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171.
172.
Photoinduced NH tautomerism, along with the reaction pathways of phototautomerization in tetrabenzoporphin and porphin free bases in n-octane polycrystalline matrices at 77 K, is studied by simulation of kinetic processes and their experimental observation. The simulation of the processes is performed by the numerical solution of the system of kinetic equations describing the populations of electronic levels and transitions between them. Kinetic dependences are obtained by measuring the perturbation of stationary fluorescence of one component of the 0-0 doublet origin upon pulsed selective photoexcitation of the other component. For two tautomeric forms related by the reversibility of the photochemical reaction, under the assumption of synchronism of the NH rearrangement, (i) analytical solutions governing the reaction rate are found, (ii) a method of measuring the rate constants of the proton rearrangement is suggested and the constants themselves are estimated, and (iii) direct evidence of the participation of T 1 levels in the photochemical reaction is obtained. With the aid of numerical simulations, the specific features of kinetic manifestation of an asynchronous mechanism of the photoinduced NH rearrangement are studied. 相似文献
173.
V. A. Varlachev G. N. Dudkin Yu. F. Krechetov V. N. Padalko E. N. Shuvalov 《JETP Letters》2004,80(3):149-151
A nuclear-reactor experiment on the search for the emission of neutral pions from the neutron-induced fission of 235U nuclei has been carried out. To this end, an experimental setup for searching for the emission of π0 mesons with high sensitivity to this process has been designed and produced. This setup consisted of two Cherenkov total-absorption spectrometers for the detection and measurements of the energy of two gamma-ray photons from π 0-meson decay. The spectrometers were placed at the exits of two coaxial horizontal experimental channels. To protect the detectors from low-energy β and γ rays and neutron fluxes, 3.5-m-long water filters were situated in the channels. To reject the cosmic background, large-area scintillation counters operating in the anticoincidence mode were placed over each spectrometer. The energy and time resolution of the spectrometers, as well as the efficiency of detecting charged particles by scintillation counters, were tested on the secondary electron beam of the Tomsk electron synchrotron Sirius. Runs of measurements of the effect on the operating reactor (duration of 805 h) were alternated with runs of measurements of background on the stopped reactor (duration of 403 h). Statistical processing of the experimental results yields an upper limit of ≤5.3×10 ?12 with a 90% confidence level for the probability of the emission of neutral pions from the neutron-induced fission of 235U nuclei. This result and results of other works carried out with sources of spontaneously fissioning 252Cf nuclei show that the probabilities of the emission of π0 mesons from spontaneous fission and fission induced by fission-spectrum neutrons are equal to each other. 相似文献
174.
Polyphenols of Certain Plants of the Euphorbiaceae Family 总被引:1,自引:0,他引:1
N. G. Abdulladzhanova S. M. Mavlyanov D. N. Dalimov 《Chemistry of Natural Compounds》2003,39(4):399-400
175.
Summary The detachment of a rubber matrix from a rigid inclusion under monotonic loading and at subsequent relaxation is investigated within two dimensional analysis. Examined are stress–strain experimental data acquired with the help of a test bed equipped with a digital image-acquisition device. The influence of the interfacial bonding strength and the particle size on the detachment process is analyzed. The influence of the interfacial bonding strength is visible in the stress–strain diagram of loading and in the recorded images. The relaxation test reveals no influence of the bonding strength on the stress-relaxation. However, the image analysis indicates a secondary transient creep of the contour of detachment, which depends on the interfacial bonding. 相似文献
176.
N. N. Rozanov 《Optics and Spectroscopy》2004,97(4):497-498
A scheme of trapping of temporal solitons by a moving grating induced in an optical fiber by external radiation is proposed. Prospects for using the scheme to increase the capacity and the range of data transmission with the help of dissipative solitons are discussed. 相似文献
177.
178.
A magnetic susceptibility study of solid solutions of calcium-doped lanthanum manganite inlanthanum gallate showed that exchange interactions in clusters of manganese atoms do not change theircharacter with increasing temperature, unlike what is observed with solid solutions on the basis of lanthanumaluminate. 相似文献
179.
180.
Absorption of cnoidal electromagnetic waves, which are the most general periodic solution to the sine-Gordon equation, by electrons of a one-dimensional quantum semiconductor superlattice in the process of impurity ionization is studied in terms of the semiclassical approximation. The dependence of the absorption coefficient on the electric field of an electromagnetic wave is found to be nonmonotone with a pronounced peak. 相似文献