粉粒体两相流的电容层析成象测量

粉粒体系统中的固相浓度分布的在线测量是十分困难的问题．电容层析成象技术是一种近年来发展起来的非侵入式快速浓度场测量技术．它不干扰流场，不受流动中颗粒浓度、加速度、不透明等因素的制约．本文讨论其测量原理、应用、近期进展、存在的主要问题及其解决的对策．     

ac Conductivity of mixed spinel NiAl0.7Cr0.7Fe0.6O4

ac Conductivity measurements are carried out across the metal to insulator transition in NiAl_0.7Cr_0.7Fe_0.6O₄. The low frequency data is analyzed using Summerfield scaling theory for hopping conductivity. The exponent of the scaling behavior has significantly different values in the conducting and insulating regimes. The hopping frequency and the zero frequency conductivity are found to increase with temperature, slowly in the metallic regime and rapidly in the insulating regime.     

Pulse‐shape instabilities and their measurement

Multi‐shot pulse‐shape measurements of trains of ultrashort pulses with unstable pulse shapes are studied. Measurement techniques considered include spectral‐phase interferometry for direct electric‐field reconstruction (SPIDER), second harmonic generation frequency‐resolved optical gating (FROG), polarization gate FROG, and cross‐correlation FROG. An analytical calculation and simulations show that SPIDER cannot see unstable pulse‐shape components and only measures the coherent artifact. Further, the presence of this instability cannot be distinguished from benign misalignment effects in SPIDER. FROG methods yield a better, although necessarily rough, estimate of the pulse shape and also indicate instability by exhibiting disagreement between measured and retrieved traces. Only good agreement between measured and retrieved FROG traces or 100% SPIDER fringe visibility guarantees a stable pulse train.     

The vitamin D debate: translating controlled experiments into reality for human sun exposure times

Exposure to sunlight, specifically the ultraviolet radiation, has both positive and negative health effects. Maximizing the benefits (vitamin D synthesis) while minimizing the damage is a multifaceted problem in which many of the elements are poorly quantified. Here we show how rigorously conducted large sample size laboratory studies of the effect of ultraviolet radiation dose on vitamin D status can be applied to real-life situations. This was achieved by modeling the radiation incident on different surfaces for different solar locations, and equating with the controlled exposures in the laboratory studies. Results from both model and experimental data show that relatively short exposures of a modest amount of unprotected skin to summer sunlight in northern climes, on a regular basis during lunchtime hours, increases vitamin D to sufficiency status (≥20 ng mL(-1) ) in the white Caucasian population. While both sun exposure conditions and human skin responses are variable in real life, these quantitative findings provide a guide for authorities devising sunlight exposure recommendations.     

A radiolabelling study of radicals derived from benzene, toluene and benzaldehyde sorbed in model environmental carbon

Radiolabelled free radicals were formed by the addition of muonium--a radioactive hydrogen atom with a positive muon as its nucleus--to benzene, toluene and benzaldehyde, as sorbed in porous carbon. The activation parameters associated with their reorientational motion were measured using longitudinal-field muon spin relaxation (LF-MuSRx). Two distinct sorbed fractions were detected in each sample, characterised by molecular reorientational activation energies of 5.9/25.8 kJ/mol for benzene, 2.5/5.9 kJ/mol for toluene and 2.9/11.5 kJ/mol for benzaldehyde.     

Limiting laws of supercritical branching random walks

In this Note, we make explicit the limit law of the renormalized supercritical branching random walk, giving credit to a conjecture formulated in Barral et al. (2012) [5] for a continuous analogue of the branching random walk. Also, in the case of a branching random walk on a homogeneous tree, we express the law of the corresponding limiting renormalized Gibbs measures, confirming, in this discrete model, conjectures formulated by physicists (Derrida and Spohn, 1988 [9]) about the Poisson–Dirichlet nature of the jumps in the limit, and precising the conjecture by giving the spatial distribution of these jumps.     

Role of zonal flow predator-prey oscillations in triggering the transition to H-mode confinement

Direct evidence of zonal flow (ZF) predator-prey oscillations and the synergistic roles of ZF- and equilibrium E×B flow shear in triggering the low- to high-confinement (L- to H-mode) transition in the DIII-D tokamak is presented. Periodic turbulence suppression is first observed in a narrow layer at and just inside the separatrix when the shearing rate transiently exceeds the turbulence decorrelation rate. The final transition to H mode with sustained turbulence and transport reduction is controlled by equilibrium E×B shear due to the increasing ion pressure gradient.     

44-Methylgambierone,a new gambierone analogue isolated from Gambierdiscus australes

A new analogue of gambierone, 44-methylgambierone, was isolated from the benthic dinoflagellate Gambierdiscus australes collected from Raoul Island (Rangitahua/Kermadec Islands). This molecule has been previously reported as maitotoxin-3. The structure of 44-methylgambierone was elucidated using 1D- and 2D-nuclear magnetic resonance spectroscopy and mass spectrometry techniques. The nine-ring polyether backbone (A–I) and functional groups (carbonyl, terminal diol, 1,3-diene and monosulphate) are the same for both compounds with the addition of an olefinic methyl group being the only modification in 44-methylgambierone.     

Local canted spin behaviour in Co1.4−x Zn x Ge0.4Fe1.2O4 spinels: A macroscopic, mesoscopic and microscopic study

DC magnetization, neutron depolarization and neutron diffraction (with both polarized and unpolarized neutrons) measurements have been reported for the Co_1.1−x Zn _x Ge_0.1Fe_1.2O₁ spinels with x=0.5, 0.6 and 0.7. Neutron depolarization and neutron diffraction measurements confirm the presence of a long range ferrimagnetic ordering of the local canted spins in these ferrite samples. The observed features of low field magnetization have been explained under the framework of thermally activated domain wall movement of ferrimagnetic arrangement of local canted spins. An important role of magnetic anisotropy (due to the presence of Co²⁺ ions) in establishing the magnetic ordering and domain kinetics in these ferrites has been observed.