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961.
Superoxide generated in DMF readily converts the dihalovinyl group of permethrin and related compounds to a haloethynyl moiety and yields major products from elimination reactions of DDT, -chlordane, and 1,2-dibromo-3-chloropropane (DBCP). 相似文献
962.
The effect of destroying carbonyl and hydroperoxide groups in oxidised polypropylene on the subsequent rate of photo-oxidation has been examined using infra-red spectroscopy. The results show that carbonyl groups dominate the rate of photo-oxidation in severely oxidised polymer. In mildly oxidised polymer hydroperoxide groups control the rate, but to a much smaller extent. Destruction of the photo-active carbonyl and hydroperoxide groups in the unoxidised and oxidised polymers by prior photolysis in an inert atmosphere gave rise to some interesting and complex effects on subsequent photo-oxidation. The results indicate that although carbonyl and hydroperoxide groups may control the rates of photo-oxidation of thermally oxidised/processed polymer, their importance as primary photo-initiators is highly questionable. Oxygen-polymer charge transfer complexes appear to be the more likely photo-initiators. 相似文献
963.
The regioselectivity of the reactions of perimidine with cinnamic acids in polyphosphoric acid (PPA) depends on the P2O5 content. Procedures were developed for the synthesis of 4(9)- and 6(7)-cinnamoylperimidines. Cyclization of the latter under the action of an excess of AlBr3 was accompanied by dearylation to form 6-hydroxy-1,3-diazapyrene. 相似文献
964.
S. A. Denisova O. S. Kudryashova A. E. Lesnov E. A. Sazonova 《Russian Journal of General Chemistry》2007,77(11):1855-1858
Solubility isotherms of the antipirin-pyrocatechol-water ternary system at 25 and 50°C were constructed. A field where two liquid phases are present in equilibrium which results from the protolytic interaction between the components was revealed. The various-composition chemical compounds that formed were isolated preparatively. Interphase distribution of a series of metal ions was studied. The half-extraction pHs of rare-earth metals were found to be linearly related to their ionic radii. 相似文献
965.
I. I. Kandror V. A. Usov I. O. Bragina T. L. Usova V. K. Bel'skii M. G. Voronkov 《Russian Chemical Bulletin》1989,38(4):811-815
1. | Radical arylation of 3-arylamino-2-phenyl-1-indenthiones with aryldiazonium fluoroborates or N-nitrosoacetanilide leads to the corresponding 1-arylamino-2-phenyl-3-arylthioindenes with high yield. Partial hydrolysis of the latter under the reaction conditions form 1-oxo-2-phenyl-3-arylthioindenes as by-products. |
2. | The similarity of thioamides and their vinylogs (the aminoindenthiones) in radical arylation reactions was established. |
966.
O.A. Vita 《Analytica chimica acta》1976,81(1):45-52
Uranium hexafluoride reacts with nitrosyl fluoride (NOF), nitryl fluoride (NO2F), and nitrogen oxides to form solid compounds such as nitrosyl heptafluorouranate (NOUF7) and nitryl heptafluorouranate (NO2UF7). Since these compounds are undesirable impurities in uranium hexafluoride, a method has been developed for the determination of these nitrogen oxyfluorides in uranium hexafluoride. Uranium hexafluoride is hydrolyzed in a potassium permanganate solution which converts the uranium hexafluoride to uranyl fluoride and the nitrogen oxyfluorides to nitric acid. The nitrate is reduced with aluminum powder to ammonia, which is then measured with an ammonia electrode in a basic solution. The method is relatively interference-free because the electrode is a gas-sensing device. The detection limit is 0.8 μg bound N/g U, and the precision at 3 μg bound N/g U is ± 16%. 相似文献
967.
Zusammenfassung Die Systeme Co
x
Mg
1-x
TiO3 (I) und Co
x
Cd
1-x
TiO3 (II) wurden röntgenographisch und spektralphotometrisch untersucht. I stellt eine lückenlose Mischkristallreihe dar. Mit wachsendemx nehmen bei I die Gitterkonstantena
0undc
0geringfügig zu und die drei Hauptabsorptionsbanden verschieben sich ein wenig in Richtung IR. In II liegt keine lückenlose Mischkristallreihe vor. Sowohl röntgenographisch als auch spektralphotometrisch wurde für die an CoTiO3 gesättigte CdTiO3-Phase die Zusammensetzung Co0,3Cd0,7TiO3 (II a) und für die an CdTiO3 gesättigte CoTiO3-Phase die Zusammensetzung Co0,8Cd0,2TiO3 (II b) gefunden.Beim Übergang III (x=0,1) wird eine beträchtliche IR-Verschiebung beobachtet. Die IR-Verschiebung ist die Folge der Gitteraufweitung bei der Substitution von Mg2+ durch Cd2+. Hierbei nimmt derRacah-Parameter geringfügig zu infolge Verminderung der covalenten Anteile der Bindung Co-O.
Mit 4 Abbildungen
11. Mitt.:D. Reinen, Mh. Chem.96, 730 (1965). 相似文献
The systems Co x Mg 1-x TiO3 (I) and Co x Cd 1-x TiO3 (II) had been investigated spectrophotometrically and by X-ray diffraction. I represents mixed crystals without any miscibility gap. An increase ofx causes a small enhancement of the lattice unitsa 0andc 0of I and the three main absorption bands will be shifted slightly towards IR. II are mixed crystals with a broad miscibility gap. Spectrophotometrically and by X-ray diffraction it could be found that the CdTiO3-phase saturated with CoTiO3 and the CoTiO3-phase saturated with CdTiO3 have the compositions Co0,3Cd0,7TiO3 (II a) and Co0,8Cd0,2TiO3 (II b), respectively. The transition III (x=0,1) produces a considerable shift of the main absorption bands towards IR as a consequence of the expansion of the lattice caused by the substitution of Cd2+ for Mg2+. This shift is accompanied by a small increase of theRacah-Parameter owing to a decrease of covalency of the bonding Co-O.
Mit 4 Abbildungen
11. Mitt.:D. Reinen, Mh. Chem.96, 730 (1965). 相似文献
968.
Yu. B. Vysotsky V. S. Bryantsev O. A. Gorban 《Chemistry of Heterocyclic Compounds》2002,38(12):1451-1468
The effects of benzannellation, phenyl substitution at the nitrogen atom, protonation at the carbene carbon, ionization, and the state of the carbene center (2 or 2) on the electronic structure, diamagnetic susceptibility, induced -electron ring currents, the 1H, 13C, and 14N chemical shifts, and the energies of the lowest electronic transitions of imidazol-2-ylidenes and their oxo and thio analogs were examined in the bound version of -electron perturbation theory. The calculated and experimental data are compared. 相似文献
969.
970.
The molecular structure of 1,1,1,2-tetrafluoroethane is studied using gas-phase electron diffraction data collected on the Balzers KDG2 instrument. Effective least-squares refinement of the geometry is achieved with values for vibrational amplitudes transferred from normal coordinate calculations on related molecules. The following values for the main independent geometrical parameters are obtained (ra values with e.s.d. in parentheses): C-C = 1.501(4) Å, C-H = 1.077 (15) Å, C-F(CH2F) = 1.389(6) Å, C-F(CF3) = 1.334 (2) Å, ∠CCH= 106.1(12)°, ∠CCF(CH2F)= 112.3(4) Å, ∠CCF(CF3)= 110.4(2). Other angles are ∠FCF = 108.6 (2)° and ∠FCH = 111.4(15)°, with ∠HCH constrained at 109.4°. The ra bond lengths of all the fluoroethanes are compared. 相似文献