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141.
Poupard P Sanoner P Baron A Renard CM Guyot S 《Journal of mass spectrometry : JMS》2011,46(11):1186-1197
Procyanidins (i.e. condensed tannins) are polyphenols commonly found in fruits. During juice and cider making, apple polyphenol oxidase catalyzes the oxidation of caffeoylquinic acid (CQA) into its corresponding o-quinone which further reacts with procyanidins and other polyphenols, leading to the formation of numerous oxidation products. However, the structure and the reaction pathways of these neoformed phenolic compounds are still largely unknown. Experiments were carried out on a model system to gain insights into the chemical processes occurring during the initial steps of fruit processing. Procyanidin B2 was oxidized by caffeoylquinic acid o-quinone (CQAoq) in an apple juice model solution. The reaction products were monitored using high performance liquid chromatography (HPLC) coupled to ultraviolet (UV)-visible and electrospray tandem mass spectrometry (ESI-MS/MS) in the negative mode. Oxidative conversion of procyanidin B2 ([M-H](-) at m/z 577) into procyanidin A2 at m/z 575 was unambiguously confirmed. In addition, several classes of products were characterized by their deprotonated molecules ([M-H](-)) and their MS/MS fragmentation patterns: hetero-dimers (m/z 929) and homo-dimers (m/z 1153 and 705) resulting from dimerization involving procyanidin and CQA molecules; intramolecular addition products at m/z 575, 573, 927, 1151 and 703. Interestingly, no extensive polymerization was observed. Analysis of a cider apple juice enabled comparison with the results obtained on a biosynthetic model solution. However, procyanidin A2 did not accumulate but seemed to be an intermediate in the formation of an end-product at m/z 573 for which two structural hypotheses are given. These structural modifications of native polyphenols as a consequence of oxidation probably have an impact on the organoleptic and nutritional properties of apple juices and other apple-derived foods. 相似文献
142.
Traoré T Clavé G Delacour L Kotera N Renard PY Romieu A Berthault P Boutin C Tassali N Rousseau B 《Chemical communications (Cambridge, England)》2011,47(34):9702-9704
Cryptophane-111 is one of the best candidates for (129)Xe MRI-based applications. Herein, we report the first metal-free and water-soluble cryptophane-111 core which involves an efficient and unusual post-synthetic sulfonation procedure. 相似文献
143.
Julien Babinot Estelle Renard Benjamin Le Droumaguet Jean‐Michel Guigner Simona Mura Julien Nicolas Patrick Couvreur Valrie Langlois 《Macromolecular rapid communications》2013,34(4):362-368
In this paper, a straightforward method to produce poly(3‐hydroxyalkanoate)‐based multicompartment micelles (MCMs) is presented. Thiol‐ene addition is used to graft sequentially perfluorooctyl chains and poly(ethylene glycol) oligomers onto poly(3‐hydroxyoctanoate‐co‐hydroxyundecenoate) oligomers backbone. Well‐defined copolymers are obtained as shown by 1H NMR and size‐exclusion chromatography. After nanoprecipitation in water, novel PHA‐based MCMs are evidenced by cryo‐transmission electron microscopy. Moreover, the cytocompatibility of MCMs is demonstrated in vitro via cell viability assay. 相似文献
144.
Aboshyan-Sorgho L Nozary H Aebischer A Bünzli JC Morgantini PY Kittilstved KR Hauser A Eliseeva SV Petoud S Piguet C 《Journal of the American Chemical Society》2012,134(30):12675-12684
This work illustrates a simple approach for optimizing long-lived near-infrared lanthanide-centered luminescence using trivalent chromium chromophores as sensitizers. Reactions of the segmental ligand L2 with stoichiometric amounts of M(CF(3)SO(3))(2) (M = Cr, Zn) and Ln(CF(3)SO(3))(3) (Ln = Nd, Er, Yb) under aerobic conditions quantitatively yield the D(3)-symmetrical trinuclear [MLnM(L2)(3)](CF(3)SO(3))(n) complexes (M = Zn, n = 7; M = Cr, n = 9), in which the central lanthanide activator is sandwiched between the two transition metal cations. Visible or NIR irradiation of the peripheral Cr(III) chromophores in [CrLnCr(L2)(3)](9+) induces rate-limiting intramolecular intermetallic Cr→Ln energy transfer processes (Ln = Nd, Er, Yb), which eventually produces lanthanide-centered near-infrared (NIR) or IR emission with apparent lifetimes within the millisecond range. As compared to the parent dinuclear complexes [CrLn(L1)(3)](6+), the connection of a second strong-field [CrN(6)] sensitizer in [CrLnCr(L2)(3)](9+) significantly enhances the emission intensity without perturbing the kinetic regime. This work opens novel exciting photophysical perspectives via the buildup of non-negligible population densities for the long-lived doubly excited state [Cr*LnCr*(L2)(3)](9+) under reasonable pumping powers. 相似文献
145.
