Raman and Infrared Spectroscopic Study of the Borate Mineral Kaliborite

We have studied the mineral kaliborite. The sample originated from the Inder B deposit, Atyrau Province, Kazakhstan, and is part of the collection of the Geology Department of the Federal University of Ouro Preto, Minas Gerais, Brazil. The mineral is characterized by a single intense Raman band at 756 cm^?1 assigned to the symmetric stretching modes of trigonal boron. Raman bands at 1229 and 1309 cm^?1 are assigned to hydroxyl in-plane bending modes of boron hydroxyl units. Raman bands are resolved at 2929, 3041, 3133, 3172, 3202, 3245, 3336, 3398, and 3517 cm^?1. These Raman bands are assigned to water stretching vibrations. A very intense sharp Raman band at 3597 cm^?1 with a shoulder band at 3590 cm^?1 is assigned to the stretching vibration of the hydroxyl units. The Raman data are complimented with infrared data and compared with the spectrum of kaliborite downloaded from the Arizona State University database. Differences are noted between the spectrum obtained in this work and that from the Arizona State University database. This research shows that minerals stored in a museum mineral collection age with time. Vibrational spectroscopy enhances our knowledge of the molecular structure of kaliborite.     

New Interfaces and Approaches to Machine Learning When Classifying Gestures within Music

Interactive music uses wearable sensors (i.e., gestural interfaces—GIs) and biometric datasets to reinvent traditional human–computer interaction and enhance music composition. In recent years, machine learning (ML) has been important for the artform. This is because ML helps process complex biometric datasets from GIs when predicting musical actions (termed performance gestures). ML allows musicians to create novel interactions with digital media. Wekinator is a popular ML software amongst artists, allowing users to train models through demonstration. It is built on the Waikato Environment for Knowledge Analysis (WEKA) framework, which is used to build supervised predictive models. Previous research has used biometric data from GIs to train specific ML models. However, previous research does not inform optimum ML model choice, within music, or compare model performance. Wekinator offers several ML models. Thus, we used Wekinator and the Myo armband GI and study three performance gestures for piano practice to solve this problem. Using these, we trained all models in Wekinator and investigated their accuracy, how gesture representation affects model accuracy and if optimisation can arise. Results show that neural networks are the strongest continuous classifiers, mapping behaviour differs amongst continuous models, optimisation can occur and gesture representation disparately affects model mapping behaviour; impacting music practice.     

Asymptotic behavior of general M-estimates for regression and scale with random carriers

Summary Let (xini, y _i be a sequence of independent identically distributed random variables, where x _i R ^p and y _i R, and let R ^p be an unknown vector such that y _i =x _i +u _i (^*), where u _i is independent of x _i and has distribution function F(u/), where >0 is an unknown parameter. This paper deals with a general class of M-estimates of regression and scale, ( ^*,^*), defined as solutions of the system: , where r= (y _i –x _i ^1*/)^*, with R ^p ×RR and RR. This class contains estimators of (, ) proposed by Huber, Mallows and Krasker and Welsch. The consistency and asymptotic normality of the general M-estimators are proved assuming general regularity conditions on and and assuming the joint distribution of (x _i , y _i ) to fulfill the model (^*) only approximately.     

Application of the P.E.M. theory to solid electrolyte pressed powder pellets: Electrically isotropic solid electrolyte particles

The a.c. electrical response of an electrically isotropic solid electrolyte pressed powder pellet, has been calculated using the Percolation Effective Medium Theory (P.E.M.T.) approximation. The pressed powder pellet is represented by a mixture of a conducting phase (solid electrolyte) and an isolation one (air). The physical meaning of the derived results is discussed in reference to a real solid electrolyte pellet response. The pellet response calculated by the P.E.M.T. equation should correspond to the usual ‘bulk’ one. The influence of the microstructure on the pellet response, derived from the model, can be used to improve the ‘bulk’ ionic conductivity, in pressed powder pellets of solid electrolytes with isotropic conductivity, and to obtain its real electrical characteristics.     

Photophysical properties of a series of 4‐aryl substituted 1,4‐dihydropyridines

In this article, a series of Hantzsch 1,4‐dihydropyridines with different substituted aryl groups were synthesized and its spectral data obtained by UV–Vis absorption and fluorescence emission spectroscopies in solution. The dihydropyridines present absorption located around 350 nm and fluorescence emission in the blue–green region. A higher Stokes’ shift could be observed for the derivative 3b because of an intramolecular charge transfer in the excited state from the dimethylaniline to the dihydropyridine chromophores, which was corroborated by a linear relation of the fluorescence maxima (ν_max) versus the solvent polarity function (Δf) from the Lippert–Mataga correlation. A comparison between the experimental data and time‐dependent density functional theory‐polarizable continuum model calculations of the vertical transitions was performed to help on the elucidation of the photophysics of these compounds. For these calculations, the S₀ and S₁ states were optimized using Becke, three‐parameter, Lee–Yang–Parr/6‐31 G* and Configuration Interaction Singles/6‐31 G*, respectively. The predicted absorption maxima are in good agreement with the experimental; however, the theoretical fluorescence emission maxima do not match the experimental, which means that the excited specie cannot be related to neither a locally excited state nor to an aromatized structure. Copyright © 2012 John Wiley & Sons, Ltd.     

