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81.
Galvanomagnetic properties of air-stable and highly conductive potassium-intercalated graphite sheet
Yumemi Gotoh Koji Tamada Noboru Akuzawa Rika Matsumoto Masatsugu Fujishige Kenji Takeuchi Morinobu Endo Yasushi Soneda Tsutomu Takeichi 《Journal of Physics and Chemistry of Solids》2013
Magnetoresistance and Hall coefficient of air-stable potassium-intercalated graphite sheets (hereafter abbreviated as K-PGS) were determined at room temperature. The magnitude of the magnetoresistance and the absolute value of Hall coefficient of K-PGS decreased with increasing potassium content of K-PGS, nK/nC. Two-carrier model was used for calculating carrier density and mobility. The electron density increased with increasing nK/nC: 3.07×1020 cm−3 (nK/nC=0.005), 5.67×1020 cm−3 (nK/nC=0.008) and 6.40×1020 cm−3 (nK/nC=0.011). The value of the electron density of K-PGS with nK/nC=0.011 (nominal composition KC91) was about 80% of the reported value, 7.8×1020 cm−3, for KC48 (nK/nC=0.021) prepared from HOPG (highly oriented pyrolytic graphite). The mobility decreased with increasing nK/nC: 2.11×103 cm2 V−1 s−1 (nK/nC=0.005), 1.42×103 cm2 V−1 s−1 (nK/nC=0.008) and 1.34×103 cm2 V−1 s−1 (nK/nC=0.011). The value of the mobility of K-PGS with nK/nC=0.011 was about 60% of the reported value (2300 cm2 V−1 s−1) for KC48 prepared from HOPG. 相似文献
82.
Abstract Structural properties and interlayer interaction in mutually incommensurate (MX) x TX2-type ternary chalcogenides with layered composite crystal structure have been investigated on the basis of structure analysis including superspace group symmetry. It has been confirmed that charge transfer between substructures occur in (LaS) x TiS2 from the results of Ti K XANES spectra. The lattice stability and interlayer interaction in the (MX) x TX2 have been discussed with the use of bond-valence-sum (BVS) method by considering modulated structure analysis. 相似文献
83.
Akiko Takeda Mahesan Niranjan Jun-ya Gotoh Yoshinobu Kawahara 《Computational Management Science》2013,10(1):21-49
Index tracking is a passive investment strategy in which a fund (e.g., an ETF: exchange traded fund) manager purchases a set of assets to mimic a market index. The tracking error, i.e., the difference between the performances of the index and the portfolio, may be minimized by buying all the assets contained in the index. However, this strategy results in a considerable transaction cost and, accordingly, decreases the return of the constructed portfolio. On the other hand, a portfolio with a small cardinality may result in poor out-of-sample performance. Of interest is, thus, constructing a portfolio with good out-of-sample performance, while keeping the number of assets invested in small (i.e., sparse). In this paper, we develop a tracking portfolio model that addresses the above conflicting requirements by using a combination of L0- and L2-norms. The L2-norm regularizes the overdetermined system to impose smoothness (and hence has better out-of-sample performance), and it shrinks the solution to an equally-weighted dense portfolio. On the other hand, the L0-norm imposes a cardinality constraint that achieves sparsity (and hence a lower transaction cost). We propose a heuristic method for estimating portfolio weights, which combines a greedy search with an analytical formula embedded in it. We demonstrate that the resulting sparse portfolio has good tracking and generalization performance on historic data of weekly and monthly returns on the Nikkei 225 index and its constituent companies. 相似文献
84.
Giuliano Freddi Patrizia Monti Masanobu Nagura Yohko Gotoh Masuhiro Tsukada 《Journal of Polymer Science.Polymer Physics》1997,35(5):841-847
Structural changes of tussah (Antheraea pernyi) silk fibroin films induced by heat treatment were studied as a function of the treatment temperature in the range 200–250°C. The DSC curve of tussah films with α-helix molecular conformation displayed characteristic endo and exo peaks at 216 and 226°C, respectively. These peaks first weakened and then completely disappeared after heating at 230°C. Accordingly, the TMA thermal shrinkage at 206°C disappeared when the films were heated at 230°C. The onset of weight loss was monitored at 210°C by means of TG measurements. X-ray diffraction profiles gradually changed from α-helix to β-sheet crystalline structure as the treatment temperature increased from 200 to 250°C. On raising the heating temperature above 200°C, the intensity of IR and Raman bands characteristic of β-sheet conformation increased in the whole ranges of amide and skeletal modes. The sample treated at 200°C showed a spectral pattern intermediate between α-helix and β-sheet molecular conformation. The IR marker band for random coil structure, still detectable at 200°C, disappeared at higher treatment temperatures. Spectral changes attributable to the onset of thermal degradation appeared at 230°C. © 1997 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 35: 841–847, 1997 相似文献
85.
Akira Horii Hitoshi Kawanowa Masayuki Kamei Hisami Yumoto Yoshihiko Gotoh Takehiko Gonda 《Crystal Research and Technology》1996,31(7):875-879
The morphology of the initial growth stage of Ag thin films on Mo(110) substrate was investigated in-situ by the scanning electron microscope (SEM). A great majority of the Ag crystallites showed a truncated Wulff's equilibrium shape of the face-centered-cubic (fcc) structure with epitaxial orientation [1 0]Ag//[11 ]Mo, (111)Ag//(110)Mo with the substrate temperature of 400 °C. In-situ SEM observation during the growth revealed two kinds of particular morphological change of Ag crystallites, namely (1) rotation of an Ag crystallite and (2) reformation of the crystal faces of the Ag crystallite. However, a small number of Ag crystal particles showed Wulff-polyhedron truncated by the (100) plane parallel to the substrate surface (oriented to the 〈100〉 axis normal to the substrate surface). 相似文献
86.
