Farbstoffe

Ohne Zusammenfassung     

An interlaboratory study of potassium determination in rocks and minerals

Seven laboratories took part in this interlaboratory study which was part of an investigation of the flame-speetrometric determination of potassium in rocks and minerals suitable for potassium-argon age-measurement. Three of these laboratories determined potassium in the following five international reference rocks: tonalite T-1, basalt BCR-1, andesite AGV-1, granite G-2, and granodiorite GSP-1. The other five samples (with the number of laboratories analysing them in parentheses) were: a chlorite rock (7), an altered basic igneous rock (5), an altered basaltic andesite (5), a biotite (6) and a potassium feldspar (7). Details of sample preparation and methods of analysis are given; no laboratory used exactly the same method as any of the other six laboratories. Results have been examined by analysis of variance; larger relative between- and within-laboratory variations occurred for the two samples containing less than 0.1% potassium than for seven of the eight other (higher potassium) samples; between-laboratory variations for the basalt BCR-1 and, to a lesser extent, the andesite AGV-1, were high and of similar magnitude to those for the samples containing less than 0.1% potassium. The causes of any poor interlaboratory agreement in the present study are considered.     

Thermodynamics of the quasi-static growth of Griffith cracks

Restrictions on the quasi-static extension, or healing, of Griffith cracks are developed in the framework of irreversible thermodynamics. It is emphasized that thermodynamics requires that (G ? 2γ)ι ? 0, where ι is crack speed, G the Irwin energy release rate, and 2γ the work of reversible separation of the surfaces to be fractured. Implications for ‘lattice trapping’ models of cracks and for thermally-activated crack motion are discussed, as are the effects on crack growth and healing of a surface-reactive environment, in which case γ must be given a definition appropriate to adsorption-altered surface properties.     

Oscillatory disruptions in the Alcator C tokamak

Periodic disruptions were observed which persisted for as long as 400 ms during plasma discharges. Soft X-ray emissions, T_e, n_e, impurity radiation and plasma position showed the pulsations. The abrupt collapse in X-ray signal (1–2 ms; period ∽10 ms) encompassed a large fraction of the plasma cross section. Plasma conditions associated with the onset of this pattern are examined.     

Elastic scattering of electrons by hydrogen molecules at intermediate energies

Several quantum mechanical calculations of differential cross sections for elastic scattering of electrons by H₂ are compared with the recent experiments by Williams.     

Ab initio studies of the structures and force fields of ketenimine and related molecules

Theoretical equilibrium geometries for ketenimine, aminoacetylene and ethynol have been obtained using the MP3/6-31G** ab initio method. Empirical scaling factors have been introduced to estimate the rotational constants A_o, B_o and C_o. In addition the complete harmonic force fields for ketenimine, ketene and diazomethane have been computed, normal coordinate analyses have been performed and the quartic centrifugal distortion constants estimated.     

直接键连原子间的NMR偶合常数的自然杂化轨道研究V.~(13)C-~(13)C和~(13)C-~(31)P核自旋偶合常数~1J_(CC)和~1J_(CP)

在前文工作的基础上，结合ＭＮＤＯ／ＥＨＭＯ分子轨道方法和自然杂化轨道方法，具体计算了ＣＣ键和ＣＰ键的核自旋偶合常数．计算结果表明，１ＪＣＣ和１ＪＣＰ主要由成键原子的轨道杂化作用和键极性这两种结构因素所决定．为从简单价键理论角度解释和计算１ＪＣＣ和１ＪＣＰ值提供了简便直观的方法．     

A study of the reaction K−p→Λπ+π− at c.m. energies in the range 1.65 to 1.72 GeV

Results are presented of a study of the reaction K^?p→Λπ⁺π^? in the c.m. energy region of 1.65 to 1.72 GeV. Dalitz plots indicate that the reaction proceeds primarily through the intermediate states Σ^?(1385)π⁺ and Σ^?(1385)π⁺, but the resonance bands intersect inside the kinematic ellipse and a simple quasi-two-body interpretation is not possible. Legendre coefficients are presented for the angular distributions of the Λπ⁺ and Λπ^? sub-systems in the overall c.m. frame. Analogous coefficients as suggested by Deler and Valladas, which describe the angular distribution of the final three-body state are also presented.