全文获取类型
收费全文 | 23622篇 |
免费 | 3968篇 |
国内免费 | 3326篇 |
专业分类
化学 | 17885篇 |
晶体学 | 284篇 |
力学 | 1130篇 |
综合类 | 303篇 |
数学 | 2585篇 |
物理学 | 8729篇 |
出版年
2024年 | 70篇 |
2023年 | 430篇 |
2022年 | 765篇 |
2021年 | 798篇 |
2020年 | 923篇 |
2019年 | 942篇 |
2018年 | 805篇 |
2017年 | 766篇 |
2016年 | 1164篇 |
2015年 | 1227篇 |
2014年 | 1364篇 |
2013年 | 1844篇 |
2012年 | 2084篇 |
2011年 | 2134篇 |
2010年 | 1520篇 |
2009年 | 1496篇 |
2008年 | 1636篇 |
2007年 | 1407篇 |
2006年 | 1400篇 |
2005年 | 1217篇 |
2004年 | 1015篇 |
2003年 | 843篇 |
2002年 | 877篇 |
2001年 | 652篇 |
2000年 | 548篇 |
1999年 | 465篇 |
1998年 | 340篇 |
1997年 | 332篇 |
1996年 | 319篇 |
1995年 | 243篇 |
1994年 | 231篇 |
1993年 | 184篇 |
1992年 | 123篇 |
1991年 | 103篇 |
1990年 | 101篇 |
1989年 | 76篇 |
1988年 | 50篇 |
1987年 | 46篇 |
1986年 | 55篇 |
1985年 | 47篇 |
1984年 | 30篇 |
1983年 | 28篇 |
1982年 | 16篇 |
1981年 | 19篇 |
1980年 | 20篇 |
1978年 | 22篇 |
1977年 | 12篇 |
1976年 | 13篇 |
1974年 | 14篇 |
1973年 | 12篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
981.
研究了多元线性阵列探测器的主频、阵元个数和阵元间距对探测器方向性的影响.实验结果表明,采用主频为2~5 MHz,阵元数为5~15,阵元间距为0.3~0.9 mm的多元线性阵列探测器,其方向性好,将有利于光声信号的探测与成像. 相似文献
982.
ZHANG QingChao PANG ShuJie LI Yi & ZHANG Tao Key Laboratory of Aerospace Materials Performance School of Materials Science Engineering Beijing University of Aeronautics Astronautics Beijing China 《中国科学:物理学 力学 天文学(英文版)》2011,(9)
Bulk metallic glasses (BMGs) with large supercooled liquid region are promising materials for superplastic forming. In this paper, we demonstrate a microstructure-based strategy to pinpoint the composition with the largest supercooled liquid region in La 86 x Al 14 Cu x (x=16 at%-20 at%) metallic glass system. By monitoring the changes in crystallization behavior of the glassy alloys with composition to search for the alloys exhibiting eutectic crystallization, the glassy alloys with the largest supercooled... 相似文献
983.
Lin Su Chao Wang Yong-hao Yu Yong-ying Ren Ke-liang Xie Guo-lin Wang 《BMC neuroscience》2011,12(1):120
Background
Chronic neuropathic pain is an intractable pain with few effective treatments. Moderate cold stimulation can relieve pain, and this may be a novel train of thought for exploring new methods of analgesia. Transient receptor potential melastatin 8 (TRPM8) ion channel has been proposed to be an important molecular sensor for cold. Here we investigate the role of TRPM8 in the mechanism of chronic neuropathic pain using a rat model of chronic constriction injury (CCI) to the sciatic nerve.Results
Mechanical allodynia, cold and thermal hyperalgesia of CCI rats began on the 4th day following surgery and maintained at the peak during the period from the 10th to 14th day after operation. The level of TRPM8 protein in L5 dorsal root ganglion (DRG) ipsilateral to nerve injury was significantly increased on the 4th day after CCI, and reached the peak on the 10th day, and remained elevated on the 14th day following CCI. This time course of the alteration of TRPM8 expression was consistent with that of CCI-induced hyperalgesic response of the operated hind paw. Besides, activation of cold receptor TRPM8 of CCI rats by intrathecal application of menthol resulted in the inhibition of mechanical allodynia and thermal hyperalgesia and the enhancement of cold hyperalgesia. In contrast, downregulation of TRPM8 protein in ipsilateral L5 DRG of CCI rats by intrathecal TRPM8 antisense oligonucleotide attenuated cold hyperalgesia, but it had no effect on CCI-induced mechanical allodynia and thermal hyperalgesia.Conclusions
TRPM8 may play different roles in mechanical allodynia, cold and thermal hyperalgesia that develop after nerve injury, and it is a very promising research direction for the development of new therapies for chronic neuroapthic pain.984.