Nanocrystalline CoSn2-carbon composite electrode prepared by using sonochemistry

A sonochemical method has been used to prepare negative electrode materials containing intermetallic nanoparticles and polyacrylonitrile (PAN). The ultrasound irradiation is applied to achieve small particle size. After annealing at 490 °C under Ar-flow, the polymer PAN is partially carbonized and the metallic nanoparticles are surrounded by a carbonaceous matrix. The main metallic phase is CoSn₂. The carbonaceous coating and the surface oxides have been explored by using XPS. The resulting CoSn₂-carbonaceous phase electrode (CoSn₂@C) shows improved electrochemical behavior (ca. 450 mAh/g after 50 cycles) in comparison with previous reports on pure crystalline CoSn₂. The reaction between CoSn₂@C and Li has been studied by using XRD and ¹¹⁹Sn Mössbauer spectroscopy. The formation of large grains of crystalline Li_xSn phases after the first discharge is discarded. The small particle size which is achieved by using ultrasonication and the carbonaceous matrix contribute to maintain the Co-Sn interactions during the electrochemical cycling. The aggregation of the nanosized metallic particles upon electrochemical cycling can be suppressed by the carbonaceous matrix (pyrolytic PAN).     

A Combined Experimental and Theoretical Study on the Formation of Ag Filaments on β‐Ag2MoO4 Induced by Electron Irradiation

A combined experimental and theoretical study is presented to understand the novel observed nucleation and early evolution of Ag filaments on β‐Ag₂MoO₄ crystals, driven by an accelerated electron beam from an electronic microscope under high vacuum. The growth process, chemical composition, and the element distribution in these filaments are analyzed in depth at the nanoscale level using field‐emission scanning electron microscopy (FE‐SEM) and transmission electron microscopy (TEM) with energy‐dispersive spectroscopy (EDS) characterization. To complement experimental results, chemical stability, structural and electronic aspects have been studied systematically using first‐principles electronic structure theory within a quantum theory of atoms in molecules (QTAIM) framework. The Ag nucleation and formation on β‐Ag₂MoO₄ are a result of structural and electronic changes of the AgO₄ tetrahedral cluster as a constituent building block of β‐Ag₂MoO₄, consistent with Ag metallic formation. The formation of Ag filament transforms the β‐Ag₂MoO₄ semiconductor from n‐ to p‐type concomitant with the appearance of Ag defects.     

Radiation efficiency of a guitar top plate linked with edge or corner modes and intercell cancellation

This paper was based on a theoretical framework to determine strong and weak radiation by a guitar top plate, vibrating through deflections hard to analyze: multipolar mode shapes. The air-structure interaction was examined in terms of edge modes or corner modes, and considering even or odd number modes. A numerical model was implemented and experimentally calibrated, exhibiting several advantages exploring the coupling between vibratory and acoustic waves in a top plate. Two analyses were applied detecting high or low radiation efficiency for the structure. First, the addition of volume velocity for odd numbers of poles and cancellation for even numbers were examined. In fact, both behaviors can happen at the same time, as it was shown for a corner radiator case used as an example. Second, the ratio between bending and acoustic wavenumbers was explored. To illustrate the importance of this ratio, some theoretical features of a more efficient radiator than the corner mode were exposed in an edge mode example. Labeling multipolar mode shapes as efficient or inefficient radiators showed to be a useful alternative analyzing the top plate behavior. It can be applied knowing the nodal lines of the vibration pattern and estimating the bending and acoustic wavelengths.     

Distributional and Classical Solutions to the Cauchy Boltzmann Problem for Soft Potentials with Integrable Angular Cross Section

This paper focuses on the study of existence and uniqueness of distributional and classical solutions to the Cauchy Boltzmann problem for the soft potential case assuming S ^n?1 integrability of the angular part of the collision kernel (Grad cut-off assumption). For this purpose we revisit the Kaniel–Shinbrot iteration technique to present an elementary proof of existence and uniqueness results that includes the large data near local Maxwellian regime with possibly infinite initial mass. We study the propagation of regularity using a recent estimate for the positive collision operator given in (Alonso et al. in Convolution inequalities for the Boltzmann collision operator. arXiv:0902.0507 [math.AP]) , by E. Carneiro and the authors, that allows us to show such propagation without additional conditions on the collision kernel. Finally, an L ^p -stability result (with 1≤p≤∞) is presented assuming the aforementioned condition.