全文获取类型
收费全文 | 341篇 |
免费 | 5篇 |
专业分类
化学 | 275篇 |
晶体学 | 5篇 |
力学 | 14篇 |
数学 | 34篇 |
物理学 | 18篇 |
出版年
2023年 | 1篇 |
2022年 | 3篇 |
2021年 | 1篇 |
2020年 | 5篇 |
2019年 | 4篇 |
2017年 | 2篇 |
2016年 | 8篇 |
2015年 | 1篇 |
2014年 | 5篇 |
2013年 | 14篇 |
2012年 | 21篇 |
2011年 | 15篇 |
2010年 | 12篇 |
2009年 | 10篇 |
2008年 | 28篇 |
2007年 | 24篇 |
2006年 | 21篇 |
2005年 | 23篇 |
2004年 | 16篇 |
2003年 | 20篇 |
2002年 | 17篇 |
2001年 | 5篇 |
2000年 | 2篇 |
1999年 | 1篇 |
1998年 | 3篇 |
1997年 | 2篇 |
1996年 | 5篇 |
1995年 | 3篇 |
1994年 | 2篇 |
1993年 | 3篇 |
1991年 | 2篇 |
1990年 | 3篇 |
1989年 | 5篇 |
1988年 | 3篇 |
1987年 | 3篇 |
1985年 | 6篇 |
1984年 | 6篇 |
1983年 | 1篇 |
1982年 | 5篇 |
1981年 | 7篇 |
1980年 | 2篇 |
1979年 | 4篇 |
1978年 | 5篇 |
1977年 | 3篇 |
1976年 | 3篇 |
1975年 | 4篇 |
1974年 | 4篇 |
1973年 | 1篇 |
1972年 | 2篇 |
排序方式: 共有346条查询结果,搜索用时 31 毫秒
341.
Galarneau A Cangiotti M di Renzo F Sartori F Ottaviani MF 《The journal of physical chemistry. B》2006,110(41):20202-20210
The EPR spectra of radical surfactant probes embedded in cetyltrimethylammonium bromide (CTAB) and trimethylbenzene (TMB) stable water emulsions (TMB/CTAB = 13) were analyzed to provide information on the kinetics of formation of micelle-templated silicoaluminas (MTSA) at 343 K, obtained by means of silica and alumina, solved in alkaline solutions, at different Si/Al ratios. Textural (surface area, pore volume, pore size, surfactant content) and structural characterization of both as-synthesized and calcined MTSA were performed by means of nitrogen sorption isotherms, TEM, and chemical analysis. This analysis showed that TMB worked as a swelling agent of the CTAB micelles, providing large-pore homogeneous and stable MTSA at TMB/CTAB = 13 for Si/Al from infinity to 10. A demixing of the emulsion occurs at Si/Al < 10: at Si/Al = 7, a double wide-and-narrow pore structure was formed; then, at Si/Al = 5, an amorphous material was obtained. At Si/Al > or = 10, the computer-aided analysis of the EPR spectra as a function of the synthesis time indicated the distribution of the probes in two different environments: "micellar" probes inserted in the surfactant aggregates, whose mobility decreases over the synthesis time, thus reporting on the progressive modification of the surfactant aggregates structure and the solid condensation, and "interacting" probes due to probe-surfactant heads electrostatically interacting with the charged surface sites induced by alumina incorporation in the silica network. This last fraction increases its relative amount over the synthesis time, informing about the condensation and structuration of the MTSA. Without alumina, the "interacting" component is absent in the EPR spectra because TMB preferentially interacts with the surfactant headgroups by cation-pi interactions, thus preventing the interactions of these headgroups with silanols. When alumina is added, the negatively charged silicoaluminate at the surface promotes the interaction of the ammonium headgroups with the surface, and some Na+ cations also interact with TMB by cation-pi interaction and contribute to decreasing the interaction of the headgroups with TMB. Therefore, increasing alumina contents promote electrostatic interactions between the positively charged surfactant heads and the negatively charged silicoaluminate groups. The strong interaction of the surfactants with the silicoaluminate surface allows the formation of a monolayerlike structure of surfactant, which is not observed in the absence of alumina. The synthesis is slowed by increasing alumina contents due to a destructuration effect of alumina in the MTSA formation. 相似文献
342.
A formulation of the n-electron valence state perturbation theory (NEVPT) at the third order of perturbation is presented. The present implementation concerns the so-called strongly contracted variant of NEVPT, where only a subspace of the first-order interacting space is taken into account. The resulting strongly contracted NEVPT3 approach is discussed in three test cases: (a) the energy difference between the 3B1 and 1A1 states of the methylene molecule, (b) the potential-energy curve of the N2 molecule ground state, and (c) the chromium dimer (Cr2) ground-state potential-energy profile. Particular attention is devoted to the last case where large basis sets comprising also h orbitals are adopted and where remarkable differences between the second- and third-order results show up. 相似文献
343.
In this paper we present the theory of implicit Riordan arrays, that is, Riordan arrays which require the application of the Lagrange Inversion Formula to be dealt with. We show several examples in which our approach gives explicit results, both in finding closed expressions for sums and, especially, in solving classes of combinatorial sum inversions. 相似文献
344.
345.
Arminas Urbonavi
ius Graziana Fortunato Emilija Ambrazaityt Elena Plytninkien Aurimas Bieliauskas Vaida Miliinait Renzo Luisi Egl Arba
iauskien Sonata Kriktolaityt Algirdas a
kus 《Molecules (Basel, Switzerland)》2022,27(12)
An efficient synthetic route to construct diverse pyrazole-based chalcones from 1-phenyl-1H-pyrazol-3-ols bearing a formyl or acetyl group on the C4 position of pyrazole ring, employing a base-catalysed Claisen–Schmidt condensation reaction, is described. Isomeric chalcones were further reacted with N-hydroxy-4-toluenesulfonamide and regioselective formation of 3,5-disubstituted 1,2-oxazoles was established. The novel pyrazole-chalcones and 1,2-oxazoles were characterized by an in-depth analysis of NMR spectral data, which were obtained through a combination of standard and advanced NMR spectroscopy techniques. 相似文献
346.