全文获取类型
收费全文 | 143877篇 |
免费 | 27215篇 |
国内免费 | 14514篇 |
专业分类
化学 | 114817篇 |
晶体学 | 1637篇 |
力学 | 7021篇 |
综合类 | 822篇 |
数学 | 16101篇 |
物理学 | 45208篇 |
出版年
2024年 | 278篇 |
2023年 | 2283篇 |
2022年 | 3535篇 |
2021年 | 4234篇 |
2020年 | 5615篇 |
2019年 | 6469篇 |
2018年 | 4833篇 |
2017年 | 4262篇 |
2016年 | 8265篇 |
2015年 | 8319篇 |
2014年 | 9518篇 |
2013年 | 12026篇 |
2012年 | 12797篇 |
2011年 | 12533篇 |
2010年 | 9911篇 |
2009年 | 9670篇 |
2008年 | 9565篇 |
2007年 | 8186篇 |
2006年 | 7498篇 |
2005年 | 6558篇 |
2004年 | 5329篇 |
2003年 | 4368篇 |
2002年 | 4845篇 |
2001年 | 3697篇 |
2000年 | 3344篇 |
1999年 | 2586篇 |
1998年 | 1963篇 |
1997年 | 1770篇 |
1996年 | 1747篇 |
1995年 | 1502篇 |
1994年 | 1366篇 |
1993年 | 1121篇 |
1992年 | 983篇 |
1991年 | 840篇 |
1990年 | 715篇 |
1989年 | 557篇 |
1988年 | 416篇 |
1987年 | 368篇 |
1986年 | 370篇 |
1985年 | 301篇 |
1984年 | 220篇 |
1983年 | 168篇 |
1982年 | 138篇 |
1981年 | 93篇 |
1980年 | 77篇 |
1979年 | 36篇 |
1978年 | 45篇 |
1976年 | 37篇 |
1975年 | 30篇 |
1957年 | 30篇 |
排序方式: 共有10000条查询结果,搜索用时 937 毫秒
941.
Influence of Turbid Medium Parameters on Back Scattered Intensity and Pulsewidth of Picosecond Pulse
In this paper, we simulate a practical in vivo technique in which is produced influence of turbid medium parameters on backscattered intensity and pulsewidth of picosecond for turbid tissue surface of a semiinfinite medium by a small narrow linewidth laser beams. It is shown that the interaction of the ultra short pulse and the turbid tissue is very used as researching the optical parameters of the turbid medium. 相似文献
942.
P. Budrugeac J. M. Criado F. J. Gotor J. Malek L. A. Prez‐Maqueda E. Segal 《国际化学动力学杂志》2004,36(6):309-315
The isoconversional method suggested by Friedman and the invariant kinetic parameters method (IKP) were used in order to examine the kinetics of the nonisothermal crystallization of (GeS2)0.3(Sb2S3)0.7. The objective of the paper is to show the usefulness of the IKP method both for determining the activation parameters as well as the model of the investigated process. It was shown that the kinetic triplet [(E, A, f(α), where E is the activation energy, A is the preexponential factor, and f(α) is the differential function of conversion], which results through the application of the IKP method, depends on the set of kinetic models considered. For different sets of kinetic models, proportional values of f(α) are obtained. A criterion for the selection of this set, the use of which lead to the true kinetic triplet corresponding to the analyzed process (E = 163.2 kJ mol?1; A = 2.47 × 1012 min?1 and the Avrami‐Erofeev model, Am, for m = 2.5–2.6 was suggested. © 2004 Wiley Periodicals, Inc. Int J Chem Kinet 36: 309–315, 2004 相似文献
943.
Esperanza Salfrn Carlos Seoaneb Margarita Surez Yamila Verdecia Amaury Alvarez Estael Ochoa Roberto Martínez‐Alvarez Nazario Martín 《Journal of heterocyclic chemistry》2004,41(4):509-516
Novel 4‐amino‐6‐aryl‐2‐phenylpyrimidine‐5‐carbonitriles have been prepared in one step procedure from the readily available 4‐aryl‐2‐amino‐3‐cyano‐5,6,7,8‐tetrahydro‐7,7‐dimethyl‐5‐oxo‐4H‐benzopyrans. The mass spectroscopy study under EI conditions shows molecular peaks with high intensity corresponding to the loss of benzonitrile from the C2 position of the pyrimidine ring. Semiempirical (AMI and PM3) and ab initio HF/6–31G* calculations reveal a favored distorted geometry where the three rings are not in the same plane. 相似文献
944.
