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51.
Richard A. Cairncross Jeffrey G. Becker Shri Ramaswamy Ryan O'Connor 《Applied biochemistry and biotechnology》1996,131(1-3):774-785
Management of moisture penetration and hydrolytic degradation of polylactide (PLA) is extremely important during the manufacturing,
shipping, storage, and end-use of PLA products. Moisture transport, crystallization, and degradation, in PLA have been measured
through a variety of experimental techniques including size-exclusion chromatography, differential scanning calorimetry, and
X-ray diffraction. Quartz crystal microbalance and dynamic vapor sorption experiments have also been used to measure moisture
sorption isotherms in PLA films with varying crystallinity. A surprising result is that, within the accuracy of the experiments,
crystalline and amorphous PLA films exhibit identical sorption isotherms. 相似文献
52.
Jon Samseth Richard J. Spontak Kell Mortensen 《Journal of Polymer Science.Polymer Physics》1993,31(4):467-474
Poly(siloxaneimide) (PSI) segmented copolymers exhibit organized microdomains if the blocks are sufficiently incompatible. As with neat diblock and triblock copolymers, the processing route employed to prepare films of PSI materials is expected to influence the dimensions and/or morphology of the resultant microstructure. In this work, small-angle neutron scattering (SANS) is utilized to characterize the disordered microstructure found in films of a series of PSI copolymers which are subjected to solvent casting and various thermal treatments. Microstructural dimensions such as the periodicity and correlation length are deduced from the Teubner-Strey (TS) model for disordered microemulsions. The scattering intensity of each copolymer up to q = 5.0 nm?1, where q is the scattering vector, is found to scale as q?2.8+?0.1. Results indicate that processing the materials as cast films or as melt-pressed films allowed to cool slowly has a small, but discernible, effect on microstructural characteristics. SANS profiles of films quenched from elevated temperatures reveal a clear transition in microdomain periodicity, which correlates well with the glass transition temperature of the imide microphase in these and other materials of similar chemical structure. © 1993 John Wiley & Sons, Inc. 相似文献
53.
The complete convergence theorem implies that starting from any initial distribution the one dimensional contact process converges to a limit ast. In this paper we give a necessary and sufficient condition on the initial distribution for the convergence to occur with exponential rapidity.This work was discussed while the authors were visiting the Nankai Mathematics Institute in Tianjin.Partially supported by the National Science Foundation, the Army Research Office through the Mathematical Sciences Institute at Cornell University, and a Guggenheim fellowship.Research supported by the National Science Foundation of China. 相似文献
54.
Richard Valenta 《Czechoslovak Journal of Physics》1990,40(10):1117-1122
In this article, homogeneous Parker's equation is solved. Relations for temperature, velocity and pressure are found. The possibility of low frequency approximation is shown and thermoacoustic effect in gas near plane motionless wall is treated.I would like to thank Prof. Zdenk kvor for his interest and encouragement. 相似文献
55.
William W. Paudler Richard A. Vandahm Young N. Park 《Journal of heterocyclic chemistry》1972,9(1):81-85
The diazaanalog of “cycl[3,2,2]azine”, “1,4-diazacycl[3,2,2]azine” (1,4,7b-triazacyclopent-[cd]indene) and its 2-methyl derivative were prepared. These compounds are subject to facile acid-catalyzed hydrolysis affording substituted imidazo[1,2-a]pyridines. 相似文献
56.
Richard Neu 《Fresenius' Journal of Analytical Chemistry》1954,143(1):30-38
Ohne ZusammenfassungII. Mitteilung: R. Neu 7. 相似文献
57.
58.
59.
Richard Neu 《Fresenius' Journal of Analytical Chemistry》1956,151(5):328-332
Ohne ZusammenfassungVIII. Mitt. Über Tetraphenyl-diboroxyd.VII. Mitt. Vgl. Naturwissenschaften 43, 82 (1956).Verf. dankt Frl. Elisabeth Buhl für zuverlässige und eifrige Mitarbeit. 相似文献
60.
Bernard A. Mikrut Krishan K. Khullar Pamela Y. P. Chan John M. Kokosa Ludwig Bauer Richard S. Egan 《Journal of heterocyclic chemistry》1974,11(5):713-718
The reaction of pyridine 1-oxide with 1-adamantanethiol in acetic anhydride produced a mixture of 2- and 3-(1-adamantanethio)pyridines, 1-aeetyl-2-(1-adamantanethio)-3-hydroxy-4-acetoxy-1,2,3,4-telrahydropyridine and the corresponding 3-acetoxyderivative. Pure substances were separated by means of column chromatography on alumina. The tetrahydropyridines were identified by means of their proton magnetic and mass spectra. 4-(1-Adamantanethio)pyridine was synthesized from 4-chloropyridinc and 1-adamantanethiol. The three isomeric (1-adamantanethio)-pyridines were, each, cleaved by concentrated hydrochloric acid to give 1-chloroadamantane and the corresponding pyridinethiol. 相似文献