Yi Liu Tao Zou Fen Wang Chang-Hui Li Lin Zheng Young Sun 《Physica B: Condensed Matter》2011,406(6-7):1263-1266
We report on exotic dielectric properties of composite materials consisting of traditional ferroelectric BaTiO3 and electronic ferroelectric LuFe2O4. The composites were synthesized by a simple ceramic processing method with properties that can be tailored by adjusting LuFe2O4 concentration. A percolative effect was observed at the volume fraction of ~0.26, which led to an abrupt increase in the dielectric permittivity. For composites with high LuFe2O4 fractions, a giant dielectric tunability was observed over a broad temperature interval, which is in strong contrast to traditional ferroelectrics. 相似文献
985.
Min‐Min Xu Ya‐Xian Yuan Jian‐Lin Yao San‐Yang Han Mei Wang Ren‐Ao Gu 《Journal of Raman spectroscopy : JRS》2011,42(3):324-331
The adsorption of 2‐amino‐5‐cyanopyridine (2‐ACP) was investigated in solution at different pH values by i n situ surface‐enhanced Raman scattering (SERS) spectroscopy combined with the electrochemical method. The assignments of the main bands were first performed on the basis of the spectral features of similar compounds and with the help of density functional theory calculations. The results revealed that the adsorption and the interfacial structure of 2‐ACP on the Au electrode depended on the applied potential and the pH values of the solution. In the natural solution, 2‐ACP was adsorbed on the surface with a vertical orientation by the CN group from − 0.4 to − 1.0 V, whereas in the − 0.4 to 0.8 V range, the N atom of the pyridine ring was bound to the surface. A transition region for the reorientation of the two adsorption modes was observed from − 0.8 to − 0.4 V. A flat configuration was preferred at an extremely negative potential. A similar surface adsorption behavior was observed in the alkali environment, while the Stark effect slope decreased because of the adsorption of OH−. Due to the protonation of N atom in the acidic solution, the potential region for the coexistence of two configurations ranged from − 0.4 to 0.2 V. Additionally, a similar adsorption configuration was proposed on the Au colloids at various pH values. The results revealed that the adsorption behavior became more complex on colloidal surfaces than that on a rigid electrode surface. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
986.
对面心立方(fcc)、体心立方(bcc)和六角密堆积(hcp)三种不同结构的晶体,在假设它们的原胞中包含8个价电子并将价电子近似为自由电子的情况下,采用“自由电子气理论”和“自由电子能带模型”,研究其根据费米球确定的费米能级EF与根据自由电子能带模型计算的平均键能Em。研究结果表明,由自由电子能带模型计算所得3种不同结构晶体(因而电子密度也不一样)的平均键能Em等于各自自由电子系统的费米能级EF。平均键能Em是我们在异质结带阶理论计算中建议的一种参考能级,研究结果在深化对平均键能Em物理实质认识的同时,提供了一种借助于自由电子能带模型计算自由电子系统费米能级EF的新方法。 相似文献
987.
988.
High power nano-LiMn2Oa cathode materials with high-rate pulse discharge capability for lithium-ion batteries* 下载免费PDF全文
Nano-LiMn2O4 cathode materials with nano-sized particles are synthesized via a citric acid assisted sol-gel route. The structure, the morphology and the electrochemical properties of the nano-LiMn204 are investigated. Compared with the micro-sized LiMn2O4, the nano-LiMn2O4 possesses a high initial capacity (120 mAh/g) at a discharge rate of 0.2 C (29.6 mA/g). The nano-LiMn2O4 also has a good high-rate discharge capability, retaining 91% of its capacity at a discharge rate of 10 C and 73~ at a discharge rate of 40 C. In particular, the nano-LiMn2O4 shows an excellent high-rate pulse discharge capability. The cut-off voltage at the end of 50-ms pulse discharge with a discharge rate of 80 C is above 3.40 V, and the voltage returns to over 4.10 V after the pulse discharge. These results show that the prepared nano-LiMn2O4 could be a potential cathode material for the power sources with the capability to deliver very high-rate pulse currents. 相似文献
989.
990.
On semipolar epitaxial ZnO grown by chemical vapor deposition consists of two distinct orientations as evidenced by transmission electron microscopy and X‐ray diffraction. The initially grown ZnO on GaN follows the GaN lattice with the epitaxial relationship of // and The other oriented ZnO domains then grow on faceted with and with good coherency with the ‐oriented grains. (© 2015 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim) 相似文献