Dynamic acoustoelastic testing of weakly pre-loaded unconsolidated water-saturated glass beads

Dynamic acoustoelastic testing is applied to weakly pre-loaded unconsolidated water-saturated glass beads. The gravitational acceleration produces, on the probed beads, a static stress of order 130 Pa, thus the granular medium is close to the jamming transition. A low-frequency (LF) acoustic wave gently disturbs the medium, inducing successively slight expansion and compaction of the granular packing expected to modulate the number of contacts between beads. Ultrasound (US) pulses are emitted simultaneously to dynamically detect the induced modification of the granular skeleton. US propagation velocity and attenuation both increase when the LF pressure increases. The quadratic nonlinear elastic parameter β, related to the pressure dependence of US propagation velocity, was measured in the range 60-530 if water-saturated glass beads are considered as an effective medium. A dynamic modification of US scattering induced by beads is proposed to modulate US attenuation. Complex hysteretic behaviors and tension-compression asymmetry are also observed and analyzed by time-domain and spectral analyses. Furthermore acoustic nonlinearities are measured in cases of quasi-static and dynamic variations of the LF wave amplitude, providing quantitatively similar acoustic nonlinearities but qualitatively different.     

Combined Infrared Multiphoton Dissociation with Ultraviolet Photodissociation for Ubiquitin Characterization

Herein we report the successful implementation of the consecutive and simultaneous photodissociation with high (213 nm) and low (10.6 μm) energy photons (HiLoPD, high-low photodissociation) on ubiquitin in a quadrupole-Orbitrap mass spectrometer. Absorption of high-energy UV photon is dispersed over the whole protein and stimulates extensive C–C_α backbone fragmentation, whereas low-energy IR photon gradually increases the internal energy and thus preferentially dissociates the most labile amide (C–N) bonds. We noticed that simultaneous irradiation of UV and IR lasers on intact ubiquitin in a single MS/MS experiment provides a rich and well-balanced fragmentation array of a/x, b/y, and z ions. Moreover, secondary fragmentation from a/x and z ions leads to the formation of satellite side-chain ions (d, v, and w) and can help to distinguish isomeric residues in a protein. Implementation of high-low photodissociation in a high-resolution mass spectrometer may offer considerable benefits to promote a comprehensive portrait of protein characterization.

Open image in new window

Graphical Abstract ?

     

Experimental evidence of simultaneous multi-resonance noise reduction using an absorber with essential nonlinearity under two excitation frequencies

The addition of an essentially nonlinear membrane absorber to a linear vibroacoustic system with multiple resonances is studied experimentally, using quasiperiodic excitation. An extended experimental dataset of the system response is analyzed under steady-state excitation at two frequencies. Thresholds between low and high damping states within the system and associated noise reduction are observed and quantified thanks to frequency conversion and RMS efficiency indicators. Following previous numerical results, it is shown that the membrane NES (Nonlinear Energy Sink) acts simultaneously and efficiently on two acoustic resonances. In all cases, the introduction of energy at a second excitation frequency appears favorable to lower the frequency conversion threshold and to lower the noise within the system. In particular, a simultaneous control of two one-to-one resonances by the NES is observed. Exploration of energy conversion in the two excitation amplitudes plane advocates for a linear dependence of the frequency conversion thresholds on the two excitation amplitudes.     

P-type nitrogen-doped ZnO nanoparticles stable under ambient conditions

Zinc oxide is considered as a very promising material for optoelectronics. However, to date, the difficulty in producing stable p-type ZnO is a bottleneck, which hinders the advent of ZnO-based devices. In that context, nitrogen-doped zinc oxide receives much attention. However, numerous reviews report the controversial character of p-type conductivity in N-doped ZnO, and recent theoretical contributions explain that N-doping alone cannot lead to p-typeness in Zn-rich ZnO. We report here that the ammonolysis at low temperature of ZnO(2) yields pure wurtzite-type N-doped ZnO nanoparticles with an extraordinarily large amount of Zn vacancies (up to 20%). Electrochemical and transient spectroscopy studies demonstrate that these Zn-poor nanoparticles exhibit a p-type conductivity that is stable over more than 2 years under ambient conditions.     

