is also demonstrated.     

Informational masking with small set sizes

Informational masking refers to interference in the detectability of a sound, or discrimination of some property of a sound, beyond that which can be attributed to interactions at the auditory periphery. In the current experiments the signal to be detected was a tone added to a 6-tone masker, and informational masking was introduced by randomly choosing the frequencies of the tones that comprise the masker. The primary question was whether small numbers of maskers could replace randomly drawn maskers without sacrificing the underlying detection schemes adopted by observers. Similar to the method used by Wright and Saberi [J. Acoust. Soc. Am. 105, 1765-1775 (1999)], detection thresholds were measured for different masker set sizes, where set size refers to the number of 6-tone maskers from which any one masker was drawn. Set sizes of 3, 6, 12, and 24 were tested as well as conditions in which the maskers were chosen at random. In addition, observers' memory for maskers was coarsely evaluated. Large differences in thresholds were found across observers and across different masker sets. Even for set sizes of 24, the memory test suggests some recognition of maskers for some observers. Post hoc analysis of the data included an evaluation of the relative contribution of different frequencies using a single linear model. As a base for comparison, a linear model fitted to each condition was also evaluated. Although the data were fitted better using many rather than one linear model, the reduction in quality of fit was modest. This result suggests substantial consistency in decision strategies regardless of masker set size.