Adsorption and dissociation of water on LaB6(100) investigated by surface vibrational spectroscopy

The chemisorption of water (H₂O and D₂O) on a LaB₆(100) surface was studied with reflection absorption infrared spectroscopy (RAIRS) and high resolution electron energy loss spectroscopy (HREELS). The clean surface was exposed to H₂O and D₂O at temperatures from 90 K to room temperature, and spectra were acquired after heating to temperatures as high as 1200 K. It was found that water molecularly adsorbs on the surface at 90 K as a monomer at low coverages and as amorphous solid water at higher coverages. Water adsorbs dissociatively at room temperature to produce surface hydroxyl species as indicated by OH/OD stretch peaks at 3676/2701 cm^?1. Room temperature adsorption also reveals low frequency loss features in HREEL spectra near 300 cm^?1 that are quite similar to results obtained following the dissociative adsorption of O₂. In the latter case, the loss features were attributed to the LaO stretch of O atoms bridge-bonded between two La atoms. In the case of dissociative adsorption of H₂O, the low frequency loss features could be due to either the LaO vibrations of adsorbed O or of adsorbed OH.     

Tunable microlens arrays using polymer network liquid crystal

A tunable-focus microlens array based on polymer network liquid crystal (PNLC) is demonstrated. The PNLC was prepared using an ultraviolet (UV) light exposure through a patterned photomask. The photocurable monomer in each of the UV exposed spot forms an inhomogeneous centro-symmetrical polymer network which acts as a lens when a homogeneous electric field is applied to the cell. The focal length of the microlens arrays is tunable with the applied voltage.     

Global simulation for laser-driven MeV electrons in fast ignition

A comprehensive examination of the interaction of a picosecond-long ignition pulse on high-density (40 times critical density) pellets using a two-dimensional particle-in-cell model is described. The global geometry consists of a 50 mum diameter pellet surrounded by a corona which is isolated by a vacuum region from the boundary. For cone-attached targets, as much as 67% of the incident laser energy is absorbed with 12% sent forward as fast electrons in a 23 degrees cone. The current filaments are driven by the Weibel instability of the forward-going fast electron flux and its return current with the ions playing an important role of neutralizing the space charge. No global current filament coalescence has been observed. The electron distribution function obeys a power law, which begins at E approximately 0.2 MeV and falls off as E-(2-3).     

Nanoscale probing of adsorbed species by tip-enhanced Raman spectroscopy

Tip-enhanced Raman spectroscopy (TERS) is based on the optical excitation of localized surface plasmons in the tip-substrate cavity, which provides a large but local field enhancement near the tip apex. We report on TERS with smooth single crystalline surfaces as substrates. The adsorbates were CN- ions at Au(111) and malachite green isothiocyanate (MGITC) molecules at Au(111) and Pt(110) using either Au or Ir tips. The data analysis yields Raman enhancements of about 4 x 10(5) for CN- and up to 10(6) for MGITC at Au(111) with a Au tip, probing an area of less than 100 nm radius.     

对称平板传输线分布电容的计算

介绍了共形映射法及其在静电场中的应用.求出了对称平板传输线的分布电容.     

A one step synthesis of novel 4-alkoxy-β-lactams by high pressure promoted [2 + 21 cycloadditions of enol ethers and isocyanates derived from amino acids

Abstract

Novel moni-β-lactams derived from esters of amino acids have been prepared in one step by the high pressure promoted [2 + 2] cycloaddition of enol ethers with isocyanates derived from esters of amino acids. The effect of substituents in the enol ether and in the isocyanate on the scope of the synthesis has been demonstrated.     

Two‐dimensional stimulated ultraviolet resonance Raman spectra of tyrosine and tryptophan: a simulation study

We report an ab initio simulation study of the ultrafast broad bandwidth ultraviolet stimulated resonance Raman spectra (SRRS) of l ‐tyrosine, l ‐tryptophan, and trans‐l ‐tryptophan‐l ‐tyrosine (WY) dipeptide. Two‐pulse one‐dimensional SRRS and three‐pulse two‐dimensional SRRS that reveal inter‐residue and intra‐residue vibrational correlations are simulated using electronically resonant or pre‐resonant pulse configurations that select the Raman signal and discriminate against excited state pathways. Multimode effects are incorporated via the cumulant expansion. The two‐dimensional SRRS technique is more sensitive to residue couplings than spontaneous Raman. Copyright © 2013 John Wiley & Sons, Ltd.     

多模玻色二次多项式型系统的特性函数和准概率分布函数

运用多模玻色系统广义线性量子变换的普遍理论，对多模玻色二次多项式型系统进行了研究.给出了多模玻色二次多项式型系统的正规、反正规、Wigner特性函数、P表示和Q表示.举例讨论了该系统的压缩性质. 关键词： 多模玻色二次多项式型系统 特性函数 准概率分布函数     

Temperature or strain induced adjustable-chirp characteristics of uniform fibre grating with tapered metal coating

Temperature and strain characteristics of uniform fibre grating with tapered metal coatings have been analysed theoretically, by which adjustable chirp characteristics of such gratings are shown. Electroplating is adopted to fabricate such gratings, and the tapered metal coating is obtained by gradually drawing the fibre grating out of the solution during the process of electroplating. The gradually changing cross-sectional area of the metal coating is calculated by a newly suggested numerical method. By combining the theoretical and numerical simulation analyses, the gratings' characteristics are given at various temperatures and strains. The results obtained using such a method are also testified by experiments.     

A generalized 2D FDTD model for photonic crystal fibers with frequency dependent media

A generalized model based on the two-dimensional finite-difference time-domain (2D FDTD) method for photonic crystal fibers (PCF) with frequency dependent media is presented. The Maxwell’s curl equations are formulated using flux density and the magnetic field. Auxiliary differential equations are used with complex-conjugate pole-residue pairs which incorporate the material dispersion of the dispersive media. The model is demonstrated to be a unified approach for arbitrary dispersive materials; therefore, it definitely reduces implementation cost when dealing with different frequency-dependent materials.