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Mohammad Reza Shahsavari Alireza Namjoo Hossein Mohammadian Younes Saadat Soleyman Hosseinzadeh Samira Abdolbaghi 《Colloid Journal》2016,78(3):415-424
Dual-seeded dispersion polymerization (DSDP) of 2-ethylhexyl methacrylate with polystyrene (PS) and poly(methyl methacrylate) (PMMA) seed beads in the presence of saturated hydrocarbon droplets followed by evaporation of the hydrocarbon was studied. The effect of various polymerization conditions including initiator type and content, stabilizer type and concentration, and different hydrocarbon’s content on the shape of the obtained particles was investigated. The increase of concentration of 2,2'-azobis(isobutyronitrile) (AIBN) had no effect on the shape of the produced almond-shell-like PS particles, although it contributes in the formation of associated composite particles along with larger poly(2-ethylhexyl methacrylate) (PEHMA) beads produced by secondary nucleation. The experimental results showed that other initiators led to the formation of stable golf-ball-like PMMA particles as well as PS ones with symmetric shape. The type of stabilizer did not affect the shape of the particles. This observation suggests that unique almond-shelllike PS particles can be produced through a stabilizer-free DSDP process. The lowering of the concentration of hydrocarbons with long alkyl chains yielded stable disc-like PMMA particles. The formation of functional almond-shell-like particles by using light hydrocarbons was another interesting finding of this research. 相似文献
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Mohammad Hadigol Reza Nosrati Ahmad Nourbakhsh Mehrdad Raisee 《ournal of non Newtonian Fluid Mechanics》2011,166(17-18):965-971
Biofluids which exhibit non-Newtonian behavior are widely used in microfluidic devices which involve fluid mixing in microscales. In order to study the effects of shear depending viscosity of non-Newtonian fluids on characteristics of electroosmotic micromixing, a numerical investigation of flow of power-law fluid in a two-dimensional microchannel with nonuniform zeta potential distributions along the channel walls was carried out via finite volume scheme. The simulation results confirmed that the shear depending viscosity has a significant effect on the degree of mixing efficiency. It was shown as the fluid behavior index of power-law fluid, n, decreases, more homogeneous solution can be achieved at the microchannel outlet. Hence, electroosmotic micromixing was found more practical and efficient in microscale mixing of pseudoplastic fluids rather than those Newtonian and dilatant ones. Furthermore, it was found that increase in Reynolds number results in lower mixing efficiency while electroosmotic forces are kept constant. 相似文献
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