Thiol–norbornene materials: Approaches to develop high Tg thiol–ene polymers

The ability to prepare high T_g low shrinkage thiol–ene materials is attractive for applications such as coatings and dental restoratives. However, thiol and nonacrylated vinyl materials typically consist of a flexible backbone, limiting the utility of these polymers. Hence, it is of importance to synthesize and investigate thiol and vinyl materials of varying backbone chemistry and stiffness. Here, we investigate the effect of backbone chemistry and functionality of norbornene resins on polymerization kinetics and glass transition temperature (T_g) for several thiol–norbornene materials. Results indicate that T_gs as high as 94 °C are achievable in thiol–norbornene resins of appropriately controlled chemistry. Furthermore, both the backbone chemistry and the norbornene moiety are important factors in the development of high T_g materials. In particular, as much as a 70 °C increase in T_g was observed in a norbornene–thiol specimen when compared with a sample prepared using allyl ether monomer of analogous backbone chemistry. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5686–5696, 2007     

Small Exotic Molecules with Bosonic Constituents

We study the stability and the properties of the ground state of neutral systems containing up to four positively charged bosons and their antiparticles. Examples are the di-pionium molecule (π ⁺ π ⁻)², which is almost identical to the positronium molecule (e ⁺ e ⁻)², the tri-pionium (π ⁺ π ⁻)³, and the quadri-pionium (π ⁺ π ⁻)⁴ molecules. We briefly compare our results on the energy to those on the large-N limit of (π ⁺ π ⁻) ^N . We also show that the annihilation probability can be calculated accurately with simple wave functions when one uses the generalized Schwinger rule. Received September 5, 1994; accepted for publication October 15, 1994     

Non-homogeneous equations of the thermoacoustics: Thermally forced radial thermo-elastic oscillations of the visco-thermal fluid sphere

The purpose of this paper is to solve the coupled non-homogeneous equations derived from the basic classical theory of the acoustic propagation in visco-thermal fluid. The 1D radial distribution of pressure and temperature inside a spherical object was found. It is supposed that both acoustic and thermal conditions on a surface of the object are known. The starting equations are considered in the time domain and their solution was found without initial conditions for steady harmonic motion.     

Thermotropic liquid-crystalline behaviour from mixtures of non-mesogenic molecules

A class of non-mesogenic molecules, which as mixtures exhibit monotropic nematic phases, is described.