S. Sasaki M. Nagao M. Gotoh I. Uematsu 《Journal of Polymer Science.Polymer Physics》1988,26(3):637-648
Blends composed of the α-helical polymers, poly-L-glutamates [(? NHCαHRC′O? )n, R = ? CH2CH2COO? (CH2)m(C6H5] (Lm) and the corresponding D enantiomers (Dm), have been studied by x-ray diffraction and viscoelastic measurements. Binary blends of L2, D2, L3, and D3 are compatible and form isomorphous mixed crystals at all compositions, whereas other pairs, with the exception of L1/D1, are incompatible. The demixing process is described for a ternary system consisting of L1, D3, and a diluent chloroform at 40°C. The phase diagram comprises four regions, I, IA, A, and AA, with increasing polymer concentration; I: isotropic, A: anisotropic, IA: I–A biphasic, and AA: A–A biphasic. The IA biphasic gap is greater in the ternary system than in the binary ones. The high-molecular-weight component (D3) is partitioned into the A phase in the IA region. The AA separation originates from incompatibility of the polymers. The phase behavior is discussed on the basis of the Abe-Flory theory by incorporating the polymer-polymer interaction parameter. 相似文献
87.
A new approach to simultaneous measurement of isochromatics and isoclinics from a single image using a tricolor light, called as the tricolor photoelastic technique, is proposed in order to enable and facilitate the analysis of time varying phenomena. Not only an apparatus of experiment but the whole analysis system and procedure are developed. Using a color digital camera and a tricolor light source under linear polarization, fringe order and the principal direction of birefringence are obtained from a piece of color image data by a single shot using the method proposed. It is emphasized that this method can be applicable to time varying phenomena in which good repeatability and reproducibility of experiments are not expected, since multiple exposures are not necessary for sufficient data acquisition in the completion of stress analysis. 相似文献
88.
A method for determining the critical coagulation concentration (C
c) from the change in the transmittance of the sol with stand time after adding a coagulating agent is discussed. Potassium nitrate was used as the coagulating agent because the specific adsorption of electrolyte ions on the particle and the hydrolysis of electrolyte ions are negligible. Apparent critical coagulation concentrations,C
c
a, of iron (III) hydroxide and silver iodide sols were obtained from the transmittance vs. potassium nitrate concentration curves for various stand times. The values ofC
c
a decreased with increasing stand time. TheC
c
a value obtained for the shortest stand time was closer toC
c obtained from the initial turbidity change of the sol by applying Rayleigh's law. The Hamaker constant for the particle in water was calculated from theC
c
a value obtained at the shortest time and the experimentally determined outer Helmholtz plane potential. The calculated Hamaker constants were comparable to the theoretical values for iron (III) hydroxide and silver iodide. 相似文献
89.
Copper(II) compounds {CuCA(phz)(H2O)2}n (H2CA = chloranilic acid, phz = phenazine) having a layer structure of -CuCA(H2O)2- polymer chains and phenazine were studied by 35Cl nuclear quadrupole resonance (NQR). The single NQR line observed at 35.635 MHz at 261.5 K increased to 35.918 MHz at 4.2 K. The degree of reduction of electric field gradient due to lattice vibrations was similar to that of chloranilic acid crystal. Temperature dependence of spin-lattice relaxation time, T1, of the 35Cl NQR signal below 20 K, between 20 and 210 K, and above 210 K, was explained by (1) a decrease of effective electron-spin density caused by antiferromagnetic interaction, (2) a magnetic interaction between Cl nuclear-spin and electron-spins on paramagnetic Cu(II) ions, and (3) an increasing contribution from reorientation of ligand molecules, respectively. The electron spin-exchange parameter ∣J∣ between the neighboring Cu(II) electrons was estimated to be 0.33 cm−1 from the T1 value of the range 20−210 K. Comparing this value with that of J = −1.84 cm−1 estimated from the magnetic susceptibility, it is suggested that the magnetic dipolar coupling with the electron spins on Cu(II) ions must be the principal mechanism for the 35Cl NQR spin-lattice relaxation of {CuCA(phz)(H2O)2}n but a delocalization of electron spin over the chloranilate ligand has to be taken into account. 相似文献
90.
Masashi Gotoh Kazuhide Mori Reikichi Itoh 《International journal of quantum chemistry》1995,56(3):163-173
An automated method by the algebraic programming language REDUCE3 for specifying the matrix elements expressed in second quantization language is presented and then applied to the case of the matrix elements in the TDHF theory. This program works in a very straightforward way by commuting the electron creation and annihilation operators (a? and a) until these operators have completely vanished from the expression of the matrix element under the appropriate elimination conditions. An improved method using singlet generators of unitary transformations in the place of the electron creation and annihilation operators is also presented. This improvement reduces the time and memory required for the calculation. These methods will make programming in the field of quantum chemistry much easier. © 1995 John Wiley & Sons, Inc. 相似文献