全文获取类型
收费全文 | 886篇 |
免费 | 37篇 |
国内免费 | 4篇 |
专业分类
化学 | 691篇 |
晶体学 | 7篇 |
力学 | 29篇 |
数学 | 102篇 |
物理学 | 98篇 |
出版年
2023年 | 5篇 |
2022年 | 15篇 |
2021年 | 22篇 |
2020年 | 28篇 |
2019年 | 17篇 |
2018年 | 15篇 |
2017年 | 13篇 |
2016年 | 34篇 |
2015年 | 38篇 |
2014年 | 22篇 |
2013年 | 42篇 |
2012年 | 55篇 |
2011年 | 65篇 |
2010年 | 51篇 |
2009年 | 30篇 |
2008年 | 48篇 |
2007年 | 54篇 |
2006年 | 42篇 |
2005年 | 38篇 |
2004年 | 38篇 |
2003年 | 33篇 |
2002年 | 20篇 |
2001年 | 12篇 |
2000年 | 15篇 |
1999年 | 23篇 |
1998年 | 11篇 |
1997年 | 11篇 |
1996年 | 12篇 |
1995年 | 5篇 |
1994年 | 7篇 |
1993年 | 7篇 |
1992年 | 8篇 |
1990年 | 6篇 |
1989年 | 11篇 |
1988年 | 5篇 |
1987年 | 4篇 |
1986年 | 5篇 |
1985年 | 6篇 |
1984年 | 5篇 |
1983年 | 3篇 |
1982年 | 5篇 |
1981年 | 4篇 |
1979年 | 4篇 |
1976年 | 2篇 |
1973年 | 2篇 |
1971年 | 2篇 |
1939年 | 2篇 |
1935年 | 2篇 |
1890年 | 2篇 |
1881年 | 2篇 |
排序方式: 共有927条查询结果,搜索用时 15 毫秒
31.
Regina Janciene Ausra Vektariene Zita Stumbreviciute Lidija Kosychova Kazimieras Konstantinavicius Benedikta D. Puodziunaite 《Monatshefte für Chemie / Chemical Monthly》2003,44(1):1629-1639
Highly substituted, novel, 8- and 9-nitro-2,3,4,5-tetrahydro-1,5-benzodiazepin-2(1H)-ones were obtained by direct nitration of the 7-bromo-5-trifluoroacetyl (or formyl)-substituted tetrahydrobenzodiazepinones. Alkaline and acidic hydrolysis of the novel mononitro derivatives was examined. Semiempirical AM1 calculations of aromatic substituents orientation in the nitration products are presented. 相似文献
32.
33.
34.
35.
Magaly A. M. Lyra José L. Soares-Sobrinho Regina C. B. Q. Figueiredo Jana M. Sandes ádley A. N. Lima R?mulo P. Tenório Danilo A. F. Fontes Fabiana L. A. Santos Larissa A. Rolim Pedro J. Rolim-Neto 《Journal of inclusion phenomena and macrocyclic chemistry》2012,73(1-4):397-404
The current chemotherapy for Chagas disease is still based on benznidazole, which has low solubility, but complexation with cyclodextrins provides a way of increasing the solubility. The objective of this work was to characterize the inclusion complexes formed between benznidazole (BNZ) and randomly 2-methyled-β-cyclodextrin (RM-β-CD) in aqueous solution and study cytotoxicity and trypanocidal. BNZ:RM-β-CD solution complex systems were prepared and characterized using the phase solubility diagram, nuclear magnetic resonance and a photostability assays, also to investigate the in vitro trypanocidal activity with epimastigote forms of Trypanossoma cruzi and the study of cytotoxicity against mammal cells. The phase-solubility diagram displayed an A L-type feature, providing evidence of the formation of soluble inclusion complexes. The continuous variation method showed the existence of a complex with 1:1 stoichiometry. Toxicity assays demonstrated that inclusion complexes were able to reduce the toxic effects caused by benznidazole alone and that this did not interfere with the trypanocidal activity of the benznidazole. The use of inclusion complexes benznidazole:cyclodextrin is thus a promising alternative for the development of a safe and stable liquid formulation and a new option for the treatment of Chagas disease. 相似文献
36.
37.
38.
It is shown that the model of interaction of high-power few-cycle optical pulses with media, which is based on the density matrix formalism, is capable of simultaneously considering generation of longwave radiation in the infrared and terahertz range and describing the broadening of the radiation spectrum into the high-frequency region. The results of the mathematical modeling are compared to the known experimental data. 相似文献
39.
We construct an example of a non-metric perfectly normal hereditarily indecomposable continuum. The example is constructed as an inverse limit of non-metric analogues of solenoids. Theorems needed to insure perfect normality are stated and proven. It is shown that the example cannot be embedded in a countable product of Hausdorff arcs. 相似文献
40.
Manfred Meisel Annegrit Rabis Arnd-Rüdiger Grimmer Irmgard Hartwich Regina Bienert Dirk Wulff-molder 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1)
Abstract Previoudy we reported on the preparative use of donorstabilized monometaphosphates, Py.PO2Cl and Py.PS2Cl[1]. 3P MAS investigations as well as X-ray single crystal analysis have been carried out. The isotropic chemical shift of the sulfur compound shows the typical downfield shift (106 ppm) with respect to the oxygen compound The chemical shift anisotropy gives additional information. The relative large spans ω (Py.PO2Cl: 401 ppm, Py.PS2Cl: 461 ppm) [2] reveal strong deviations from tetrahedral symmetry (ω = 0 ppm) in agreement with the structural data. The values of the skew parametem K (0.64 and 0.71 resp.) reflect the trend to axial symmetry (k = ± l). X-ray diffraction and NMR data suggest a structural model corresponding to a concentration of double bond character on the two P-X bonds. This model is consistent with the extremely short P-X bond length (1.449 Å and 1.921 Å rasp.) as well as the large P-X-P bond angles (126.4°and 123.7° resp.). 相似文献