从初中进入高一级学校,物理跨了一个高台阶,常使学生感到束手无策,“一听就懂,一做就错.”是学生经常向老师谈的体会.为什么会产生这一情况呢?原因是他们的习惯思维在作怪,使他们在看问题时总有盲点,怎样才能开拓学生的发散性思维?使他们的思维在今后的学习中不为所“框”、不为所“漏”.我认为应从以下方面着手. 相似文献
945.
In this paper, existence criteria are established for the existence of periodic solutions of a second order sublinear differential equation with delay and forcing function. Our method is based on careful a priori estimation and continuation theorems, and our sublinear condition is an improvement of the boundedness condition in some recent results. 相似文献
946.
947.
Ke-Zhi Li Jian Wei He-Jun Li Yu-Lei Zhang Chuang Wang Dang-She Hou 《Applied Surface Science》2007,253(18):7365-7368
Well-aligned carbon nanotubes (CNTs) of high quality were synthesized by pyrolysis of phenolic resin at 800 °C in anodic alumina oxide (AAO) pores under argon protection. The innocuous source materials and safe operational conditions permit this method to synthesize well-aligned CNTs in large-scale and low cost. The formation mechanism of the synthesized CNTs is also proposed in this work by a series of visual sketches and is proved with obvious evidence. Firstly, phenolic resin nanotubes form in the template pores through the evaporation of solvent. Heat treatment then transfers these tubes into CNTs. 相似文献
948.
In the paper we obtain vector-valued inequalities for Calder6n-Zygmund operator, simply CZO on Herz space and weak Herz space. In particular.we obtain vector-valued inequalities for CZO on Lq(Rd, |x|αdμ) space, with 1< q <∞, -n <α< n(q -1), and on L1,∞(Rd,|x|αdμ) space, with -n <α< 0. 相似文献
949.
In this article, the linear and nonlinear shear rheological behaviors of polylactide (PLA)/clay (organophilic‐montmorillonite) nanocomposites (PLACNs) were investigated by an Advanced Rheology Expanded System rheometer. The nanocomposites were prepared by master batch method using a twin‐screw extruder with poly(ε‐caprolactone) (PCL) as a compatibilizer. The presence of org‐MMT leads to obvious pseudo‐solid‐like behaviors of nanocomposite melts. The behaviors caused by the formation of a “percolating network” derived from the reciprocity among the strong related sheet particles. Therefore, the storage moduli, loss moduli, and dynamic viscosities of PLACNs show a monotonic increase with MMT content. Nonterminal behaviors exists in PLACNs nanocomposites. Besides the PLACNs melts show a greater shear thinning tendency than pure PLA melt because of the preferential orientation of the MMT layers. Therefore, PLACNs have higher moduli but better processibility compared with pure PLA. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 3189–3196, 2007 相似文献
950.
Yonggang Shangguan Li Zhao Liyang Tao Qiang Zheng 《Journal of Polymer Science.Polymer Physics》2007,45(13):1704-1712
The effects of preparation method, composition, and thermal condition on formation of β‐iPP in isotactic polypropylene/ethylene–propylene rubber (iPP/EPR) blends were studied using modulated differential scanning calorimeter (MDSC), wide angle X‐ray diffraction (WAXD), and phase contrast microscopy (PCM). It was found that the α‐iPP and β‐iPP can simultaneity form in the melt‐blended samples, whereas only α‐iPP exists in the solution‐blended samples. The results show that the formation of β‐iPP in the melt‐blended samples is related to the crystallization temperature and the β‐iPP generally diminishes and finally vanishes when the crystallization temperature moves far from 125 °C. The phenomena that the lower critical temperature of β‐iPP in iPP/EPR obviously increases to 114 °C and the upper critical temperature decreases to 134 °C indicate the narrowing of temperature interval, facilitating the formation of β‐iPP in iPP/EPR. Furthermore, it was found that the amount of β‐iPP in melt‐blended iPP/EPR samples is dependent on the composition and the maximum amount of β‐iPP formed when the composition of iPP/EPR blends is 85:15 in weight. The results through examining the effect of annealing for iPP/EPR samples at melt state indicate that this annealing may eliminate the susceptibility to β‐crystallization of iPP. However, only α‐iPP can be observed in solution‐blended samples subjected to annealing for different time. The PCM images demonstrate that an obvious phase‐separation happens in both melt‐blended and solution‐blended iPP/EPR samples, implying that compared with the disperse degree of EPR in iPP, the preparation method plays a dominant role in formation of β‐iPP. It is suggested that the origin of formation of β‐iPP results from the thermomechanical history of the EPR component in iPP/EPR. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1704–1712, 2007 相似文献