全文获取类型
收费全文 | 1236篇 |
免费 | 27篇 |
国内免费 | 2篇 |
专业分类
化学 | 875篇 |
晶体学 | 18篇 |
力学 | 20篇 |
数学 | 98篇 |
物理学 | 254篇 |
出版年
2023年 | 8篇 |
2022年 | 29篇 |
2021年 | 36篇 |
2020年 | 30篇 |
2019年 | 31篇 |
2018年 | 27篇 |
2017年 | 20篇 |
2016年 | 37篇 |
2015年 | 36篇 |
2014年 | 39篇 |
2013年 | 81篇 |
2012年 | 84篇 |
2011年 | 105篇 |
2010年 | 74篇 |
2009年 | 94篇 |
2008年 | 100篇 |
2007年 | 81篇 |
2006年 | 56篇 |
2005年 | 45篇 |
2004年 | 33篇 |
2003年 | 32篇 |
2002年 | 30篇 |
2001年 | 20篇 |
2000年 | 16篇 |
1999年 | 19篇 |
1998年 | 13篇 |
1997年 | 11篇 |
1996年 | 11篇 |
1995年 | 3篇 |
1994年 | 7篇 |
1993年 | 4篇 |
1992年 | 6篇 |
1991年 | 4篇 |
1990年 | 7篇 |
1989年 | 2篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1984年 | 3篇 |
1983年 | 6篇 |
1981年 | 6篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1978年 | 1篇 |
1976年 | 1篇 |
1974年 | 2篇 |
1973年 | 2篇 |
1971年 | 1篇 |
1965年 | 1篇 |
1961年 | 1篇 |
排序方式: 共有1265条查询结果,搜索用时 15 毫秒
61.
Nádia R. Aguiam Vânia I. CastroAna I.F. Ribeiro Rui D.V. FernandesCarina M. Carvalho Susana P.G. CostaSílvia M.M.A. Pereira-Lima 《Tetrahedron》2013
The multicomponent Ugi reaction is a straightforward method that can be used for the synthesis of highly hindered C-tetrasubstituted amino acids by reacting an amine, a ketone or aldehyde, a carboxylic acid and an isocyanide. In the present work, the synthesis of several α,α-dialkylglycines (α,α-diethylglycine, Deg; α,α-dipropylglycine, Dpg; 1-amino-1-cyclohexanecarboxylic acid, Ac6c) was achieved by solid phase Ugi reaction using resins functionalized with the isocyanide group. Since no resins with these features were available commercially, the functionalization of an aminomethylated resin started by the use of glycine (Gly), β-alanine (β-Ala) and γ-aminobutyric acid (GABA) as spacers. After spacer N-formylation, followed by dehydration, isocyanide functionalised resins were obtained. The resins were then used in solid phase Ugi reaction, using phenylacetic acid as the acid component, 4-methoxybenzylamine as the amine component and different ketones, to afford the desired N-acylated α,α-dialkylglycines in good overall yields (60–80%), after acidolytic cleavage from the resin, thus proving the feasibility of this approach. 相似文献
62.
63.
M. C. Morán T. Laranjeira A. Ribeiro M. G. Miguel B. Lindman 《Journal of Dispersion Science and Technology》2013,34(10):1494-1499
Novel DNA-chitosan particles were prepared based on associative phase separation and interfacial diffusion. These particles formed at water/water emulsion type interfaces were characterized with respect to several properties including stability, DNA conformational state, and entrapment and release of DNA. In particular it was found that the chitosan molecular weight is a good controlling parameter. 相似文献
64.
L. N. Gonçalves J. P. Casquilho A. C. Ribeiro J. L. Figueirinhas Corresponding author 《Liquid crystals》2013,40(11):1335-1342
We present an experimental study of the transient periodic structures appearing in the nematic director field in the magnetically induced reorientation of the director in the vicinity of the twist Fréedericksz geometry. Thin nematic samples (50?µm thick) were exposed to magnetic fields of variable intensity and orientation relative to the surface aligning direction of the sample. The director reorientation was induced by a rapid rotation of the sample in the static magnetic field producing a misalignment between the director and the magnetic field. The director field was optically monitored during the reorientation process and the transient periodic structures were characterized. Two types of periodic structures could be identified, namely bands and walls. Walls grow from bands close to the twist Fréedericksz geometry. The time dependence of the wave length and inclination of the periodic structures was obtained as a function of the magnetic field intensity and orientation relative to the surface aligning direction of the sample. The results for the bands are compared with the predictions of a model that we specifically developed to account for the non-orthogonal field orientations. It is seen that our model can account rather well for the experimental results considering that it uses only the field rotation time as adjustable parameter. All other model parameters are known. 相似文献
65.
