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991.
中心有刚体质量的环形薄板的非线性强迫振动 总被引:2,自引:0,他引:2
本文研究中心带有刚体质量外部固定铰支或活动铰支的环形薄板的非线性强迫振动。考虑板的弯曲变形、面内位移和几何非线性,用哈米尔顿原理建立板的运动方程,用Kantorovich平均法消去时间变量,然后用数值积分求得非线性振动的振幅随激振力的大小及激振力的频率而变化的关系。求解过程中用打靶法逐步改进未知参量,以保证边界条件的满足。最后讨论薄膜力、激振力的分布、板的内外半径比等因素对响应的影响 相似文献
992.
聚氨酯泡沫塑料压缩杨氏模量的理论预测 总被引:6,自引:0,他引:6
通过微分法导出了泡沫塑料剪切模量和体积模量所满足的微分方程组,再利用联系泡沫塑料泊松比和孔隙比的Kerner-Rusch经验关系及泡沫塑料弹性常数间满足足的关系,在基体材料不可压缩的假设下,确定了泡沫塑料的杨氏模量。本文针对几种密度的泡沫塑料,分别对它们的杨氏模量进行了理论预测和实验测定,结果表明:理论预测的模量在较高密度下与实验符合的很好,在低密度下也给出相当好的近似值。此外,本文的结果同其他理 相似文献
993.
Individual Surface‐Engineered Microorganisms as Robust Pickering Interfacial Biocatalysts for Resistance‐Minimized Phase‐Transfer Bioconversion
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Zhaowei Chen Haiwei Ji Chuanqi Zhao Enguo Ju Prof. Dr. Jinsong Ren Prof. Dr. Xiaogang Qu 《Angewandte Chemie (International ed. in English)》2015,54(16):4904-4908
A powerful strategy for long‐term and diffusional‐resistance‐minimized whole‐cell biocatalysis in biphasic systems is reported where individually encapsulated bacteria are employed as robust and recyclable Pickering interfacial biocatalysts. By individually immobilizing bacterial cells and optimizing the hydrophobic/hydrophilic balance of the encapsulating magnetic mineral shells, the encased bacteria became interfacially active and locate at the Pickering emulsion interfaces, leading to dramatically enhanced bioconversion performances by minimizing internal and external diffusional resistances. Moreover, in situ product separation and biocatalyst recovery was readily achieved using a remote magnetic field. Importantly, the mineral shell effectively protected the entire cell from long‐term organic‐solvent stress, as shown by the reusability of the biocatalysts for up to 30 cycles, while retaining high stereoselective catalytic activities, cell viabilities, and proliferative abilities. 相似文献
994.
Crystalline Hetero‐Stereocomplexed Polycarbonates Produced from Amorphous Opposite Enantiomers Having Different Chemical Structures
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Dr. Ye Liu Meng Wang Wei‐Min Ren Yue‐Chao Xu Prof. Dr. Xiao‐Bing Lu 《Angewandte Chemie (International ed. in English)》2015,54(24):7042-7046
Stereocomplexation is the stereoselective interaction between two opposite enantiomeric polymers through an interlocked orderly assembly. Most studies focus on the stereocomplex formation from the crystalline opposite enantiomers having the identical structure; nevertheless, rare examples were reported regarding the crystalline stereocomplexes from enantiomeric polymers having different chemical structures. Herein we show a strategy for polymer orderly assembly through the formation of crystalline hetero‐stereocomplexed polymeric materials by the cocrystallization of amorphous isotactic polycarbonates with different chemical structures and opposite configurations. The behaviors in the crystalline state are significantly different from that of the component enantiomeric polymers or their homo‐stereocomplexes. This study is expected to open up a new way to prepare various semicrystalline materials having a wide variety of physical properties and degradability. 相似文献
995.
Rhodium(III)‐Catalyzed [3+2]/[5+2] Annulation of 4‐Aryl 1,2,3‐Triazoles with Internal Alkynes through Dual C(sp2)H Functionalization
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Yuan Yang Ming‐Bo Zhou Xuan‐Hui Ouyang Rui Pi Dr. Ren‐Jie Song Prof. Dr. Jin‐Heng Li 《Angewandte Chemie (International ed. in English)》2015,54(22):6595-6599
A rhodium(III)‐catalyzed [3+2]/[5+2] annulation of 4‐aryl 1‐tosyl‐1,2,3‐triazoles with internal alkynes is presented. This transformation provides straightforward access to indeno[1,7‐cd]azepine architectures through a sequence involving the formation of a rhodium(III) azavinyl carbene, dual C(sp2)? H functionalization, and [3+2]/[5+2] annulation. 相似文献
996.
