Two Beam Coupling in Semi-Insulating GaN Film Using Electroabsorption Effect

The photorefractive effect was observed in He-ion-implanted semi-insulating GaN film in the UV spectral region. The photorefractive grating is induced by the electroabsorption effect near the band-edge. Two beam coupling experiments were performed at a wavelength of 363.8 nm. The experimental results indicate that absorption grating mainly contributes to the beam coupling.     

A charge-transfer host system composed of a chiral 1,1′-bi-2-naphthol cluster and benzylviologen

Chiral charge-transfer (CT) complexes composed of a chiral 1,1′-bi-2-naphthol cluster as the electron donor and 1,1′-dibenzyl-4,4′-bipyridinium dichloride as the electron acceptor serve as a host system for molecular recognition. CT complexes that include guest alcohols show different diffuse reflectance spectra (DRS) depending on the included guest.     

Diversity of Ligularia kanaitzensis in sesquiterpenoid composition and neutral DNA sequences

Twenty-six eremophilane-type sesquiterpenoids, including six new compounds, were isolated from the title species. One of the new compounds, kanaitzensol, suggested the presence of an enzyme for the conversion of eremophil-7(11)-en-8-one derivative to furanoeremophilanes. The plant was collected at 15 locations in Yunnan Province of China and found to be diverse with respect to its sesquiterpenoid composition. DNA sequencing also revealed a large intraspecific diversity of the plant.     

Hydrogen bonding of urea-salicylic acid,U·SA

Urea (U) and salicylic acid (SA) crystallize from aqueous solution as a 11 adduct whose structure shows them to be linked via several weak and one strong hydrogen bonds. The ir spectra of the adduct and its deuterated counterpart have been analyzed and the stretching modes of the various hydrogen bonds identified. The¹H and¹³C nmr. spectra are also interpreted to show that discrete adducts of U·SA persist in solution. On heating, U·SA decarboxylates at a much lower temperature than SA itself.     

Preparation of mixed isopropyl/trimethylsilyl derivatives of boric acid, (Me3SiO)nB(OiPr)3-n(n = 1–3), and their GC-M

Boric acid was trimethylsilylated with Me₃SiCl/(Me₃Si)₂O in the presence of 2-propanol. The resulting mixture was analysed by using a combi     

A study of the fluorescence lifetime of Pr3+ in SBN40

The fluorescence lifetime τ₁ of Pr³⁺ doped in the ferroelectric solid solution SNB40 (Ba_0.4Sr_0.6Nb₂O₆) was measured ar various temperatures. The fluorescence lifetime decreases gradually with increasing temperature. Furthermore, an anomalous increase of τ₁ was observed at a specific temperature. The fluorescence linewidth and the peak wavelength of fluorescence also showed an anomalous change at this temperature. It is likely that this phenomenon is due to the phase transition of the host crystal SBN40.