Joana Patricia N. Ribeiro Joao A. Lopes 《International journal of environmental analytical chemistry》2013,93(10):701-710
The use of microbial biomass in biosorption is already being studied as a potential alternative to (or combined with) conventional processes, where several algae and microorganisms have already shown promising ability to uptake metals. Cyanobacteria (blue-green algae) are widespread organisms, with specific properties, such as high nutrient removal capacity and tolerance to highly variable conditions which make them well-suited for wastewater and remediation purposes. The main aim of this work was to evaluate the use of a marine cyanobacterium LEANCYA 21 (Synechocystis sp.), collected from the Portuguese southern border, for the removal of selected trace metals when in natural seawater culture medium. It was observed, for the first time, that this particular strain is capable of uptaking Pb, Ni and Zn (at nM levels) from seawater solutions using small amounts of biomass. Uptake values for Pb were up to 90% (0.75 mg g?1 biomass) in 6 h. The specific biosorption curves of Ni and Zn showed that these metals follow a first order kinetics biosorption in batch conditions. Solutions containing multimetals have revealed that Ni uptake is affected by the presence of Pb and Zn. The calculated specific absorption values were high enough to predict a possible application in aquaculture where such low levels of metals may inhibit microalgae growth. 相似文献
66.
Kobelnik Marcelo Valentin Leonardo Antônio Valentin Clever Aparecido Lavoie Fernando Luiz da Silva Jefferson Lins Ribeiro Clóvis Augusto 《Journal of Thermal Analysis and Calorimetry》2022,147(21):11739-11745
Journal of Thermal Analysis and Calorimetry - Asphalt emulsion is a versatile product that can be used for different waterproofing applications in civil construction and highway constructions.... 相似文献
67.
do Nascimento Ticiano Gomes Borges Arthur Luy Tavares Ferreira de Almeida Lara Mendes Ribeiro Êurica Adélia Nogueira Silva Fernanda Geny Calheiros da Costa Silva Valdemir do Nascimento Prata Ana Paula Basílio-Júnior Irinaldo Diniz Goulart Marília Oliveira Fonseca Morilla Demetrius Peireira de Freitas Johnnatan Duarte Aragão Cícero Flávio Soares 《Journal of Thermal Analysis and Calorimetry》2022,147(21):11949-11963
Journal of Thermal Analysis and Calorimetry - This work prepared and characterized microcapsule of Uncaria tomentosa (UT) in order to standardize a spray-dryer Uncaria tomentosa extract. The UT... 相似文献
68.
Magon CJ Lima JF Ribeiro RR Martins MJ 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2007,184(1):176-183
When the spin Hamiltonian is a linear function of the magnetic field intensity the resonance fields can be determined, in principle, by an eigenfield equation. In this report, we show a new technical approach to the resonance field problem where the eigenfield equation leads to a dynamic equation or, more specifically, to a first order differential equation of a variable L(x), where x is associated with the magnetic field h. Such differential equation has the property that: its stationary solution is the eigenfield equation and the spectral information contained in L(x) is directly related to the resonance spectrum. Such procedure, known as the "harmonic inversion problem" (HIP), can be solved by the "filter diagonalization method" (FDM) providing sufficient precision and resolution for the spectral analysis of the dynamic signals. Some examples are shown where the resonance fields are precisely determined in a single procedure, without the need to solve eigenvalue equations. 相似文献
69.
We construct commuting transfer matrices for models describing the interaction between a single quantum spin and a single bosonic mode using the quantum inverse scattering framework. The transfer matrices are obtained from certain inhomogeneous rational vertex models combining bosonic and spin representations of SU(2), subject to non-diagonal toroidal and open boundary conditions. Only open boundary conditions are found to lead to integrable Hamiltonians combining both rotating and counter-rotating terms in the interaction. If the boundary matrices can be brought to triangular form simultaneously, the spectrum of the model can be obtained by means of the algebraic Bethe ansatz after a suitable gauge transformation; the corresponding Hamiltonians are found to be non-Hermitian. Alternatively, a certain quasi-classical limit of the transfer matrix is considered where Hermitian Hamiltonians are obtained as members of a family of commuting operators; their diagonalization, however, remains an unsolved problem. 相似文献
70.
Marina Nídia Ferreira dos Santos Costa Marcos Antônio Pena Muniz Charles Alberto Brito Negrão Carlos Emmerson Ferreira da Costa Maria Louze Nobre Lamarão Luiz Morais José Otávio Carréra Silva Júnior Roseane Maria Ribeiro Costa 《Journal of Thermal Analysis and Calorimetry》2014,115(3):2269-2275
The Pracaxi oil—(Pentaclethra macroloba) contains high concentrations of fatty acids with emollient action that contribute to skin hydration. The use of this oil is supported by the utilization of natural resources thus enabling regional development and social contribution. The objective of this study was to characterize the P. macroloba oil by thermogravimetry (TG, DTG, and DTA), gas chromatography, Fourier transform infrared spectroscopy (FT-IR), and oxidation stability—Rancimat, aiming at the quality control of plant raw material. Three samples of crude oil sold by Amazon Oil Industry (Ananindeua, Pará, Brazil) were studied. The analysis of these oil samples showed different fatty acids, especially the behenic, oleic, linoleic, and lignoceric acids totalizing approximately 96 % of the grease composition and in smaller percentage arachidic, lauric, myristic, palmitic, and linolenic acids were found. The major acids have wide medicinal use. According to the TG/DTG curve, thermal stability was observed up to 220 °C, indicating a greater mass loss related to the dehydration and elimination of volatile substances. The thermal decomposition process occurred in the range of 430–450° C according to the DTG curve. The absorption spectrum in the infrared region (FT-IR) showed well-defined bands confirming the presence of functional groups present in the oil. Tests in a Rancimat have shown an induction period between 8 and 10 h demonstrating that the samples are in agreement with the standards required by ANP No. 14/2012 which requires at least 6 h of testing. 相似文献