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91.
Wafaa M. Abdou Liborius Born Herwig Hulpke M. Refat Mahran Mahmoud M. Sidky Heinrich Wamhoff 《Phosphorus, sulfur, and silicon and the related elements》2013,188(2-4):179-185
Abstract UV-irradiation (λ > 313 nm) of o,o-diethyl-o-(3-chloro-4-methyl-coumarin-7-yl)-thiophosphate (Coumaphos; 1) in chloroform results in an regioselective dimerization reaction to afford the head-to-tail anti-dimer 2. The structure of 2 is established by single crystal x-ray diffraction. Singlet oxygen does not affect the formation of 2. 相似文献
92.
The Potential of O‐MMT as a Reinforcing Filler for Uncured and Dynamically Cured PVC/XNBR Composites
Organic montmorillonite modified with quaternary ammonium (O‐MMT) was compounded with uncured and dynamically cured poly(vinyl chloride)/carboxylated nitrile butadiene rubber (PVC/XNBR) composites, using a Brabender Plasticorder at 130°C and 50 rpm rotor speed. The reinforcing efficiency of the O‐MMT was investigated in the uncured PVC/XNBR composite and the dynamically cured PVC/XNBR counterpart. Mixing and dynamic curing of the composites were monitored by typical torque‐time curves derived from a Brabender internal mixer. The torque‐time curves revealed that the dynamic curing process was successful and the incorporation of O‐MMT has no adverse effect on the processibility of the composites. It has been found that the introduction of crosslinks within the rubbery phase in the presence of the O‐MMT has further improved the tensile properties. DMA studies revealed that dynamically cured composite with O‐MMT showed higher storage modulus than the composite without O‐MMT. Furthermore, a one‐step tensile modulus vs. temperature curve and a related one peak tensile loss modulus vs. temperature curve were obtained, consequently, both are characteristics of a miscible polymers system. Further evidence on the composite miscibility was purchased by thermal scans from DSC, which showed a single glass transition temperature of PVC/XNBR composites. This claim was further supported by ATR‐IR spectra which revealed that hydrogen bonding is extensively involved in PVC/XNBR composites. This evidence unveiled the exact nature of the specific interactions responsible for miscibility and hence, enhanced mechanical properties. Furthermore, we proved in our studies the reinforcing role played by layered clay due to better dispersion, as well as improved interactions. 相似文献
93.
94.
D. Haristoy S. Mery B. Heinrich L. Mager J. F. Nicoud D. Guillon 《Liquid crystals》2013,40(3):321-328
A series of [1]benzothieno[3,2-b][1]benzothiophene-2,7-dicarboxylate derivatives consisting of a flat, conjugated aromatic moiety containing sulphur hetero-atoms and substituted by terminal chains - ethyl, decyl, Z-4-decenyl or 2-(2-butoxyethoxy)ethyl - has been synthesized. These materials exhibit a smectic liquid crystalline phase, the stability of which was found to be strongly dependent on the length and the nature of the terminal chains. In the mesophase, the molecular arrangement within the smectic layer is characterized by a local stacking of the rigid parts similar to that found in discotic columnar systems. Finally, clear photoconductive behaviour was found in mechanically aligned samples of these liquid crystals. 相似文献
95.
Tao Zhou Silke Richter Ralf Matschat Heinrich Kipphardt 《Accreditation and quality assurance》2013,18(4):341-349
A candidate material for the use as primary standard for silver determination was characterized with respect to total purity. Except the radioactive elements and He, all possible impurities were considered. Based on glow discharge mass spectrometry, inductively coupled plasma-mass spectrometry and carrier gas hot extraction measurements, the demonstrated total purity and its standard uncertainty is w(Ag) = (99.999 52 ± 0.000 11) %. The purity value and its uncertainty is dominated by the contributions from the measurements of the nonmetallic impurities, namely S, N, C and O. 相似文献
96.
Sren Arlt Vladana Petkovi Gerd Ludwig Thomas Eichhorn Heinrich Lang Tobias Rüffer Sanja Mijatovi Danijela Maksimovi-Ivani Goran N. Kaluerovi 《Molecules (Basel, Switzerland)》2021,26(7)
Neutral [Ru(η6-arene)Cl2{Ph2P(CH2)3SPh-κP}] (arene = benzene, indane, 1,2,3,4-tetrahydronaphthalene: 2a, 2c and 2d) and cationic [Ru(η6-arene)Cl(Ph2P(CH2)3SPh-κP,κS)]X complexes (arene = mesitylene, 1,4-dihydronaphthalene; X = Cl: 3b, 3e; arene = benzene, mesitylene, indane, 1,2,3,4-tetrahydronaphthalene, and 1,4-dihydronaphthalene; X = PF6: 4a–4e) complexes were prepared and characterized by elemental analysis, IR, 1H, 13C and 31P NMR spectroscopy and also by single-crystal X-ray diffraction analyses. The stability of the complexes has been investigated in DMSO. Complexes have been assessed for their cytotoxic activity against 518A2, 8505C, A253, MCF-7 and SW480 cell lines. Generally, complexes exhibited activity in the lower micromolar range; moreover, they are found to be more active than cisplatin. For the most active ruthenium(II) complex, 4b, bearing mesitylene as ligand, the mechanism of action against 8505C cisplatin resistant cell line was determined. Complex 4b induced apoptosis accompanied by caspase activation. 相似文献
97.
