Privacy-preserving data splitting: a combinatorial approach

Privacy-preserving data splitting is a technique that aims to protect data privacy by storing different fragments of data in different locations. In this work we give a new combinatorial formulation to the data splitting problem. We see the data splitting problem as a purely combinatorial problem, in which we have to split data attributes into different fragments in a way that satisfies certain combinatorial properties derived from processing and privacy constraints. Using this formulation, we develop new combinatorial and algebraic techniques to obtain solutions to the data splitting problem. We present an algebraic method which builds an optimal data splitting solution by using Gröbner bases. Since this method is not efficient in general, we also develop a greedy algorithm for finding solutions that are not necessarily minimally sized.

     

Some Novel Cobalt Diphenylphosphine Complexes: Synthesis,Characterization, and Behavior in the Polymerization of 1,3-Butadiene

Some novel cobalt diphenylphosphine complexes were synthesized by reacting cobalt(II) chloride with (2-methoxyethyl)diphenylphosphine, (2-methoxyphenyl)diphenylphosphine, and 2-(1,1-dimethylpropyl)-6-(diphenylphosphino)pyridine. Single crystals suitable for X-ray diffraction studies were obtained for the first two complexes, and their crystal structure was determined. The novel compounds were then used in association with methylaluminoxane (MAO) for the polymerization of 1,3-butadiene, and their behavior was compared with that exhibited in the polymerization of the same monomer by the systems CoCl₂(PⁿPrPh₂)₂/MAO and CoCl₂(PPh₃)₂/MAO. Some significant differences were observed depending on the MAO/Co ratio used, and a plausible interpretation for such a different behavior is proposed.     

Cholinesterase sensors based on screen-printed electrodes for detection of organophosphorus and carbamic pesticides

Cholinesterase sensors based on screen-printed electrodes modified with polyaniline, 7,7,8,8-tetracyanoquinodimethane (TCNQ), and Prussian blue have been developed and tested for detection of anticholinesterase pesticides in aqueous solution and in spiked grape juice. The influence of enzyme source and detection mode on biosensor performance was explored. It was shown that modification of the electrodes results in significant improvement of their analytical characteristics for pesticide determination. Thus, the slopes of the calibration curves obtained with modified electrodes were increased twofold and the detection limits of the pesticides were reduced by factors of 1.6 to 1.8 in comparison with the use of unmodified transducers. The biosensors developed make it possible to detect down to 2×10^–8 mol L^–1 chloropyrifos-methyl, 5×10^–8 mol L^–1 coumaphos, and 8×10^–9 mol L^–1 carbofuran in aqueous solution and grape juice. The optimal conditions for grape juice pretreatment were determined to diminish interference from the sample matrix.Abbreviations ChE Cholinesterase - TCNQ 7,7,8,8-Tetracyanoquinodimethane - ChO Choline oxidase - AChE Acetylcholinesterase - BChE Butyrylcholinesterase - BSA Bovine serum albumin - 2-PAM 2-Pyridine aldoxime methiodide     

Time-scale and excitation energy partition in sequential binary decays induced by heavy-ion collisions at ≃6 MeV·A

We studied the sequential binary decay of the systems ³²S+⁴⁵Sc, ⁷⁶Ge, ⁸⁹Y, ⁵⁹Co, ⁶³Cu and ¹⁹F+⁶³Cu induced by collisions at ≃6 MeV·A. The two stages of the process have reaction-times compatible with the dynamics of different mechanisms. The study of the excitation energy partition shows that the reaction mechanism of the first step has influence on the de-excitation of the primary fragments producing two decay components which have different time scale. Received: 25 March 1997 / Revised version: 2 December 1997     

Accreditation of reference material producers: the example of IRMM's Reference Materials Unit

The potential approaches for third-party assessment of reference material producers are revisited and the activities of the Reference Materials (RM) Unit of the Institute for Reference Materials and Measurements (IRMM) to obtain accreditation to ISO Guide 34 and ISO 17025 are described. Accreditation was related to the Unit as all matrix RM activities of the institute are concentrated there. A management system was established that allows sufficient flexibility to be applicable to a wide range of RMs while being precise enough to ensure compliance with ISO Guides 30, 31 and especially 34 and 35. Accreditation was achieved in 2004 with independent scopes for testing and RM production and was confirmed and extended in 2005. The key aspects of the RM Unit's management system for RM production are presented. Presented at BERM-10, April 2006, Charleston, SC, USA     

Projectile-like fragments excitation and gamma-rays emission after the deep inelastic reaction of32S on58Ni

The deep-inelastic reaction induced by 143 MeV³²S on⁵⁸Ni have been studied detecting projectile-like fragments (PLF) in coincidence withγ-rays in NaI(TI) scintillators. γ-ray multiplicity and anisotropy have been derived for Z_plf=14, 15 as a function of energy loss and/or γ-energy. The information obtained are compared with a discrete γ-line study of the same reaction. The effect of the exit channel selection (ejectileZ, energy loss,E _γ) on the γ-observables is discussed in connection with the evidence of a strong PLF γ-emission.     

EPR evidence of a triplet biradical in the photolysis of nifedipine

UV irradiation of nifedipine leads to of triplet biradicals that can be detected by means of EPR spectroscopy.     

Preparation of a second station for the measurement of solar oscillations of low degree

Summary An observing station to detect low-degree global solar oscillations is already operational at Jet Propulsion Laboratory (Pasadena, CA-USA). In collaboration with Reparto Raggi Cosmici, I.F.S.I.-C.N.R., a second station for continuative measurements of such oscillations has recently been installed and successfully tested in Rome. The high transmission and stability of the magneto-optical filter (MOF) coupled with the lock-in amplifier technique allow analogic and real time detection of oscillation modes with a noise level of only a few cm/s. We show observing runs and estimates of the signal-to-noise ratio in time and frequency domains. Routine observations will establish whether the MOF sensitivity and stability is suitable to detect stellar oscillations. To speed up publication, the proofs were not sent to the authors and were supervised by the Scientific Committee.