HPTLC Determination of Catechins in In-Vitro Cultures of Two Species of the Genus Phyllanthus

JPC – Journal of Planar Chromatography – Modern TLC - Densitometric HPTLC has been used for determination of catechins in shoot and callus cultures of two species from the genus...     

Monomiality and partial differential equations

We show that the combination of the formalism underlying the principle of monomiality and of methods of an algebraic nature allows the solution of different families of partial differential equations. Here we use different realizations of the Heisenberg–Weyl algebra and show that a Sheffer type realization leads to the extension of the method to finite difference and integro-differential equations.     

Modelling population growth vialaguerre-type exponentials

We use the Laguerre-type exponentials, i.e., eigenfunctions of the Laguerre-type derivatives, in order to construct new models for population growth. Relevant modifications of the classical exponential, logistic, and Volterra-Lotka models are investigated.     

Efficient hollow fiber compression scheme for generating multi-mJ,carrier-envelope phase stable,sub-5 fs pulses

We show that a standard hollow-core fiber (HCF) compressor device can be used to efficiently compress multi-mJ energy laser pulses down to few-cycle duration, when seeded with linearly chirped, circularly polarized pulses. With this approach, we routinely generate carrier-envelope phase (CEP)-locked, 1.6 mJ, 4.8 fs pulses using only 3 mJ, 25 fs pulses as the seed.     

Cryogenics and Einstein Telescope

The dominant noises which limit the present sensitivity of the gravitational wave detectors are the thermal noise of the suspended mirrors and the shot noise. For the third generation of gravitational wave detectors as the Einstein Telescope (ET), the reduction of the shot noise implies to increase the power stored in the detector at 1 MW level and, at the same time, to compensate the huge optic distortion due to induced thermal lensing. At low temperature it is possible to reduce both these effects. However, lowering the temperature of the test masses without injecting vibration noise from the cooling system is a technological challenge. We review here the thermal noise impact on the ultimate ET sensitivity limit and we discuss possible cryogenic configurations to cool the mirror.     

Reconstitution of aluminium and iron core in horse spleen apoferritin

This study investigates the uptake of iron and aluminium by apoferritin. In particular, we provide the first evidence that apoferritin is able to bind in vitro the physiological form of aluminium, Al(OH)₄ ^?, to reach an Al/Fe atomic ratio of about 0.15. Mass spectrometry analysis shows that the Al content increases linearly as a function of Al concentration in solution. These findings provide a better understanding of the Al uptake in vivo, confirming that the metal content of ferritin depends on the metal bio-availability.     

Mechanochemical Reactions from Individual Impacts to Global Transformation Kinetics

Typically induced by the mechanical processing of powders in ball mills, mechanochemical transformations are considered to result from the application of mechanical force to solid reactants. However, the undeniable deep connection between the dynamic compaction of powders during impacts and the overall transformation degree has yet to be disclosed. In the present work, we show that the square planar bis(dibenzoylmethanato)Ni^II coordination compound undergoes trimerization when its powder experiences even a single ball impact. Based on systematic experiments with individual ball impacts and analysis by Raman spectroscopy, we provide here quantitative mapping of the transformation in the powder compact and deduce bulk reaction kinetics from multiple individual impacts.     

Recent advances in the field of diolefin polymerization with transition metal catalysts

Recent advances in the field of catalysis for 1,3-diene polymerization and in the interpretation of the polymerization mechanism are examined. Catalysts prepared from methylaluminoxanes and soluble transition metal compounds are in general more active than the analogous systems prepared from AlR₃. With some catalysts, however, (e.g. lanthanide systems) a high activity is obtained only when transition metal compounds containing preformed metal-carbon bonds are used. Methylaluminoxanes affect also the stereospecificity of the polymerization. Active and stereospecific systems are obtained from monocyclopentadienyl derivatives of Ti and aluminoxanes. Recent views on the factors that determine stereospecificity are examined. Schemes are presented for the formation of iso- or syndiotactic polymers, with 1,2, cis-1,4 or trans-1,4 structure, from various dienes.