New uranyl vanadates A3(UO2)7(VO4)5O (M=Li (1), Na (2), Ag (3)) have been synthesized by solid-state reaction and their structures determined from single-crystal X-ray diffraction data for 1 and 3. The tetragonal structure results of an alternation of two types of sheets denoted S for ∞2[UO2(VO4)2]4− and D for ∞2[(UO2)2(VO4)3]5− built from UO6 square bipyramids and connected through VO4 tetrahedra to ∞1[U(3)O5-U(4)O5]8− infinite chains of edge-shared U(3)O7 and U(4)O7 pentagonal bipyramids alternatively parallel to a- and b-axis to construct a three-dimensional uranyl vanadate arrangement. It is noticeable that similar ∞[UO5]4− chains are connected only by S-type sheets in A2(UO2)3(VO4)2O and by D-type sheets in A(UO2)4(VO4)3, thus A3(UO2)7(VO4)5O appears as an intergrowth structure between the two previously reported series. The mobility of the monovalent ion in the mutually perpendicular channels created in the three-dimensional arrangement is correlated to the occupation rate of the sites and by the geometry of the different sites occupied by either Na, Ag or Li. Crystallographic data: 293 K, Bruker X8-APEX2 X-ray diffractometer equipped with a 4 K CCD detector, MoKα, λ=0.71073 Å, tetragonal symmetry, space group P4¯m2, Z=1, full-matrix least-squares refinement on the basis of F2; 1,a=7.2794(9) Å, c=14.514(4) Å, R1=0.021 and wR2=0.048 for 62 parameters with 782 independent reflections with I?2σ(I); 3, a=7.2373(3) Å, c=14.7973(15) Å, R1=0.041 and wR2=0.085 for 60 parameters with 1066 independent reflections with I?2σ(I). 相似文献
146.
Matthieu Virot Valérie Tomao Carine Le Bourvellec Catherine M.C.G. Renard Farid Chemat 《Ultrasonics sonochemistry》2010,17(6):1066-1074
Apple pomace, a by-product of the cider production, has been studied as a potential source of polyphenols, compounds of great interest for the industry. Ultrasound has been used to improve extraction efficiency in terms of time needed and total polyphenol content. A preliminary study has been first investigated to optimize ethanol proportion of aqueous extractant (50%, v/v) and solid/liquid ratio (<15%, w/v). A response surface methodology has then been used to maximize total polyphenol content of extracts and investigate influence of parameters involved in extraction procedures for both total polyphenols content and composition of extracts. Optimal settings reached from a central composite design were applied for ultrasound-assisted extraction and were compared to conventional procedure: yields were increased by more than 20%. Ultrasound-assisted polyphenols extraction from apple pomace appears to be a relevant, rapid, sustainable alternative to conventional procedure, and that scale up of the process is possible. 相似文献
147.
G. Montes-Hernandez A. Fernndez-Martínez L. Charlet D. Tisserand F. Renard 《Journal of Crystal Growth》2008,310(11):2946-2953
The hydrothermal carbonation of calcium hydroxide (Ca(OH)2) at high pressure of CO2 (initial PCO2=55 bar) and moderate to high temperature (30 and 90 °C) was used to synthesize fine particles of calcite. This method allows a high carbonation efficiency (about 95% of Ca(OH)2–CaCO3 conversion), a significant production rate (48 kg/m3 h) and high purity of product (about 96%). However, the various initial physicochemical conditions have a strong influence on the crystal size and surface area of the synthesized calcite crystals. The present study is focused on the estimation of the textural properties of synthesized calcite (morphology, specific surface area, average particle size, particle size distribution and particle size evolution with reaction time), using Rietveld refinements of X-ray diffraction (XRD) spectra, Brunauer–Emmett–Teller (BET) measurements, and scanning electron microscope (SEM) and transmission electron microscope (TEM) observations. This study demonstrate that the pressure, the temperature and the dissolved quantity of CO2 have a significant effect on the average particle size, specific surface area, initial rate of precipitation, and on the morphology of calcium carbonate crystals. In contrast, these PTx conditions used herein have an insignificant effect on the carbonation efficiency of Ca(OH)2.
Finally, the results presented here demonstrate that nano-calcite crystals with high specific surface area (SBET=6–10 m2/g) can be produced, with a high potential for industrial applications such as adsorbents and/or filler in papermaking industry. 相似文献
148.
Angheluta L Jettestuen E Mathiesen J Renard F Jamtveit B 《Physical review letters》2008,100(9):096105
The application of stress to multiphase solid-liquid systems often results in morphological instabilities. Here we propose a solid-solid phase transformation model for roughening instability in the interface between two porous materials with different porosities under normal compression stresses. This instability is triggered by a finite jump in the free energy density across the interface, and it leads to the formation of fingerlike structures aligned with the principal direction of compaction. The model is proposed as an explanation for the roughening of stylolites-irregular interfaces associated with the compaction of sedimentary rocks that fluctuate about a plane perpendicular to the principal direction of compaction. 相似文献
149.
M. Beccaria P. Ciafaloni D. Comelli F. Renard C. Verzegnassi 《The European Physical Journal C - Particles and Fields》1999,10(2):331-336
We examine the possibility that SUSY particles are light, i.e. have a mass just beyond the final kinematical reach of LEP2.
In this case, even if light particles are not directly detected, their virtual effects are enhanced by a “close-to-threshold”
resonance in the s-channel. We find that this resonant effect is absent in the case of light sfermions, while it is enhanced
in the case of light gauginos, since neutralinos and charginos add coherently in some regions of the allowed parameter space.
We discuss this “virtual alliance” in detail and try to examine the possibilities of its experimental verification.
Received: 19 March 1999 / Published online: 12 August 1999 相似文献
150.
The process e+e?→HHZ is strongly dependent on the Higgs boson couplings HZZ, HHZZ and HHH, and provides therefore a test of the Higgs assignment to gauge group representations. The cross section varies between 5 × 10?38 and 10?39 cm2 for Higgs masses between 5GeV and 40 GeV in the Weinberg-Salam model. 相似文献