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31.
This paper is devoted to a detailed theoretical study of an ion pair SN2 reaction LiNCO+CH3F in the gas phase and in solution at the level of MP2(full)/6-31+G**//HF/6-31+G**. Two possible reaction mechanisms, inversion and retention, are discussed. There are eight possible reaction pathways. The inversion mechanism is more favorable no matter in the gas phase or in solution based on analyses of the transition structures. Methyl isocyanate should form preferentially in the gas phase and more stable methyl cyanate is the main product in solution. The retardation of the reaction in solvents was attributed to the difference in solvation in the separated reactants and in the transition state. 相似文献
32.
The concept of super hamiltonian semigroup is introduced. As a result, the structure theorems obtained by A. Cherubini and A. Varisco on quasi commutative semi-groups and quasi hamiltonian semigroups respectively are extended to super hamiltonian semigroups. 相似文献
33.
何先应 《南昌大学学报(理科版)》2004,28(4):338-340
设G是有限群。H是G的一个正规子群。P是|H|的一个素因子。P是H的一个Sylow p-子群。若下列条件之一满足。则H是p-幂零:1)P的极大子群都是G的CAP-子群且(|H|,P-1)=1;2)P的二次极大子群都是G的CAP-子群且(|H|,P^2-1)=1。特别地,若进一步假设G/H为P-幂零且(|G|,P-1)=1或(|G|,P^2-1)=1。则G自身亦为P-幂零。 相似文献
34.
35.
XiWenHE HongShengGUO YuMeiJIA 《中国化学快报》2003,14(9):979-982
In order to obtain mechanically stable membrane for practical application, the imprinted polymer was synthesized in the pores of polyfluoromembrane, the binding and transport ability of the membrane were studied. 相似文献
36.
HE Xiao-Rong ZHOU Li-Juan Wei-Xing 《理论物理通讯》2005,44(4):670-674
Based on Dyson Schwinger Equations (DSEs) in the “rainbow” approximation, the dependence of quark effective mass on gluon propagator is investigated by use of three different phenomenological gluon propagators with two parameters, the strength parameter x and range parameter △. Our theoretical calculations for the quark effective mass Mf(p^2), defined by the self-energy functions Af(p^2) and Bi(p%2) of the DSEs, show that the dynamically running quark effective mass is strongly dependent on gluon propagator. Therefore, because gluon propagator is completely unknown, the quark effective mass cannot be exactly determined theoretically. 相似文献
37.
A novel super-hydrophobic stearic acid (STA) film with a water contact angle of 166o was prepared by chemical adsorption on aluminum wafer coated with polyethyleneimine (PEI) film. The micro-tribological behavior
of the super-hydrophobic STA monolayer was compared with that of the polished and PEI-coated Al surfaces. The effect of relative
humidity on the adhesion and friction was investigated as well. It was found that the STA monolayer showed decreased friction,
while the adhesive force was greatly decreased by increasing the surface roughness of the Al wafer to reduce the contact area
between the atomic force microscope (AFM) tip and the sample surface to be tested. Thus the friction and adhesion of the Al
wafer was effectively decreased by generating the STA monolayer, which indicated that it could be feasible and rational to
prepare a surface with good adhesion resistance and lubricity by properly controlling the surface morphology and the chemical
composition. Both the adhesion and friction decreased as the relative humidity was lowered from 65% to 10%, though the decrease
extent became insignificant for the STA monolayer.
The project supported by the National Natural Science Foundation of China (50375151, 50323007, 10225209) and the Chinese Academy
of Sciences (KJCX-SW-L2) 相似文献
38.
Ren‐Shen Lee Jen‐Ming Yang Tz‐Feng Lin 《Journal of polymer science. Part A, Polymer chemistry》2004,42(10):2303-2312
Water‐soluble poly(ester‐carbonate) having pendent amino and carboxylic groups on the main‐chain carbon is reported for the first time. This article describes the melt ring‐opening/condensation reaction of trans‐4‐hydroxy‐N‐benzyloxycarbonyl‐L ‐proline (N‐CBz‐Hpr) with 5‐methyl‐5‐benzyloxycarbonyl‐1,3‐dioxan‐2‐one (MBC) at a wide range of molar fractions. The influence of reaction conditions such as catalyst concentration, polymerization time, and temperature on the number average molecular weight (Mn) and molecular weight distribution (Mw/Mn) of the copolymers was investigated. The polymerizations were carried out in bulk at 110 °C with 3 wt % stannous octoate as a catalyst for 16 h. The poly(ester‐carbonate)s obtained were characterized by Fourier transform infrared spectroscopy, 1H NMR, differential scanning calorimetry, and gel permeation chromatography. The copolymers synthesized exhibited moderate molecular weights (Mn = 6000–14,700 g mol?1) with reasonable molecular weight distributions (Mw/Mn = 1.11–2.23). The values of the glass‐transition temperature (Tg) of the copolymers depended on the molar fractions of cyclic carbonate. When the MBC content decreased from 76 to 12 mol %, the Tg increased from 16 to 48 °C. The relationship between the poly(N‐CBz‐Hpr‐co‐MBC) Tg and the compositions was in approximation with the Fox equation. In vitro degradation of these poly(N‐CBz‐Hpr‐co‐MBC)s was evaluated from weight‐loss measurements and the change of Mn and Mw/Mn. Debenzylation of 3 by catalytic hydrogenation led to the corresponding linear poly(ester‐carbonate), 4 , with pendent amino and carboxylic groups. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2303–2312, 2004 相似文献
39.
Study on the Superhydrophilicity of the SiO2-TiO2 Thin Films Prepared by Sol-Gel Method at Room Temperature 总被引:2,自引:0,他引:2
Dasen Ren Xiaoli Cui Jie Shen Qun Zhang Xiliang Yang Zhuangjian Zhang Lu Ming 《Journal of Sol-Gel Science and Technology》2004,29(3):131-136
Nanoscale SiO2-TiO2 composite thin films with the thickness of about 100 nm were prepared by sol-gel method at room temperature in air. The chemical states of the elements on the surface and near the surface were measured by XPS. The results showed that the Ti on/near the surface of the thin films existed not only as TiO2 but also as Ti2O3. Part of the TiO2 was changed to Ti2O3 after UV irradiation. The crystalline structure of the TiO2 in the SiO2-TiO2 thin films was anatase with the crystallite size of 14–20 nm. It was found that the thin film prepared at room temperature in air has good superhydrophilic property and has strong adherence to the substrate. 相似文献
40.