Porous zinc(Ⅱ)-organic framework with potential open metal sites:Synthesis,structure and property

Reaction of Zn(NO3)2.6H2O with 5-(isonicotinamido) isophthalic acid(H2INAIP) in N,N-dimethylformamide(DMF) affords a new three-dimensional(3D) coordination polymer {[Zn(INAIP)(DMF)].0.5DMF.4H2O}n(1).The X-ray crystallographic structural analysis reveals that complex 1 is a 3D porous framework containing a potential open metal site inside the pores.Topology analysis confirms that complex 1 is a two-fold interpenetrated(10,3)-b net with both metal ion and ligand acting as 3-connecting nodes.The thermal stabil...     

一维CdS/TiO2纳米材料的制备及其光催化性能

采用含有氯化镉和硫脲的钛溶胶对钛酸纳米管载体进行修饰,再经焙烧制得不同CdS含量的一维CdS/TiO2纳米材料.运用X射线衍射、透射电子显微镜、N2吸附-脱附、紫外-可见光谱和X射线光电子能谱等手段表征了材料的结构和性质,并考察了CdS/TiO2样品在紫外光及模拟日光条件下光催化降解甲基橙溶液的活性.结果表明,经高温焙...     

Influence of arsenic,antimony and cobalt impurities on the cathodic process in zinc electrowinning

By means of an electrochemical study,the influence of arsenic,antimony and cobalt on cathodic polarization in the zinc electrowinning process,the associated kinetic equations and parameters,and the polarization mechanism have been studied.The results show that the experimental values of the kinetic parameters are in accord with the theoretical values in the ZnSO4/H2SO4 solution with a single impurity is added.In contrast,the charge transfer coefficient α is smaller than the theoretical value in the ZnSO4/H2...     

光催化还原CO2的研究现状和发展前景

综述了光催化还原CO2的研究进展,并重点介绍了本课题组在光催化还原CO2为碳氢燃料方面的研究工作,通过该途径可降低CO2在大气中的排放浓度,还可将CO2转化为烷烃、醇或其它有机物质,从而实现碳材料的再循环使用.最后展望了该研究领域的前景.     

微脉冲束团诊断系统的时间分辨性能研究

北京自由电子激光器(BFEL)加速器束团的主要特点是微脉冲宽度仅4ps,这对束团诊断系统的时间分辨性能提出了很高的要求。本文分析了一些影响系统分辨率的因素,其中首次考虑到了色散及斜置辐射体的影响,这些分析计算将主要用来对实验数据进行校正。     

微型自由电子激光电子运动特性分析

作者曾首次提出以铁电单晶表面势代替摇摆器磁场的自由电子激光新机制.本文从单电子的洛仑兹方程出发,对电子的单摆方程,共振行为进行了研究,获得了第j个表面势共振态的增益公式.单摆方程和文献[1]中从能量方程得到的一致,本文的研究充实了文献[1]的论据。     

用改进的全耗型燃烧器火焰光度法测定锂的研究

本文报导了用改进的贝克曼燃器火焰分光光度法测定锂的研究。改进后的燃烧器可采用液化石油气——氧气。直接测定铋中锂的下限为50μg/g,分析结果同发射光谱法很好地符合。     

利用同步辐射进行X射线激发光学发光研究

本文介绍利用北京正负电子对撞机产生的同步辐射X光进行激发晶体(GGG:Nd~(3+),LaF_3:Nd~(3+))的光学发光研究的有关实验技术和设备。     

脉冲束六维相空间相点方程的建立

从当前脉冲束设计中经常出现的一个问题入手,以曲线坐标为例详细介绍了如何从粒子在位形空间坐标系中的向量运动方程出发,严格地推导六维粒子动力学方程的一般方法。     

Neutrino masses and lepton-flavor-violating τ decays in the supersymmetric left-right model

In the supersymmetric left-right model, the light neutrino masses are given by the Type-Ⅱ seesaw mechanism. A duality property of this mechanism indicates that there exist eight possible Higgs triplet Yukawa couplings which result in the same neutrino mass matrix. In this paper, we work out the one-loop renormalization group equations for the effective neutrino mass matrix in the supersymmetric left-right model. The stability of the Type-Ⅱ seesaw scenario is briefly discussed. We also study the lepton-flavor-violating processes (τ→ μγ and τ→eγ) by using the reconstructed Higgs triplet Yukawa couplings.