Dr. Julian Heinrich Dr. Karolina Bossak-Ahmad Mie Riisom Dr. Haleh H. Haeri Tasha R. Steel Vinja Hergl Alexander Langhans Corinna Schattschneider Jannis Barrera Dr. Stephen M. F. Jamieson Prof. Matthias Stein Prof. Dariush Hinderberger Prof. Christian G. Hartinger Prof. Wojciech Bal Prof. Nora Kulak 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(72):18093-18102
Redox-active Cu(II) complexes are able to form reactive oxygen species (ROS) in the presence of oxygen and reducing agents. Recently, Faller et al. reported that ROS generation by Cu(II) ATCUN complexes is not as high as assumed for decades. High complex stability results in silencing of the Cu(II)/Cu(I) redox cycle and therefore leads to low ROS generation. In this work, we demonstrate that an exchange of the α-amino acid Gly with the β-amino acid β-Ala at position 2 (Gly2→β-Ala2) of the ATCUN motif reinstates ROS production (•OH and H2O2). Potentiometry, cyclic voltammetry, EPR spectroscopy and DFT simulations were utilized to explain the increased ROS generation of these β-Ala2-containing ATCUN complexes. We also observed enhanced oxidative cleavage activity towards plasmid DNA for β-Ala2 compared to the Gly2 complexes. Modifications with positively charged Lys residues increased the DNA affinity through electrostatic interactions as determined by UV/VIS, fluorescence, and CD spectroscopy, and consequently led to a further increase in nuclease activity. A similar trend was observed regarding the cytotoxic activity of the complexes against several human cancer cell lines where β-Ala2 peptide complexes had lower IC50 values compared to Gly2. The higher cytotoxicity could be attributed to an increased cellular uptake as determined by ICP-MS measurements. 相似文献
98.
D. Thao Nguyen Matthias Freitag Christian Gutheil Dr. Kai Sotthewes Dr. Bonnie J. Tyler Dr. Marcus Böckmann Mowpriya Das Friederike Schlüter Prof. Dr. Nikos L. Doltsinis Prof. Dr. Heinrich F. Arlinghaus Prof. Dr. Bart Jan Ravoo Prof. Dr. Frank Glorius 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(32):13754-13759
99.
Sebastian Scharf Eduard Kovalski Tobias Rüffer Alexander Hildebrandt Heinrich Lang 《无机化学与普通化学杂志》2020,646(22):1820-1833
The synthesis of [Ti6O4(OiPr)8(O2CPh)8] ( 3 ) and [RuCl(N≡CR)5][RuCl4(N≡CR)2] ( 4a , R = Me; 4b , R = Ph), [Ru(N≡CPh)6][RuCl4(N≡CPh)2] ( 5 ) and [H3O][RuCl4(N≡CMe)2] ( 7a ) is discussed. Crystallization of 5 from CH2Cl2 gave trans-[RuCl2(N≡CPh)4] ( 6 ). The solid-state structures of 3 , 4a , b , 5 , 6 and 7a are reported. Complex 4b forms a 3D network, while 6 displays a 2D structure, due to π-interactions between the benzonitrile ligands. The (spectro)electrochemical behavior of 4a , b and 6 was studied at 25 and –72 °C and the results thereof are compared with [NEt4][RuCl4(N≡CMe)2] ( 7b ) and [RuCl(N≡CPh)5][PF6] ( 8 ). The electrochemical response of the cation and the anion in 4a , b are independent from each other. [RuCl(N≡CR)5]+ possesses one reversible RuII/RuIII process. However, [RuCl4(N≡CMe)2]– was shown to be prone to ligand exchange and disproportionation upon formation of either a RuIV and RuII species at 25 °C, while at –72 °C the rapid conversion of the electrochemically formed species is hindered. In situ IR and UV/Vis/NIR studies confirmed the respective disproportionation reaction products of the aforementioned oxidation and reduction, respectively. 相似文献
100.
D. Thao Nguyen Matthias Freitag Christian Gutheil Kai Sotthewes Bonnie J. Tyler Marcus Bckmann Mowpriya Das Friederike Schlüter Nikos L. Doltsinis Heinrich F. Arlinghaus Bart Jan Ravoo Frank Glorius 《Angewandte Chemie (International ed. in English)》2020,59(32):13651-13656
A novel photoresponsive and fully conjugated N‐heterocyclic carbene (NHC) has been synthesized that combines the excellent photophysical properties of arylazopyrazoles (AAPs) with an NHC that acts as a robust surface anchor (AAP‐BIMe). The formation of self‐assembled monolayers (SAMs) on gold was proven by ToF‐SIMS and XPS, and the organic film displayed a very high stability at elevated temperatures. This stability was also reflected in a high desorption energy, which was determined by temperature‐programmed SIMS measurements. E‐/Z‐AAP‐BIMe@Au photoisomerization resulted in reversible alterations of the surface energy (i.e. wettability), the surface potential (i.e. work function), and the conductance (i.e. resistance). The effects could be explained by the difference in the dipole moment of the isomers. Furthermore, sequential application of a dummy ligand by microcontact printing and subsequent backfilling with AAP‐BIMe allowed its patterning on gold. To the best of our knowledge, this is the first example of a photoswitchable NHC on a gold surface. These properties of AAP‐BIMe@Au illustrate its suitability as a molecular switch for electronic devices. 相似文献