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71.
The orthorhombic crystal structure of [Co2(CO)6(μ‐CO)(μ‐C4O2H2)] ( 1 ) was determined at 150 K (Fig. 1). Two C−H⋅⋅⋅O bonds connect the molecules, forming waving ribbons along the b axis. The experimental electron density, determined with the aspherical‐atom formalism, was analyzed with the topological theory of molecular structure. The presence of the Co−Co bond critical point indicates for the first time the existence of a metal−metal bond in a system with bridged ligands. The bond critical properties of the intramolecular bonds and of the intermolecular interactions show features similar to those found in [Mn2(CO)10], confirming our previously established bonding classification for organometallic and coordination compounds. 相似文献
72.
73.
Riccardo Flamini Mirko De Rosso Annarita Panighel Antonio Dalla Vedova Fabiola De Marchi Luigi Bavaresco 《Journal of mass spectrometry : JMS》2014,49(12):1214-1222
A ‘suspect screening analysis’ method for grape metabolomics by ultra‐high performance‐liquid chromatography (UHPLC) and high‐resolution quadrupole‐time of flight (QTOF) mass spectrometry was recently developed. This method was applied to study grape monoterpene glycosides, the main grape aroma precursors. Since standard compounds were not available, they were tentatively identified by overlapping various analytical approaches, in agreement with the indications recommended in mass spectrometry (MS)‐based metabolomics. Accurate mass and isotopic pattern, MS/MS fragmentation, correlation between fragments observed and putative structures and between liquid chromatography coupled with mass spectrometry (LC/MS) and gas chromatography/mass spectrometry signals were studied. Seventeen monoterpene glycosides were identified without performing the hydrolytic artifacts commonly used to study these compounds which may affect sample profile. This is the first time that a detailed study of these aroma precursors has been carried out by direct LC/MS analysis. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
74.
Luca Bagnarelli Alessandro Dolmella Carlo Santini Riccardo Vallesi Roberto Giacomantonio Serena Gabrielli Maura Pellei 《Molecules (Basel, Switzerland)》2021,26(20)
A new dimeric copper(II) bromide complex, [Cu(LOHex)Br(μ-Br)]2 (1), was prepared by a reaction of CuBr2 with the hexyl bis(pyrazol-1-yl)acetate ligand (LOHex) in acetonitrile solution and fully characterized in the solid state and in solution. The crystal structure of 1 was also determined: the complex is interlinked by two bridging bromide ligands and possesses terminal bromide ligands on each copper atom. The two pyrazolyl ligands in 1 coordinate with the nitrogen atoms to complete the Cu coordination sphere, resulting in a five-coordinated geometry—away from idealized trigonal bipyramidal and square pyramidal geometries—which can better be described as distorted square pyramidal, as measured by the τ and χ structural parameters. The pendant hexyloxy chain is disordered over two arrangements, with final site occupancies refined to 0.705 and 0.295. The newly synthesized complex was evaluated as a catalyst in copper-catalyzed C–H oxidation for allylic functionalization through a Kharasch–Sosnovsky reaction without any external reducing agent. Using 0.5 mol% of this catalyst, and tert-butyl peroxybenzoate (Luperox) as an oxidant, allylic benzoates were obtained with up to 90% yield. The general reaction time was only slightly decreased to 24 h but a very significant decrease in the alkene:Luperox ratio to 3:1 was achieved. These factors show relevant improvements with respect to classical Kharasch–Sosnovsky reactions in terms of rate and amount of reagents. The present study highlights the potential of copper(II) complexes containing functionalized bis(pyrazol-1-yl)acetate ligands as efficient catalysts for allylic oxidations. 相似文献
75.
Giacomo?Saielli Riccardo?Bini Alessandro?BagnoEmail author 《Theoretical chemistry accounts》2012,131(3):1140
Fluorine-19 NMR chemical shifts have been calculated for a wide variety of fluorine-containing inorganic and organic molecules
by relativistic DFT methods. The agreement with experimental values, spanning the whole range from ClF to FOOF, is satisfactory
but somewhat less accurate than for comparable light nuclei. 19F shifts in uranium chlorofluorides have been analyzed in detail, and the poor agreement with experiment is partly rationalized. 相似文献
76.
Riccardo Zecchina 《Pramana》2005,64(6):1161-1173
The combinatorial problem of satisfying a given set of constraints that depend on N discrete variables is a fundamental one in optimization and coding theory. Even for instances of randomly generated problems, the question “does there exist an assignment to the variables that satisfies all constraints?” may become extraordinarily difficult to solve in some range of parameters where a glass phase sets in. We shall provide a brief review of the recent advances in the statistical mechanics approach to these satisfiability problems and show how the analytic results have helped to design a new class of message-passing algorithms — the survey propagation (SP) algorithms — that can efficiently solve some combinatorial problems considered intractable. As an application, we discuss how the packing properties of clusters of solutions in randomly generated satisfiability problems can be exploited in the design of simple lossy data compression algorithms. 相似文献
77.
Riccardo Rosso André M. Sonnet Epifanio G. Virga 《Continuum Mechanics and Thermodynamics》2002,14(1):127-136
kinks created in a biological membrane by the interaction with a movable bead. We arrive at the evolution equations for both the
bead and the membrane, whence we conclude that the force exerted on the bead by a fixed membrane points in the direction along
which the curvature of the membrane is more concentrated. This is the first step towards understanding the basic mechanism
behind the dynamics of protein aggregation which takes place on biological membranes.
Received November 6, 2001 / Published online February 4, 2002 相似文献
78.
Riccardo LeardiRandy J. Pell 《Analytica chimica acta》2002,461(2):189-200
Variable selection using a genetic algorithm is combined with partial least squares (PLS) for the prediction of additive concentrations in polymer films using Fourier transform-infrared (FT-IR) spectral data. An approach using an iterative application of the genetic algorithm is proposed. This approach allows for all variables to be considered and at the same time minimizes the risk of overfitting. We demonstrate that the variables selected by the genetic algorithm are consistent with expert knowledge. This very exciting result is a convincing application that the algorithm can select correct variables in an automated fashion. 相似文献
79.
Riccardo Ricceri Alessandro Abbotto Antonio Facchetti Daniela Grando Gabriella Gabrielli Giorgio A. Pagani 《Colloids and surfaces. A, Physicochemical and engineering aspects》1999,150(1-3):289-296
We report on Langmuir-Blodgett (LB) films characterization of 4-[5-dicyanomethanido)thien-2-y1]-N-(n-hexadecyl)pyridinium (C16H33-PDCNT), and 1-(N-(n-hexadecy]-4-pyridinio)-2-[5-(dicyanomethanido)thien-2-yl]ethene (C16H33-PDCNTE); LB films of the pure compounds and of the mixtures of the two compounds were prepared at 291 K: UV-vis investigation revealed the presence of photobleachable absorption bands, the ones at about 530 nm and 640 nm were due to charge transfer transitions of the monomer of C16H33-PDCNT and C16H33-PDCNTE, respectively; the sharp, photobleachable ones shifted to shorter wavelengths were due to H-aggregates of the two compounds. By changing the molar ratios of the two compounds in the mixtures and in other cases by annealing the LB films, the absorption maxima of the sharp, photobleachable bands due to H-aggregates could be tuned in the range 415–467 nm. These LB films are thus very promising in view of optical data storage applications. 相似文献
80.