Combined electrospray ionization source with a velocity map imaging spectrometer for studying large gas phase molecular ions

We present a new compact and versatile experimental set-up that has been designed to perform electron and ion imaging experiments on large multiply charged gas phase molecular and cluster species. It combines an electrospray ionization source, a quadrupole mass filter guiding ion optics and a velocity map imaging spectrometer. Characterization of the spectrometer has been performed on atomic ions. Results obtained on molecular species (stilbene 420 dianions) demonstrate the possibility offered by this experimental set-up.     

95 GHz millimeter wave signal generation using an arrayed waveguide grating dual wavelength semiconductor laser

We report the generation of a 95?GHz carrier frequency by optical heterodyning of two wavelengths from adjacent channels from an arrayed waveguide grating-based multiwavelength laser. The extended cavity structure of the device provides low phase noise and narrow optical linewidth, further enhanced by the intracavity filter effect of the arrayed waveguide grating. We demonstrate that the generated RF beat note, at 95?GHz, has a -3 dB linewidth of 250?kHz. To the best of our knowledge, this is the narrowest RF linewidth generated from a free-running dual-wavelength semiconductor laser. The device is realized as a photonic integrated circuit using active-passive integration technology, and fabricated on a multiproject wafer run, constituting a novel approach for a compact, low-cost dual-wavelength heterodyne source.     

Microfluidic synthesis of chitosan-based nanoparticles for fuel cell applications

A microfluidic platform is developed for the synthesis of monodisperse, 100 nm, chitosan based nanoparticles using nanogelation with ATP. The resulting nanoparticles tuned and enhanced transport and electrochemical properties of Nafion based nanocomposite membranes, which is highly favorable for fuel cell applications.     

Heuristics for the multi-depot petrol station replenishment problem with time windows

In the multi-depot petrol station replenishment problem with time windows (MPSRPTW), the delivery of petroleum products stored in a number of different petroleum depots to a set of petrol distribution stations has to be optimized. Each depot has its own fleet of heterogeneous and compartmented tank trucks. Stations specify their demand by indicating the minimum and maximum quantities to be delivered for each ordered product and require the delivery within a predetermined time window. Several inter-related decisions must be made simultaneously in order to solve the problem. For this problem, the set of feasible routes to deliver all the demands, the departure depot for each route, the quantities of each product to be delivered, the assignment of these routes to trucks, the time schedule for each trip, and the loading of the ordered products to different tanks of the trucks used need to be determined. In this paper, we propose a mathematical model that selects, among a set of feasible trips, the subset that allows the delivery of all the demands while maximizing the overall daily net revenue. If this model is provided with all possible feasible trips, it determines the optimal solution for the corresponding MPSRPTW. However, since the number of such trips is often huge, we developed a procedure to generate a restricted set of promising feasible trips. Using this restricted set, the model produces a good but not necessarily optimal solution. Thus the proposed solution process can be seen as a heuristic. We report the results of the extensive numerical tests carried out to assess the performance of the proposed heuristic. In addition, we show that, for the special case of only one depot, the proposed heuristic outperforms a previously published solution method.     

Photodissociation pathways and lifetimes of protonated peptides and their dimers

Photodissociation lifetimes and fragment channels of gas-phase, protonated YA(n) (n = 1,2) peptides and their dimers were measured with 266 nm photons. The protonated monomers were found to have a fast dissociation channel with an exponential lifetime of ~200 ns while the protonated dimers show an additional slow dissociation component with a lifetime of ~2 μs. Laser power dependence measurements enabled us to ascribe the fast channel in the monomer and the slow channel in the dimer to a one-photon process, whereas the fast dimer channel is from a two-photon process. The slow (1 photon) dissociation channel in the dimer was found to result in cleavage of the H-bonds after energy transfer through these H-bonds. In general, the dissociation of these protonated peptides is non-prompt and the decay time was found to increase with the size of the peptides. Quantum RRKM calculations of the microcanonical rate constants also confirmed a statistical nature of the photodissociation processes in the dipeptide monomers and dimers. The classical RRKM expression gives a rate constant as an analytical function of the number of active vibrational modes in the system, estimated separately on the basis of the equipartition theorem. It demonstrates encouraging results in predicting fragmentation lifetimes of protonated peptides. Finally, we present the first experimental evidence for a photo-induced conversion of tyrosine-containing peptides into monocyclic aromatic hydrocarbon along with a formamide molecule both found in space.