Reversible Modulation of Surface Plasmons in Gold Nanoparticles Enabled by Surface Redox Chemistry
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Dr. Zheng Li Dr. Jonathan J. Foley IV Dr. Sheng Peng Dr. Cheng‐Jun Sun Dr. Yang Ren Dr. Gary P. Wiederrecht Dr. Stephen K. Gray Dr. Yugang Sun 《Angewandte Chemie (International ed. in English)》2015,54(31):8948-8951
Switchable surface redox chemistry is demonstrated in gold@iron/iron oxide core–shell nanoparticles with ambient oxidation and plasmon‐mediated reduction to modulate the oxidation state of shell layers. The iron shell can be oxidized to iron oxide through ambient oxidation, leading to an enhancement and red‐shift of the gold surface plasmon resonance (SPR). This enhanced gold SPR can drive reduction of the iron oxide shell under broadband illumination to reversibly blue‐shift and significantly dampen gold SPR absorption. The observed phenomena provide a unique mechanism for controlling the plasmonic properties and surface chemistry of small metal nanoparticles. 相似文献
997.
Flexible,Stretchable, and Rechargeable Fiber‐Shaped Zinc–Air Battery Based on Cross‐Stacked Carbon Nanotube Sheets
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Yifan Xu Ye Zhang Ziyang Guo Jing Ren Prof. Yonggang Wang Prof. Huisheng Peng 《Angewandte Chemie (International ed. in English)》2015,54(51):15390-15394
The fabrication of flexible, stretchable and rechargeable devices with a high energy density is critical for next‐generation electronics. Herein, fiber‐shaped Zn–air batteries, are realized for the first time by designing aligned, cross‐stacked and porous carbon nanotube sheets simultaneously that behave as a gas diffusion layer, a catalyst layer, and a current collector. The combined remarkable electronic and mechanical properties of the aligned carbon nanotube sheets endow good electrochemical properties. They display excellent discharge and charge performances at a high current density of 2 A g?1. They are also flexible and stretchable, which is particularly promising to power portable and wearable electronic devices. 相似文献
998.
Synthesis and magnetic properties of organic multilayer films based on the layer‐by‐layer assembly
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Two polymers containing pyridine rings were prepared by free‐radical polymerization and confirmed by Fourier transform infrared and 1H NMR spectra. The preparation of four multilayer films that were obtained by self‐assembly of the polymer and the transition metal neutralized polyelectrolyte on PE substrate was described. UV–vis spectra and atomic force microscopy images were applied to characterize these films and indicate the uniform assembling process. The driving force for building up the multilayer films was identified by infrared spectroscopy to be the coordination interaction. The magnetic behavior was examined as a function of magnetic field strength at 30 kOe and as a function of temperature (5–300 K). All films display strong soft ferromagnetic properties and higher than those of the bulk materials. The magnetic results show that the layer‐by‐layer self‐assembling approach is beneficial to the ordered alignment of adjacent paramagnetic spins and induces better magnetic phenomena. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
999.
Dr. Guang‐Ping Hao Giovanni Mondin Dr. Zhikun Zheng Tim Biemelt Stefan Klosz René Schubel Prof. Alexander Eychmüller Prof. Stefan Kaskel 《Angewandte Chemie (International ed. in English)》2015,54(6):1941-1945
There is significant interest in high‐performance materials that can directly and efficiently capture water vapor, particularly from air. Herein, we report a class of novel porous carbon cuboids with unusual ultra‐hydrophilic properties, over which the synergistic effects between surface heterogeneity and micropore architecture is maximized, leading to the best atmospheric water‐capture performance among porous carbons to date, with a water capacity of up to 9.82 mmol g?1 at P/P0=0.2 and 25 °C (20 % relative humidity or 6000 ppm). Benefiting from properties, such as defined morphology, narrow pore size distribution, and high heterogeneity, this series of functional carbons may serve as model materials for fundamental research on carbon chemistry and the advance of new types of materials for water‐vapor capture as well as other applications requiring combined highly hydrophilic surface chemistry, developed hierarchical porosity, and excellent stability. 相似文献
1000.
Formation of DNA:RNA Hybrid G‐Quadruplex in Bacterial Cells and Its Dominance over the Intramolecular DNA G‐Quadruplex in Mediating Transcription Termination
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